Journal of Textile Research ›› 2022, Vol. 43 ›› Issue (04): 110-116.doi: 10.13475/j.fzxb.20201204307

• Dyeing and Finishing & Chemicals • Previous Articles     Next Articles

Cyanotype process of cotton fabric under photocatalytic conditions

HOU Qianqian, LI Wenxi, ZHAO Meihua()   

  1. College of Textiles and Clothing, Qingdao University, Qingdao, Shandong 266071, China
  • Received:2020-12-16 Revised:2022-01-18 Online:2022-04-15 Published:2022-04-20
  • Contact: ZHAO Meihua E-mail:jennymhzhao@126.com

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Abstract:

In order to identify the influencing factors affecting the process of cyanotype exposure, a photocatalytic reactor with stable conditions was experimented as a new exposure method. The influence of printing factors such as photosensitizer concentration, cotton fabric type, ultraviolet(UV) lamp power and exposure time on the image effect of cyanotype process was investigated, and the optimized printing conditions of the cyanotype process were obtained. The properties of cotton fabrics were characterized by the scanning electron microscope, universal tensile tester and others. The results show that cotton fabrics with an areal density of 180 g/m2 has the best cyanotype image effect when exposed to 600 W UV light for 30 min, with much improved efficiency. The lamp power is proportional to the exposure time, and both are found to be the main factors affecting the quality of cyanotype image. Comparing to the raw cotton fabric, the mass of plain dyed fabric (without pattern) and that of the printed fabric (with pattern) under the optimized conditions were 7.26% and 5.57% respectively, and the tensile strength was increased by 66.89 and 46.78 N, respectively. It was concluded that the properties of fabric substrate change with the different amount of Prussian blue pigment precipitation.

Key words: cyanotype, cotton fabric, classical printing technology, Prussian blue, photocatalysis

CLC Number: 

  • TS193.8

Fig.1

Carrier before exposure"

Fig.2

Sun exposure"

Fig.3

Schematic effect diagram of exposure process"

Tab.1

Values of each factors during exposure"

棉织物种类 灯管功率/W 曝光时间/min
薄型 300 10
中厚型 600 20
较厚型 900 30

Fig.4

SEM images of raw cotton fabries at different magnification"

Fig.5

SEM images of plain dyed cotton fabries at different magnification"

Fig.6

Image effect of different concentrations of sensitizer"

Fig.7

Influence of cotton fabrics on cyanotype. (a)Thin size;(b)Medium size;(c)Thicker size"

Fig.8

Influence of lamp power on cyanotype"

Fig.9

Influence of exposure time on cyanotype"

Tab.2

Performance test result of fabric"

织物名称 断裂强
力/N		 断裂伸长
率/%		 透气率/
(mm·s-1)		 质量增加
率/%
原棉织物 145.09 28.60 746.75 —
印相织物 191.87 13.01 711.34 5.57
素染织物 211.98 12.36 695.75 7.26

Fig.10

Cyanotype image under optimized conditions. (a)Building;(b)Lao tze portrait;(c)Fire lines;(d) Plant"

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