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Table of Content

    15 June 2025, Volume 46 Issue 06
        
    • Column of Youth Scientists′Salon on New Fiber Materials and Green Textile Development
      Transformation rule of polyester glycolysis products in methanol transesterification
      XU Wenhao, CHEN Lin, XU Shimei, WANG Xiuli, WANG Yuzhong
      Journal of Textile Research. 2025, 46(06):  1-7.  doi:10.13475/j.fzxb.20241201301
      Abstract ( 230 )   HTML ( 24 )   PDF (5326KB) ( 156 )   Save
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      Objective Polyester is the most widely used fiber material in waste textiles, and its efficient recycling is the key to solving the problem of waste textiles. At present, the combined glycolysis-methanol transesterification process is widely used in industry. In this process, the methanol transesterification reaction of glycolysis products into dimethyl terephthalate (DMT)is the key step. Therefore, the transformation rule of glycolysis products in methanol transesterification can provide theoretical guidance for the efficient chemical recycling of waste polyester.

      Method In this paper, the chemical recycling of polyester was studied according to the industrial combined glycolysis-methanol transesterification process. The depolymerization products of polyester textile during glycolysis and methanol transesterification were qualitatively and quantitatively studied by high performance liquid chromatography-mass spectrometry (HPLC-MS).

      Results In the first step of glycolysis, the glycolysis products of polyester are mainly bis(2-hydroxyethyl) terephthalate (BHET) monomer, dimer, trimer, tetramer, and pentamer. The oligomer content can be controlled by reducing the ethylene glycol ratio and shortening the depolymerization time. Firstly, the glycolysis solution with a mass ratio of polyethylene terephthalate (PET) to ethylene glycol (EG) of 1∶1 and depolymerized at 190 ℃ for 1 h was selected for methanol transesterification. HPLC-MS showed that BHET monomer, dimer, and trimer could be completely converted into DMT within 3 h, while tetramer and pentamer could not be completely converted into DMT due to their large molecular weight and low reaction activity. The intermediate 2-hydroxyethyl methyl terephthalate is generated during the conversion of BHET and oligomers to DMT. The conversion rate of BHET and oligomers to DMT was very fast (within 5 min), and then remain at a very low content. The BHET in the PET glycolysis products was separated by water washing, and the conversion process of BHET oligomers to DMT was studied in detail. HPLC-MS confirmed that the separated oligomer products were mainly BHET dimer, tetramer, pentamer and trace trimer. The separated BHET oligomers were subjected to methanol transesterification reaction. It was found that the BHET dimer and trimer completely disappeared after methanol transesterification, which again showed that dimer and trimer were completely converted into DMT. However, BHET tetramer and pentamer still exist, proving that it was difficult to completely convert them into DMT. This is because BHET tetramer and pentamer have larger molecular weights and lower reactivity. They have fewer effective collisions with methanol in the transesterification reaction and cannot be completely converted into DMT. Since DMT is the final recycled monomer of polyester in this combined process, the depolymerization of polyester into BHET monomer, dimer, and trimer during glycolysis is the ″effective″ depolymerization.

      Conclusion Aiming at the glycolysis-methanol transesterification combined process used in industry, the methanol transesterification process of the glycolysis depolymerization products of polyester was researched and revealed. In the first step of glycolysis, the glycolysis products of polyester are mainly BHET monomer, dimer, trimer, tetramer, and pentamer. In the second step of methanol transesterification, BHET monomer, dimer, and trimer can be completely converted into DMT at 65 ℃ for 3 h. However, BHET tetramers and pentamers exhibit low reactivity due to their large molecular weight and are difficult to be completely converted into DMT. The depolymerization of polyester into BHET monomer, dimer, and trimer during glycolysis represents the ″effective″ depolymerization. Therefore, the content of BHET monomer and its dimer and trimer can be increased by increasing the proportion of ethylene glycol and prolonging the depolymerization time, thereby improving the final DMT yield and achieving efficient chemical recycling of polyester fibers. The transformation rules of BHET and its oligomers to DMT in the glycolysis products of polyester were determined, which provides theoretical guidance for the chemical recycling of polyester textiles in glycolysis-methanol transesterification combined process.

      Preparation of fluorinated waterborne polyurethane from waste polyester fibers by alcoholysis
      SHI Sheng, WANG Yazhou, WANG Shuhua, PANG Mingke, LI Xin, ZHANG Meiling, GAO Chengyong
      Journal of Textile Research. 2025, 46(06):  8-16.  doi:10.13475/j.fzxb.20240702201
      Abstract ( 181 )   HTML ( 27 )   PDF (3635KB) ( 121 )   Save
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      Objective Polyester fibers is popularly used in modern textile industry, and the recycling of waste polyester fibers is very meaningful. The objective of this paper is to recycle waste polyester by chemical methods and synthesize the obtained products into fluorinated waterborne polyurethane (FWPU) with higher value, in order to realize the recycling and reuse of waste polyester fibers.

      Mothed The alcoholysis of waste polyester fibers was carried out under the conditions of choline chloride and zinc acetate as composite catalysts using ethylene glycol as alcoholysis agent. The effects of the molar ratio of choline chloride and zinc acetate, the reaction temperature, and the mass ratio of polyester fibers to ethylene glycol on the conversion rate of polyester fibers and the production rate of bis(2-hydroxyethyl)terephthalate(BHET) were explored, respectively. The products from the alcoholysis were studied. The alcoholysis products were synthesized into FWPU, and the effects of different isocyanate index(R-values), 2,2-bis(hydroxymethyl)propionic acid(DMPA) additions, and 2,2,3,3,4,4,5,5-octafluoro-1-pentanol(F8) additions on the properties of FWPU emulsion appearance, emulsion stability, pH value, and emulsion viscosity were investigated, and the molecular structure of FWPU was characterized.

      Results The best conditions for alcoholysis reaction were found as follows: reaction temperature 180 ℃, zinc acetate to choline chloride was 1∶1, reaction time 4 h, polyester to ethylene glycol was 1∶5, under which the polyester fiber conversion rate was as high as 100%, the product yield of BHET reached up to 91.5%. When the R vlaue was 1.3, the content of DMPA was 8%, the content of F8 was 15%, the appearance of FWPU emulsion was clear and transparent, particle size was less than 255 nm, which belongs to the range of polyurethane emulsion. Viscosity was 95 mPa·s, pH value was weak alkaline, emulsion has good stability.

      Conclusion In this study, waste polyester fibers were recycled and FWPU were synthesized by alcoholysis, and it was found that waste polyester fibers can be recycled by glycol alcoholysis, and FWPU can be successfully synthesized from the alcoholysis products, and the obtained FWPU has small particle size and viscosity, good stability, and appearance.

      Construction of organic/inorganic nanoflowers on carbon fiber for detection of hydrogen peroxide
      LI Mufang, WEI Wanru, LI Qianqian, SONG Yinnan, WANG Dong, LUO Mengying
      Journal of Textile Research. 2025, 46(06):  17-22.  doi:10.13475/j.fzxb.20241201401
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      Objective Excessive hydrogen peroxide (H2O2) can cause cardiovascular diseases, neurodegenerative diseases, diabetes complications, arthritis and other diseases. H2O2 detection is conducive to physiological disease monitoring, production process optimization, product quality improvement, and environmental monitoring. The existing biosensors have some drawbacks such as low sensitivity, poor selectivity and complicated technology. Therefore, it is of great significance to develop an H2O2 sensor with simple manufacturing processes and excellent performance.

      Method A copper layer was constructed on the carbon fiber surface by chemical copper plating, and the copper-loaded carbon fiber was immersed in 0.1 mg/mL horseradish peroxidase (HRP) solution for in-situ growth of organic/inorganic nanoflowers. The morphological structure and chemical structure of the modified carbon fiber were investigated. The cyclic voltammetry and current response curves were measured to verify the capability of the modified carbon fiber for H2O2 detection. Furthermore, the specificity of HRP/Cu3(PO4)2/carbon fiber was studied.

      Results A uniform copper layer was successfully deposited on the carbon fiber surface through chemical copper plating at room temperature for 30-60 min. Subsequently, the copper-coated carbon fiber was immersed in a phosphate-buffered saline (PBS) solution containing 0.1 mg/mL HRP. The copper could be oxidized into copper ions, which first chelated with the amide groups of HRP to form a crystal nucleus and then bound with phosphate ions in a buffer solution to achieve crystal growth. As the process continued, the grains gradually aggregated, forming petal-like structures that eventually developed into a hierarchical flower-like morphology. The prepared carbon fiber electrode with HRP/Cu3(PO4)2 organic/inorganic nanoflowers showed excellent electrocatalytic performance. The HRP/Cu3(PO4)2/carbon fiber exhibited a sensitive current response to H2O2 within a concentration range of 0.1 to 2 mmol/L, and it showed a good linear response to H2O2 with a correlation coefficient R2 of 0.999, a sensitivity of 146.3 μA/(mmol·L-1·cm) and a low detection limit of 0.441 μmol/L. Additionally, The electrode has no current response to potential interfering substances such as glucose, NaCl, KCl, ascorbic acid and urea, demonstrating it has excellent anti-interference capabilities.

      Conclusion The HRP/Cu3(PO4)2/carbon fiber H2O2 electrochemical sensor was prepared by in-situ organic/inorganic nanoflowers growth on the highly conductive carbon fiber surface at room temperature. This method is simple, cost-effective, and environmentally friendly. The modified carbon fiber demonstrated excellent electrocatalytic performance. It exhibited a good linear relationship in the concentration range of H2O2 from 0.1 to 2 mmol/L with a linear correlation coefficient R2 of 0.999, a sensitivity of 146.3 μA/(mmol·L-1·cm) and the detection limit of 0.441 μmol/L. In addition, the electrode has no current response to potential interfering substances such as glucose, NaCl, KCl, ascorbic acid, and urea, highlighting its excellent anti-interference capabilities. These results indicated its potential for highly selective and sensitive detection of H2O2 in complex biological and environmental samples.

      Continuous preparation and application of nickel-doped liquid metal composite fibers
      WANG Xu, LI Huanyu, FU Fan, YANG Weifeng, GONG Wei
      Journal of Textile Research. 2025, 46(06):  23-30.  doi:10.13475/j.fzxb.20250104001
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      Objective Liquid metal-based conductive fibers offer several advantages, such as excellent electrical conductivity, and high stretchability, making them highly promising for smart textile applications. To enable the continuous fabrication of this kind of fiber, it is crucial to reduce the surface tension of the liquid metal and improve its interface adhesion. In this study, a liquid metal modification and fiber coating process was developed. Moreover the adhesion properties of the modified liquid metal composite paste were examined, as well as the electrical and mechanical properties of the resulting liquid metal composite fibers.

      Method Nickel powder doping modification was used to prepare the liquid metal composite (LMC) paste with low surface tension and strong adhesion. This paste was then applied to the surface of silver-plated polyamide fibers through a coating process, enabling the continuous fabrication of LMC fibers. The morphology of these fibers was characterized, and their adhesion, mechanical, oxidation resistance, electrical, and electrothermal conversion properties were systematically investigated.

      Results The surface morphology of three types of fibers(silver-plated polyamide fibers, liquid metal fibers(LM fibers), and LMC fibers)was examined using a super ultra-depth-of-field microscope. The experimental outcomes demonstrated that under identical coating procedures, the LM fibers had minute liquid metal droplets on their surfaces. In sharp contrast, the surfaces of the LMC fibers were uniformly covered with a compact layer of liquid metal composite paste. As a direct consequence of this coating, the diameter of the LMC fibers experienced a subtle augmentation, rising from an initial 223 μm to 248 μm. This study also investigated the effect of incorporating nickel powder into the liquid metal on its adhesion properties. When liquid metal and liquid metal composite paste were dropped onto the surface of an inclined glass plate, the liquid metal droplets slid off, while the liquid metal composite paste remained firmly in place. This suggests that the liquid metal modified with nickel powder has significantly improved adhesion properties. After coating the silver-plated polyamide fibers with the liquid metal composite paste, their electrical conductivity was greatly enhanced, achieving a conductivity of 4.8 × 105 S/m,an impressive 728% increase compared to the uncoated silver-plated polyamide fibers. Moreover, the LMC fibers demonstrated excellent stability across various environments. When immersed in water for 1 h, or bent at different angles, the increase in resistance was only 1.9% and 0%, respectively, indicating that the LMC fibers possess strong environmental adaptability and stability. Stress-strain analysis of the three types of fibers revealed that the LMC fibers showed a slight reduction in tensile extensibility, but their overall performance remained comparable to that of the silver-plated polyamide fibers. These findings demonstrate that the coating of silver-plated polyamide fibers with liquid metal composite paste significantly improves their electrical conductivity and stability, while having minimal impact on their mechanical properties. Additionally, in three cycles of heating and cooling tests at a low voltage of 1.62 V, the fibers heated from 22.2 ℃ to 27.0 ℃ in just 15 s, further highlighting their excellent thermal responsiveness.

      Conclusion This study successfully achieved the dynamic renewal of the surface oxide layer of liquid metal through nickel doping technology, resulting in a liquid metal composite paste with enhanced electrical conductivity and strong adhesion. By applying this paste to the surface of silver-plated polyamide fibers, LMC fibers with outstanding electrical conductivity and good flexibility were produced. The electrical conductivity of the LMC fibers reached 4.8×105 S/m, with only 285 g of paste required to produce 10 km of fiber. Stress-strain tests demonstrated that coating the fiber surface with the liquid metal composite paste did not significantly compromise the mechanical properties of the fibers, ensuring their structural stability and reliability for practical applications. Additionally, the LMC fibers exhibited excellent stability in both bent states and underwater environments. Leveraging their electrothermal properties, these fibers can also be utilized as a solution for thermal management. In conclusion, the LMC fibers hold significant promise for applications in the field of smart clothing.

      Preparation and touching characterization of textile-based touch electronics fabric
      XU Tong, XU Ruidong, WANG Yiwen, TIAN Mingwei
      Journal of Textile Research. 2025, 46(06):  31-37.  doi:10.13475/j.fzxb.20241001901
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      Objective The bionic reconfiguration of touch as a basic human sensory channel has become a key scientific issue in the development of artificial intelligence and robotics. But, most of the current touch sensing devices are composed of composite electrodes with hydrogel as the sensing layer, which has inherent problems such as poor bio-compatibility and low inter-facial fastness. Therefore, this work provide a strategy to address the above issues. Silk fabric with natural bio-compatibility is used as substrate material. Conductive waterborne polyurethane(WPU) which can form inter-molecular interactions with silk fabric is used as upper material, constructing textile-based touch electronics fabric.

      Method Textile-based touch electronics fabric has a laminated structure with a conductive waterborne polyurethane upper layer and a silk fabric lower layer. Conductive waterborne polyurethane which is a blend of waterborne polyurethane and multi-walled carbon nanotube has excellent electrical properties and stability. Waterborne polyurethanes are synthesized by the self-emulsification method. Electronics fabric can recognize touch position, because before touching electronics fabric has been construct uniform electric field. When touching electronics fabric, electrical circuit is built and touch current is stimulated. Based on natural skin-friendly and presence of inter-molecular interaction between silk and conductive waterborne polyurethane, electronics fabric has high bio-compatibility and stable inter-facial fastness.

      Results Select 11 points on the surface of the electronics fabric at equal intervals and touch them sequentially from left to right. The results displayed that the touch current monitored by the A1 ammeter decreases and touch current with A2 rises insteps, which the sum of current monitored by two ammeters is constant. Choosing the midpoint of the fabric as the test point, the test found that the response time is 73 ms and the recovery time is 100 ms, which proves that the touch electronics fabric has a high response speed. Touching the midpoint of the fabric for 500 times and comparing the change of touch current for 1, 50, 100, 300 and 500 times, the result shows that the change rate of touch current is only 0.118%, which proves that the touch electronic fabric has excellent touch stability. Touch electronics fabric is placed for 60 d and the midpoint is selected as the touch point. Comparing the change of touch current in 0, 5, 10, 15, 30 and 60 d, the result proves that the change rate of touch current is less than 1.5%, which proves that the touch electronic fabric has excellent touch durability. Different bending angles, including 30°, 60°, 90°, 120°, 150°, 180°, are applied to touch electronics fabric, and the midpoint of touch electronics fabric is selected as touch point. By monitoring the change of touch current under different angles, the result proves that the maximum fluctuation of touch current is only 5%, which proves that the touch electronic fabric can still work under the bending state. In addition touch electronics fabric is successfully applied to the development of a flexible keyboard. The electronics fabric is divided into three parts, the left, middle, right parts correspond to the left, down and right movement in the control of Tetris. Based on this function, the interface interaction can be realized by dividing the touch electronics fabric into different zones.

      Conclusion A textile-based touch electronics fabric with silk fabric as the substrate and waterborne polyurethane/multi-walled carbon nanotubes as the conductive paste is prepared and investigated, which solves the bottlenecks such as poor bio-compatibility and low inter-facial fastness of traditional ionogel-based touch devices. The silk touch electronics fabric has excellent touch sensing characteristics such as high-precision touch positioning function, excellent response time (73 ms), touch stability and touch durability. In addition, the touch electronics fabric also has deformation insensitive characteristics, and the touch current of the textile can still be maintained constant after many times of bending and deformation. On this basis, a fabric control interface is developed to realize touch game control, which has a broad application prospect in the field of intelligent wearable human-computer interaction.

      Preparation and performance of dual-directional temperature-regulating flame-retardant and anti-static textiles
      LIN Siling, LIU Fuyao, ZHANG Cheng, HOU Lin, XU Yanyan, FU Ranqian, FAN Wei
      Journal of Textile Research. 2025, 46(06):  38-44.  doi:10.13475/j.fzxb.20241100401
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      Objective In order to address the limitations of traditional clothing in temperature regulation and meet the higher demand for thermal comfort in contemporary society, this research develops smart textiles with temperature-regulating, flame-retardant, and anti-static functions. The research focused on effectively combining textile materials with phase change microcapsules (PCMs) to endow textiles with the ability to store and release heat, thereby achieving bidirectional temperature regulation.

      Method The study involved three main steps. First, viscose fibers with temperature-regulating functions were prepared by mixing phase change microcapsules with viscose fiber spinning solutions and using a wet spinning process. Second, these fibers were blended with intrinsic flame-retardant fibers (acrylic chlorine, aramid 1313, and flame-retardant viscose) through a ring spinning process to produce temperature-regulating flame-retardant yarns. Finally, these yarns were combined with polyamide conductive yarns to create intelligent yarns with flame-retardant, anti-static, and temperature-regulating properties, which were then woven into fabrics using a semi-automatic loom.

      Results The blended fibers obtained by combining phase change microcapsule-viscose fibers with intrinsic flame-retardant fibers through ring spinning exhibited an obvious flame-retardant synergistic effect. The optimal fiber ratio was determined to be 30% phase change microcapsule-viscose fibers, 20% flame-retardant viscose, and 50% aramid 1313. The 33 ℃ temperature-regulating flame-retardant yarn combined with polyamide conductive yarn showed better performance in textile applications compared to the 28 ℃ temperature-regulating flame-retardant yarn. The surface morphology analysis revealed that the phase change microcapsule-viscose fibers had a rough surface with distinct longitudinal groove structures due to the stretching during the wet spinning process. The composite yarns and fabrics exhibited good appearance characteristics. The thermoregulation performance analysis showed that both 28 ℃ and 33 ℃ phase change composite fabrics had bidirectional temperature regulation capabilities. The 33 ℃ phase change composite fabric had a higher temperature regulation range and greater latent heat of fusion and crystallization, indicating stronger temperature regulation ability. The flame retardancy analysis demonstrated that both composite fabrics met the national standard requirements for B-level flame-retardant protective clothing. The 33 ℃ phase change composite fabric showed better flame retardancy, with no after-flame or smoldering during the test, and the damage length was less than 100 mm. The char residue analysis indicated that the dense char structure formed during combustion effectively inhibited heat and smoke release, contributing to the flame-retardant performance. The anti-static performance analysis revealed that both phase change composite fabrics met the national standard requirements for anti-static clothing, with point-to-point resistance values below the specified upper limit, indicating good charge dissipation ability. The 33 ℃ composite fabric exhibited better anti-static performance with lower resistance values.

      Conclusion This research successfully developed a multi-functional intelligent textiles with bidirectional temperature regulation, flame-retardant, and anti-static performance. The textiles were prepared by optimizing the blending ratio of phase change microcapsule-viscose fibers with different flame-retardant fibers and combining them with polyamide conductive yarns. The results showed that the developed textile had good thermoregulation, flame-retardant, and anti-static performance, meeting national standards and demonstrating significant potential for application in industries such as petroleum, chemical engineering, and fire protection. The study provides a new solution for improving safety and comfort in these fields and offers valuable insights for future research and development in intelligent textiles.

      Review on multidimensional structural evolution of natural cellulose and its functional materials
      YU Houyong, HUANG Chengling, CHEN Yi, GAO Zhiying
      Journal of Textile Research. 2025, 46(06):  45-55.  doi:10.13475/j.fzxb.20241104802
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      Significance Driven by global sustainable development goals to reduce reliance on petrochemical-based plastics and developing green, low-carbon alternative materials have become a key focus in both academia and industry. Cellulose, as a natural polymer, is an ideal candidate to replace traditional plastics due to its excellent biocompatibility and low toxicity. With advancements in nanotechnology, material science, and chemical modification techniques, natural cellulose can be transformed into various forms, including nanocellulose, regenerated cellulose fibers, regenerated cellulose films, and cellulose-based aerogels. These multidimensional structures exhibit unique functional properties and can be widely applied in pharmaceutical excipients, smart textiles, degradable packaging materials, and energy-efficient water purification materials. Therefore, studying the preparation methods, properties, and applications of cellulose-based materials is of great academic and practical significance, providing a theoretical foundation and technical support for the development and industrialization of green alternative materials.

      Progress In recent years, research into cellulose-based materials has advanced considerably, driven by the growing demand for sustainable alternatives to petrochemical-based products. Through chemical modification and nanoscale processing techniques, natural cellulose can now be transformed into a range of innovative materials with diverse structural forms, including low-dimensional nanocellulose, one-dimensional regenerated cellulose fibers, two-dimensional regenerated cellulose films, and three-dimensional cellulose-based aerogels. These various structural forms offer distinct advantages in terms of mechanical properties, processing technologies, and functional applications. For example, nanocellulose, with its high surface area, nanoscale dimensions, and exceptional mechanical strength, has gained significant attention in fields such as composites, sensors, and biomedical applications. The remarkable properties of nanocellulose allow it to be used as a reinforcing agent in composites, enhancing the material's strength while remaining lightweight. Regenerated cellulose films have seen notable progress in applications such as smart packaging, where their ability to respond to environmental stimuli has made them particularly suitable for developing responsive, eco-friendly packaging solutions. Additionally, cellulose-based aerogels are lightweight, highly porous materials with superior adsorption properties. They are increasingly being explored for their potential in energy storage, thermal insulation, and environmental protection, particularly for applications such as oil spill cleanup and water purification. Moreover, the biodegradability of cellulose materials and their minimal environmental impact make them promising substitutes for traditional petrochemical-based materials. As environmental concerns escalate, cellulose-based materials are viewed as viable and sustainable options, offering a greener alternative for many industrial applications. This transition to renewable, biodegradable resources represents a significant step toward achieving global sustainability goals and reducing dependence on non-renewable resources.

      Conclusion and Prospect The research and application of cellulose-based multidimensional materials have demonstrated great promise, offering extensive potential across various industries, ranging from packaging to environmental protection. However, significant challenges persist, especially in the realms of processing techniques, optimization of material properties, and feasibility of large-scale production. One of the primary obstacles is the necessity to refine the methods employed for fabricating and modifying cellulose materials, ensuring their efficient and consistent production at a commercial scale. Additionally, while cellulose materials possess remarkable properties such as biodegradability and versatility, further advancements are necessary to enhance their mechanical strength, durability, and functional capabilities in order to meet the requirements of a wide range of applications. Future research should concentrate on exploring the full potential of cellulose materials in multidimensional structural transformations. Innovations aimed at improving the mechanical properties of cellulose-based materials, such as increasing their tensile strength or impact resistance, will be crucial for broadening their industrial applications. Functionalization, which refers to the ability to customize the properties of cellulose for specific applications, is another significant area of focus. This could involve developing cellulose materials with advanced characteristics like water resistance, antimicrobial properties, or responsive behaviors, which are suitable for use in smart textiles and packaging. Furthermore, ensuring the sustainability of these materials is crucial, as cellulose is inherently renewable. However, the processes used to manufacture and modify it must be environmentally friendly and energy-efficient. With the ongoing advancement of green chemistry, cellulose materials are likely to find commercial applications in various sectors, particularly in biodegradable packaging, smart textiles, and environmental protection. Researchers and industry leaders need to prioritize balancing multifunctionality with environmental impact, ensuring that cellulose-based materials offer practical solutions while also supporting the transition to a green, low-carbon economy. It will necessitate continued innovation, collaboration, and investment in both research and industrial scaling.

      Research progress in cellulose nanofluid systems for osmotic energy harvesting
      DING Zhenhua, YUAN Kaiyu, ZHOU Jing, YE Dongdong
      Journal of Textile Research. 2025, 46(06):  56-62.  doi:10.13475/j.fzxb.20241202502
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      Significance The significant osmotic pressure difference between river water and seawater presents a promising and renewable energy source ready for development. Unlike other renewable energies such as wind, solar, and tidal energy, osmotic energy depends less on environmental conditions and can offer a stable energy output. Efficient collection and utilization of osmotic energy can help reduce energy supply pressures. Ion-selective materials are crucial for osmotic energy harvesting technologies. Cellulose, the most abundant and widely distributed polysaccharide in nature, is notable for its plentiful availability and low cost. Its ease of modification and diverse processing techniques have contributed to its extensive application across various industries. Modified cellulose, with its abundant surface charges, can be processed into desired structures in a controlled manner, making it highly applicable in the field of osmotic energy harvesting.

      Progress Cellulose is a versatile biopolymer commonly derived from wood, cotton, and bacterial cultures. Cellulose nanofluid systems with nanochannels that match double-layer thickness, high charge density, and elevated ion transport flux demonstrate ionic conductivities significantly surpassing bulk solutions at very low salt concentrations. This property grants the system high sensitivity and responsiveness to changes in solution concentration driven by pressure, temperature, and material composition, resulting in enhanced osmotic energy harvesting performance under 50-fold salinity gradients. Wood is particularly notable due to its naturally oriented structure and distinct porous cross-section, which can be manipulated through twisting and compressing to densify micropores to the nanoscale, which is ideal for ion transport control. Modification treatments like N-oxo-1,2,2,6,6-pentamethylpiperidine-N-oxyl(TEMPO) oxidation or quaternization enhance the wood's ion management capabilities by imparting a rich surface charge. Techniques such as crushing and acid hydrolysis break down macro-sized wood and cotton into nanofiber structures, which can be processed into nanofluid membranes for improved ion transport. These nanofibers can be combined with two-dimensional materials like MXenes to enhance ion management and reduce production costs. The NaOH/urea/water dissolved regenerated cellulose system is gaining traction, producing highly ordered and closely packed porous structures that create shorter ion transport pathways. The combination of cellulose's surface charges and functional materials facilitates directed ion transport, making cellulose a versatile solution for various applications.

      Conclusion and Prospect Cellulose is an eco-friendly natural polymer with significant potential in ion management due to its renewability, sustainability, and low cost. Found abundantly in plants, cellulose's hydroxyl groups allow for easy modification, providing diverse surface charges to regulate ion transport. Its versatility supports osmotic energy harvesting, desalination, ion monitoring, and energy storage applications. Challenges include its crystalline structure limiting ion migration speed and hydrophilicity, which potentially reduce performance in aquatic environments. Recent advancements like ion coordination improve performance primarily in cellulose nanofibers. Continuous research and new construction strategies aim to enhance cellulose's role in high-performance material applications.

      Fiber Materials
      Preparation and radiation refrigeration properties of polylactic acid fiber aerogel
      TAN Wenping, ZHANG Shuo, ZHANG Qian, ZHANG Yin, LIU Runzheng, HUANG Xiaowei, MING Jinfa
      Journal of Textile Research. 2025, 46(06):  63-72.  doi:10.13475/j.fzxb.20231105801
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      Objective Global climate change and extreme weather have increased energy demand for refrigeration. The traditional refrigeration equipment not only consumes a lot of energy in the refrigeration process, but also brings additional heat consumption, further aggravating the urban heat island effect and energy crisis. With the growing concern for energy efficiency, and the key goal of carbon neutrality, much attention has been paid to zero-energy refrigeration technology. Hence, it is imperative to design an environmentally friendly radiation refrigeration material and to devise new refrigeration methods.

      Method Poly(L-latic acid)(PLLA) and PLLA/poly(D-latic acid)(PDLA) fiber filaments were prepared by wet spinning technology, and then the fiber filaments were dispersed into uniform fiber dispersion liquid by high-speed shear emulsifier. PLLA and fiber aerogel modified by hydrophilic Al2O3 particles were prepared by chemical crosslinking of methyl trimethoxysilane under acidic conditions, modification of hydrophilic Al2O3 particles, ice crystal growth and freeze drying. The morphology of fiber and fiber aerogel was analyzed by scanning electron microscopy (SEM). The chemical properties of the samples were analyzed by Fourier infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and differential scanning calorimeter(DSC). The physical properties of aerogel were analyzed by material testing machine and water contact angle analyzer. Finally, the emittance, reflectance and radiation cooling effect were analyzed by infrared spectroscopy with gold integrating sphere, ultraviolet-visible-near infrared spectrophotometer and homemade outdoor device.

      Results The optimum parameters for preparing PLLA/PDLA microfibers by wet spinning were obtained by testing the apparent viscosity and structural viscosity index of the spinning solution. The mass ratio of PLLA/PDLA was 10∶0 and 9∶1 and the concentration of the spinning solution was 10%. Under these parameters, smooth and uniform PLLA and PLLA/PDLA microfibers with diameter of (7.914±0.07) μm and (6.39±0.06) μm were successfully prepared. The stereo-polylactic acid fibers have been successfully prepared by wet spinning by FT-IR and DSC analysis. After ice crystal growth and freeze-drying technology, the porous fiber aerogels modified by Al2O3 particles were successfully prepared. With the increase of Al2O3 particle concentration, the coverage rate of Al2O3 on the surface of the aerogels increased. At the same time, the presence of C—O and C—O/H, and C—Si bonds were observed at the peaks of binding energy at 289.0, 286.9 and 284.8 eV. The presence of O—C—O, O—Si and bonds were observed at the peak binding energies at 533.7, 532.6 and 532.2 eV, and the Si—O and Si—C bonds in methyltrimethoxysilane(MTMS) were observed at 103.4 eV and 102.7 eV. At the same time, the presence of Al2p and low energy characteristic peaks were observed at the binding energies of 74.57 eV and 73.68 eV, which prove that the aerogel has formed a stable cross-linked network. Fiber aerogel has excellent hydrophobic and mechanical properties, and the stress of fiber aerogel was increased from 9.84 kPa to 16.71 kPa with the increasing Al2O3 contents from 5% to 15% under 60% compression. In the radiation refrigeration performance test, the reflectivity and emissivity of PLLA/PDLA aerogel were higher than that of PLLA aerogel, and when the Al2O3 content in the fiber aerogel was increased to 5.0%, the reflectivity reached the highest (81.91%), and the emissivity reached 96.18%.

      Conclusion PLLA/PDLA fibers were prepared by wet spinning. The fibers were uniform, smooth and with a diameter of (6.39±0.06) μm. The fiber aerogel with stable structure was obtained by Al2O3 modification and freeze-drying. When the Al2O3 content in the fiber aerogel was gradually increased from 5.0% to 15.0%, the water contact angle of the fiber aerogel decreased from 153.6° to 128.31°. At the same time, the stress of the fiber aerogel increased from 9.84 kPa to 16.71 kPa under 60% compression. After outdoor radiation refrigeration effect test, it was found that the highest average reflectivity of fiber aerogel was 81.91%, the highest average emissivity was 96.24%, the maximum outdoor daytime (10:30-13:30) cooling temperature was up to 3.6 ℃, and the maximum outdoor night (18:00-21:00) cooling temperature was up to 4.7 ℃, showing strong infrared radiation ability.

      Preparation and properties of gastrodia elata polysaccharide/polyvinyl alcohol antibacterial food-wrap membrane by electrospinning
      WANG Chunxiang, LI Jiao, XIE Kaifang, XUE Hongkun, XU Guangbiao
      Journal of Textile Research. 2025, 46(06):  73-79.  doi:10.13475/j.fzxb.20240606601
      Abstract ( 100 )   HTML ( 17 )   PDF (11665KB) ( 69 )   Save
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      Objective Fruits, vegetables and foods are easily contaminated by Escherichia coli, Staphylococcus aureus, mold and other common microorganisms. To extend the shelf life of fruits, vegetables and foods, it is of practical significance and application value to develop advanced packaging materials with antibacterial and fresh-keeping effects. In this paper, the feasibility of preparing antibacterial food-wrap membrane by electrospinning from gastrodia elata polysaccharides (GEP) and medical grade polyvinyl alcohol (PVA) was explored, which laid the foundation for the development of GEP nanofiber membrane with low-cost, green, antibacterial and fresh-keeping properties.

      Method GEP was extracted by hot water extraction and aqueous two-phase extraction. The dry gastrodia elata blume was soaked in water, heated and extracted twice by induction cooker, and then the extract was cooled to room temperature, and the precipitate was collected after ethanol precipitation, and the GEP was extracted in ethanol/ammonium sulfate aqueous two-phase system, and the lower supernatant was taken out after standing for 24 h, and the crude polysaccharide of gastrodia elata blume was obtained by vacuum filtration, dialysis and freeze-drying. The purity, chemical structure, crystal structure, morphology and antibacterial properties of GEP were tested and analyzed. The GEP/PVA nanofiber membranes(with a GEP addition amount of 1.0%) were prepared by electrospinning under different voltages, and their antibacterial properties, surface morphology, fiber fineness, tensile properties, and fresh-keeping effect on strawberry were tested and analyzed.

      Results The extraction rate of GEP obtained using a combination of hot water extraction and aqueous two-phase extraction is 2.0%, with a content of 82.22%, and it exhibits a typical infrared spectrum curve of polysaccharides. The GEP show that it has amorphous structure and smooth surface. The antibacterial property of GEP was tested by agar plate diffusion method, and 200 mg/mL GEP solution had good antibacterial performance against Escherichia coli and Staphylococcus aureus. The antibacterial performance of GEP/PVA spinning solution was tested by absorption method, and the antibacterial rate of GEP/PVA(1.0% GEP) spinning solution against Escherichia coli was more than 99%. When the electrospinning voltage is 18 kV, the GEP/PVA nanofiber membrane is well formed, the average fiber diameter is about 320 nm, and the tensile breaking strength of the membrane is up to 247.59 cN when the membrane thickness is 0.09 mm; The preservation effect of GEP/PVA nanofiber membrane was the best and the weight loss rate was the lowest at 5 ℃ in the refrigerator environment. The preservation effect of GEP/PVA nanofiber membrane could extend the shelf life of strawberry for 3 d at room temperature.

      Conclusion In this paper, the dry gastrodia elata blume was used as raw material to extract crude polysaccharide by hot water extraction and aqueous two-phase extraction, and the GEP/PVA nanofiber membrane was successfully prepared by electrospinning technology with PVA as the film-forming carrier. When the electrospinning voltage was 18 kV, the GEP/PVA nanofiber membrane was well formed. GEP/PVA nanofiber membrane has good fresh-keeping effect, which can effectively slow down the evaporation and loss of water, and prolong the shelf life of strawberries for 3 d at room temperature. The successful preparation of GEP/PVA nanofiber membrane not only realizes the application feasibility of GEP in fruit and vegetable preservation, but also contributes to the development of plant polysaccharide fruit and vegetable and food packaging materials with low-cost, green environmental protection, antibacterial preservation and excellent performance.

      Torsional sensing characteristics of polyacrylonitrile/MoS2 fiber membranes based on flexoelectric effect
      ZHANG Jiacheng, YU Ying, ZUO Yuxin, GU Zhiqing, TANG Tengfei, CHEN Hongli, LÜ Yong
      Journal of Textile Research. 2025, 46(06):  80-87.  doi:10.13475/j.fzxb.20240705401
      Abstract ( 98 )   HTML ( 2 )   PDF (9023KB) ( 30 )   Save
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      Objective Flexible wearable sensors have vast potential applications in the field of healthcare. For example, real-time monitoring of joint torsion in the treatment of elbow and knee arthritis plays a crucial role in the rehabilitation of conditions such as tennis elbow and meniscus injuries. However, current monitoring of joint torsion mainly relies on the traditional optical motion capture methods, which lack real-time capabilities. This research aims to develop flexible wearable torsion sensor devices to meet the joint monitoring needs for treatment of joint-related diseases.

      Method Polyacrylonitrile(PAN)/MoS2 fiber membranes were prepared using electrospinning technology, which were then characterized for their structure, morphology, elemental content, and mechanical properties. A custom-built torsional flexoelectric response test platform were used to evaluate the impact of different MoS2 mass fractions on the flexoelectric effect of the PAN/MoS2 fiber membranes. The response of the PAN/MoS2 torsion sensor to various torsion angles was tested, and its practicality was demonstrated by conducting experiments where the torsion sensor was attached to the joints of a wooden mannequin.

      Results The microscopic morphology and physical properties of the fiber membranes showed that MoS2 was successfully loaded onto PAN, and the membranes exhibited excellent crystallinity. Pure PAN membranes exhibited a weak flexoelectric effect. However, with the addition of MoS2, the response current and voltage of the fiber membranes was significantly increased with the increase of MoS2 content. When the MoS2 mass fraction reached 50%, the flexoelectric response voltage and current peak were 176.41 mV and 102.85 pA, respectively. When the MoS2 content was further increased to 55%, the response current and voltage drop to 65.61 pA and 97.77 mV. This decline was due to the excessive MoS2 nanoparticles forming aggregates on the PAN surface, which significantly hindered the orderly arrangement of polymer molecular chains and restricts ion migration. As a result, the potential difference generated by the membrane torsion was lower, reducing the flexoelectric coefficient. For torsion angle sensing tests, the PAN/MoS2 fiber membrane with 50% MoS2 was chosen. As the torsion angle increased, the response current and voltage also increased significantly, and the electrical signal waveform remains stable. When the torsion angle was increased from 6° to 30°, the response current and voltage reached a maximum of 183.73 pA and 254.16 mV. This is attributed to the increased shear strain gradient and polarization intensity within the fiber membrane with larger torsion angles. Application experiments with the torsion sensor attached to the joints of a wooden mannequin demonstrated that the PAN/MoS2 torsion sensor was able to accurately capture joint torsion changes.

      Conclusion PAN/MoS2 fiber membranes were prepared via electrospinning, successfully loading MoS2 nanoparticles onto the PAN surface. The mass fraction of MoS2 in the PAN/MoS2 fiber membranes significantly would affect their flexoelectric effect. Experiments show that when the MoS2 mass fraction is below 50%, the flexoelectric response current and voltage increase with the MoS2 content. At 50% MoS2 content, the flexoelectric current and voltage reach their optimal levels. However, when the mass fraction exceeds 50%, the MoS2 particles cluster and weaken the flexoelectric effect. Experimental results indicate that the PAN/MoS2 torsion sensor is highly sensitive to changes in torsion angles. Application experiments with the torsion sensor attached to the joints of a wooden mannequin confirm that the PAN/MoS2 torsion sensor can accurately detect joint torsion changes.

      Modification of polysuccinimide nano fibrous membrane and its dye adsorption properties
      QIU Yue, YANG Xun, LI Hao, LI Haidong, WU Guozhong, ZHANG Caidan
      Journal of Textile Research. 2025, 46(06):  88-95.  doi:10.13475/j.fzxb.20240702301
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      Objective With people gradually raising the awareness of environmental protection and increasingly strict environmental policy, the pollution of dye wastewater has been attracting extensive attention. The adsorption method is one of the most cost-effective methods and environmentally friendly absorbent materials are widely explored. Polyasparthydrazide (PAHy) is a polyaspartic acid derivative with good biodegradability and abundant amino groups, associated with low cost. It is an ideal absorbent material for wastewater treatment. However, in practical applications, challenges such as poor structural stability due to the complexity of post-adsorption separation caused by water-soluble polymers, along with limited adsorption capacity, are often encountered. To address these issues, this study aims to develop a novel insoluble PAHy nanofibrous membrane with regenerative performance through electrospinning and chemical cross-linking techniques. In this study, PAHy nanofibrous membrane with high porosity was prepared and used for Congo Red (CR) adsorption.

      Method Polysuccinimide (PSI) solution was prepared by dissolving PSI into N,N-dimethylformamide solvent and nanofibrous membrane was prepared utilizing electrospinning technology. The prepared membrane was soaked in 0.25 mol/L ethanediamine (ED) solution to form PSI crosslinking. Then, different concentration of hydrazine hydrate solution was added to transform PSI into PAHy. After that, 5% acetic acid solution was employed for the neutral reaction, and the samples were washed with deionized water and immersed in ethanol for deswelling. Finally, PAHy nanofibrous membrane was characterized and the Congo Red adsorption properties were evaluated.

      Results The result confirmed the successful modification of PSI to PAHy, with characteristic peak imide groups shifting upon crosslinking and hydrazine treatment. The PSI nanofibrous membrane exhibited adjacent bands at 1 794 cm-1 and 1 709 cm-1 due to the coupled effect of two neighboring carbonyl groups. After crosslinking and hydrazine treatment, the residue succinimide rings in PSI were opened and the PAHy was generated. PAHy membrane was able to maintain the nanofibrous morphology with partly fused together, and the fiber diameter of nanofibrous membranes increased initially after modification. PSI nanofibrous membrane exhibited an excellent swelling property after ED crosslinking. PAHy nanofibrous membranes prepared by different concentration of hydrazine hydrate had a relatively small impact on its swelling properties. PAHy nanofibrous membrane with high porosity and abundant amino groups exhibited excellent adsorption capacity for CR dye. PAHy nanofibrous membrane modified by 15% hydrazine hydrate and at pH value of 5 displayed optimal adsorption capacity. And the maximum adsorption capacity was 1 679.3 mg/g. The adsorption process followed a pseudo-second-order kinetic model, as evidenced by the high correlation coefficient, indicating a chemisorption-dominated mechanism with possible physical adsorption contributions. The adsorption isotherm analysis revealed that the Langmuir model provided a better fit than the Freundlich model, suggesting a monolayer adsorption process. The regenerative capacity of PAHy nanofibrous membranes was confirmed through repeated adsorption-desorption cycles. The desorption was carried out by alkaline elution and acid neutralization. After 4 adsorption-desorption cycles, the PAHy nanofibrous membranes retained 83.4% of its initial adsorption capacity, demonstrating the potential for reuse in practical applications.

      Conclusion In this study, PAHy nanofibrous membrane was successfully prepared through PSI nanofibrous membrane ethylenediamine crosslinking and hydrazine hydrate ammonolysis. The PAHy nanofibrous membrane with a large number of cationic amino functional groups exhibited an excellent CR adsorption capacity. PSI formed a structure after opening the ring with ethylenediamine. Cross-linked PSI nanofibrous membrane had good water absorption performance. Then PAHy nanofiber membrane was prepared by ammonolysis with hydrazine hydrate of cross-linked PSI nanofibrous membrane. The optimal adsorption conditions of PAHy nanofibrous membrane for CR were as follows: the concentration of hydrazine hydrate was 15%, the adsorption pH value was 5, and the adsorption time was 6 h. Moreover, PAHy nanofibrous membrane was reusable for CR adsorption after alkaline elution and acid neutralization. It suggests that PAHy nanofibrous membrane has a broad range of applications in dye wastewater treatment.

      Textile Engineering
      Influence of seed cotton humidification before ginning on cotton processing quality of machine harvested upland cotton in northern Xinjiang
      QIN Jianfeng, SHI Shuwei, MENG Yongfa, LI Menghui, XIA Bin
      Journal of Textile Research. 2025, 46(06):  96-102.  doi:10.13475/j.fzxb.20240804901
      Abstract ( 113 )   HTML ( 8 )   PDF (4516KB) ( 37 )   Save
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      Objective Moisture regain is one of the key factors affecting the quality of cotton processing. However, during the cotton processing season of the cotton region in northern Xinjiang, China, the amount of precipitation and hence the air humidity is low, and the moisture regain rate of cotton is lower than the optimal moisture regain level, which leads to greater damage to cotton fiber during the processing. To this end, the effects of humidification of seed cotton before ginning on cotton fiber length, length uniformity index and breaking strength were investigated.

      Method A machine cotton picking line in Kuitun City was selected, and the second drying unit of the cotton processing line was modified as the moisture conditioning unit. The experiment was conducted with seed cotton picked at the same time in the same field and stored under the same conditions, and the air temperature of the second moisture conditioning unit was used as the test factor. The moisture regain, trash content, cotton fiber length, length uniformity index and breaking strength were used as the cotton processing quality indexes, and the single-factor experimental method was designed to analyze the effect of the factors on the evaluation indexes.

      Results There was no significant difference between the control group and the groups with different treatments in the feeding link (p >0.05) and the moisture return rate of cotton after drying (p >0.05). The moisture regain rate of cotton after two humidifications (p <0.001) and that of cotton gathering (p <0.001) were significantly different under different treatments. Compared with the control group, the moisture regain of cotton after two humidification steps was increased corresponding to each treatment level, and with the increase of temperature at the treatment level, the moisture regain got increased. The moisture regain of cotton in the gathering stage also increased with the moisture regain of cotton after the second humidification process, and the increase of moisture regain of cotton after the second humidification process did not fully reflect the increase of moisture regain of cotton in the gathering stage. Different treatments had no significant effect on the impurity content of lint after processing (p >0.05), and the statistical results showed that the trash content of lint did not change regularly with the increase of treatment level temperature. The effect of different treatments on cotton fiber length was significant (p <0.001). The univariate Pearson test showed that hot and humid air temperature was positively correlated with cotton fiber length (r = 0.978, p <0.05). The cotton fiber length increased about 0.397 mm with 1% increase in moisture regain before glint. The influence of different treatments on the cotton fiber length uniformity index after processing was significant (p <0.001). The univariate Pearson test showed that the hot and humid air temperature was positively correlated with the evenness index of cotton fiber length (r = 0.910, p <0.05). Length uniformity index increased by about 0.637%. The influence of different treatments on the specific breaking strength of lint fiber after processing was significant (p <0.001). The univariate Pearson test showed that the temperature of hot and humid air was positively correlated with the breaking strength (r = 0.977, p <0.05). The breaking strength of cotton fiber is increased by about 0.335 cN/tex.

      Conclusion For the machine harvested upland cotton production line in the cotton region of northern Xinjiang, the humidification of seed cotton before ginning can improve the moisture regain of cotton ginning and baled cotton, but the moisture regain of cotton ginning is not fully reflected in the increase of moisture return of baled cotton. Under the existing process conditions, the trash content of lint is not affected by increasing the humidification of seed cotton before ginning, and cotton fiber length, length uniformity index and breaking strength are increased, which can reduce the damage to cotton fiber during processing and improve the quality of cotton processing.

      Preparation and hygroscopic properties of polyvinyl alcohol/sodium alginate/polyamide 66 composite hydrogel core-spun yarns
      CHEN Yajuan, GUO Hanyu, ZHANG Chentian, LI Xinxin, ZHANG Xueping
      Journal of Textile Research. 2025, 46(06):  103-110.  doi:10.13475/j.fzxb.20240703901
      Abstract ( 123 )   HTML ( 7 )   PDF (7461KB) ( 48 )   Save
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      Objective Polyamide 66 (PA66) filaments are commonly used in workwear and mountaineering clothing due to their high strength, cold resistance, and aging resistance. However, PA66 filaments have poor hygroscopicity, leading to easy generation of static electricity during weaving. Meanwhile fabrics accumulate sweat and breed bacteria, endangering human health during wear. Hydrogel materials exhibit excellent water absorption and retention properties. Composite hydrogel yarns combine these hydrogel properties with the unique adjustability and wearability of traditional yarns. Currently, the primary methods for preparing composite hydrogel yarns are impregnation and coating, which are simple but lack effective control over hydrogel thickness on the yarn surface.

      Method Using PA66 filaments as the core yarn and a polyvinyl alcohol and sodium alginate (PVA/SA) as nanofiber shell, with mass fractions of 12% and 3% respectively and a volume ratio of 9∶1, PVA/SA/PA66 nano core-spun yarns with varying shell layers (4, 8, 12, 16) were prepared via nano core-spun yarn technology. These nanofiber core-spun yarns were subjected to chemical crosslinking in a 4% calcium chloride saturated boric acid solution to obtain PVA/SA/PA66 composite hydrogel core-spun yarns. The yarn structure was characterized. Additionally, the droplet penetration rate, core absorption height, and saturated moisture content were tested.

      Results The cross-linking of PVA and SA with boric acid and calcium chloride were syudied. The characteristic peaks at 3 306 and 1 336 cm-1 correspond to the stretching and bending vibrations of —OH in PVA and SA. The characteristic peaks of SA appear at 1 720 and 1 097 cm-1, correspongding to the antisymmetric stretching vibration of —COOH and the stretching vibration of —C—O—C, respectively. After crosslinking, the four peaks show a significant reduction in strength, and the position of —C—O—C displays an obvious shift(from 1 097 to 1 105 cm-1), indicating that PVA and SA were crosslinked with boric acid and calcium chloride, respectively. The polarization microscope images reveal the "skin-core" structure of PVA/SA/PA66 composite hydrogel core-spun yarns, with light, transparent skin nanofibers and hydrogels, and dark PA66 filaments as the core. Layer thickness increases with the number of layers, but cross-linked yarns have thinner layers than uncross-linked ones. The scanning electron microscopy images of PVA/SA/PA66 core-spun yarns with different number of layers display that before crosslinking, nanofibers accumulate and interweave with decreasing pores as layers increase. After crosslinking, the "skin-core" structure and nanofiber morphology are maintained, and with the increase of the number of layers, the adhesion and entanglement of nanofibers are more obvious, but they are gel-like, and the nanofibers at the cross section are becoming smoother. Droplet penetration rate and core absorption velocity and height decrease with the number of layers after crosslinking, with 4 > 8 > 12 > 16 layers> PA66 filaments, and this is because as the number of layers increases, the internal structure of the yarns gradually tightens. The saturated moisture content results at 25 ℃ and 90% relative humidity indicate that when the number of layers increases, the gel content of the cortex increases, the hygroscopic capacity of the core-spun yarn increases, and the equilibrium hygroscopic capacity increases. However, after reaching a certain critical value, if the number of layers continues to increase, the exposed hydrophilic groups decrease and the contact probability with water molecules decreases. Thus, the equilibrium moisture absorption decreases. Specifically, the saturated moisture content of PA66 filaments is 0.07 g/g, 4, 8 and 16 layers is 0.23, 0.26 and 0.17 g/g, respectively, while the 12 layers yarn has a saturated moisture content of 0.29 g/g, which can reach 4 times that of the original filaments.

      Conclusion The yarns produced by nano core-spun yarn technology exhibit a distinct "skin-core" structure, with effectively regulated and directly proportional thickness of cortical nanofibers and hydrogels. As the layer number increases, the electrostatic spinning nanofibers of PVA/SA/PA66 core-spun yarns accumulate and interweave, reducing pores between nanofibers. After cross-linking, the nanofibers adhered and entangled, binding more tightly and reducing the thickness of the cortex. PVA/SA/PA66 composite hydrogel core-spun yarns with varying layer numbers show differences in morphology, structure, droplet penetration rate, core absorption velocity-height, and saturated moisture content at 25 ℃ and 90% relative humidity. Specifically, droplet penetration rate and core absorption velocity-height decrease with increasing layers, while saturated moisture content peaks at 4 to 16 layers, all higher than that of PA66 filaments. Considering preparation cycle and performance, the 8 layers yarn is optimal. In summary, PVA/SA/PA66 composite hydrogel core-spun yarns exhibit superior hydrophilic hygroscopic properties compared to PA66 filaments, expanding their application range to air-water collection, dehumidification, evaporation, and refrigeration.

      Process model and realization of fully formed protective head mask
      HONG Chuling, CONG Honglian, ZHAO Kezheng, LIU Bo, HE Haijun
      Journal of Textile Research. 2025, 46(06):  111-119.  doi:10.13475/j.fzxb.20241001201
      Abstract ( 87 )   HTML ( 6 )   PDF (5225KB) ( 40 )   Save
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      Objective This study aims to address critical issues in existing protective head masks, such as weak seam protection, poor fit, and discomfort caused by cutting and stitching processes. By proposing a seamlessly integrated manufacturing process utilizing four-needle bed fully-forming technology, seams are eliminated through three-dimensional integral knitting and optimize functional zoning. Targeting industrial manufacturing, outdoor extreme sports, and other scenarios requiring EN 388 Level 3-4 protection standards, a three-dimensional personalized parametric model is established of the head and neck of Asian adult males. Through the synergistic design of ultra-high molecular weight polyethylene (UHMWPE) materials and structural engineering, protective performance is enhanced while improving wear comfort, addressing the urgent demand for high-quality, advanced materials, eco-friendly processes, and personalized protective equipment.

      Method Based on GB/T 2428—2024 "Adult Head and Face Dimensions" and GB/T 23461—2009 "Adult Male Head 3D Dimensions", a parametric model of the human head and neck was constructed, and the four regions of the fully formed protective head mask were optimized and analyzed, which are the head fit forming region, eye opening forming region, breathable sandwich mask region, and neck and jaw dart forming region. The head fitting area was created by adopting a parabolic curve needle closing algorithm to obtain three-dimensional wrapping through gradient density control, and the eye opening area was achieved by combining C-shaped rib knitting and dynamic control of the yarn-feeder to form a smooth skeleton structure. The breathable mask area was constructed with a breathable sandwich through partial knitting technology, and the neck and jaw dart area were formed by adopting a three-step molding to ensure the precision of curved surface fitting. Shima Seiki MACH2X153 four-needle-bed computerized flatbed knitting machine with machine number E15 was used. In order to knit smoothly on the four-needle-bed computerized flatbed knitting machine and to make the fabric more elastic, two additional polyamide ammonia-covered yarns with specifications of 5.56 tex/2.22 tex were added in addition to 66.67 tex UHMWPE yarn for knitting to achieve the one-piece forming of the head mask. In order to evaluate the feasibility of UHMWPE in the knitting of the fully formed head mask and to verify the actual protective effect, as well as to ensure the practicality of the head mask, the cut resistance, tensile recovery and air permeability of the head mask were tested according to the standards of N 388:2016+A1:2018, FZ/T 70006—2004 and GB/T 5453—1997.

      Results The study demonstrated significant enhancements in the three-dimensional fit and functional performance of the head mask. In the head-fitting zone, precise control of narrowing points along a parabolic trajectory combined with a gradient narrowing process applied at longitudinal intervals was applied to successful replication of a rounded, parachute-like structure that conforms to the natural curvature of the human head. C-shaped rib knitting technology was utilized to form the eye-opening zone, with No.6 yarn feeder reciprocating across both sides of the opening to create smooth-edged openwork structures, with the width and curvature precisely matching the lateral canthus spacing and the oblique nasal-to-canthal distance. The breathable mask section was contoured through a partial knitting process that pauses on both sides while focusing on the central structure, combined with the independent operation of the needle bed and the regular movement of the yarn nozzle to complete the composite layer, thereby enhancing breathability and application potential. The neck and jaw dart were ensured through a three-step knitting process to achieve a precise three-dimensional fit in the neck and jaw area. Moreover, the introduction of UHMWPE brought the cut resistance index of the head mask to 0.99, further validating the feasibility of this material in the full-form knitting process. Test data show that the horizontal stretch recovery rate of the neck and jaw area reaches 54.27%, meeting the deformation recovery requirements during dynamic wearing. The breathability of the mask area reaches 827.9 mm/s, far exceeding the basic human respiratory requirement of 250 mm/s. These results confirm that the fully formed head mask has achieved the expected goals in terms of protective performance and practicality of wearing.

      Conclusion Combining the excellent protective performance of UHMWPE and the excellent full-forming process of four-knit and four-needle bed full-forming technology, the protective head mask is realized in one piece, which significantly improves the comfort and protective performance of the head mask. The fabricated fully formed protective head masks have good cut-resistant performance, appropriate tensile recovery, and breathability to meet human respiratory needs. The application of four-needle bed full-forming technology not only solves the cutting and sewing problems of traditional head masks but also provides a new idea for the design and production of protective head masks, and the selection of raw materials in this study also provides a reference for exploring the knitting forms of UHMWPE-based protective textiles. In the future, the knitting process can be further optimized to expand its application in special protective fields.

      Development and properties of deodorant sports socks
      TENG Yanfei, WAN Ailan
      Journal of Textile Research. 2025, 46(06):  120-126.  doi:10.13475/j.fzxb.20240406801
      Abstract ( 108 )   HTML ( 8 )   PDF (5231KB) ( 54 )   Save
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      Objective When exercising strenuously, the sweat glands in the soles of the feet secrete a lot of sweat. The microbiota of the feet decomposes sweat and proteins in the skin cuticle, resulting in organic volatile gases. Antimicrobial sports socks are commonly used in the market to solve the odor problem. However, antibacterial socks have a limited deodorizing effect, which only kill bacteria on the fabric and on the skin that clings to the fabric. For areas that the fabric cannot reach, the bacteria will still decompose secretions and produce odors, such as toes. Moreover, antimicrobial products can affect the microbiota of the feet, increasing the risk to human health from antibiotic-resistant strains. Therefore, it is necessary to develop sports socks with deodorant performance.

      Method In order to solve the odor problem of conventional sports socks after wearing, deodorant polyurethane filaments (DPUF) was used to prepare socks with plating stitch structure in this study. Nine samples with different plating yarn (polyamide fiber, Modal, cotton) and DPUF contents were knitted. DPUF was characterized by scanning electron microscopes and infrared spectrometer (FT-IR) for the morphology and chemical structure. Referring to GB/T 33610.2—2017 ″Textiles-Determination of Deodorant Property-Part 2: Detector Tube Method″, a deodorizing performance testing equipment was set up to evaluate the deodorizing and mechanical properties of DPUF and covered yarn. Deodorizing durability, sensory assessment, air and moisture permeability of socks were also tested.

      Results Deodorant rate detection device was set up to test the deodorant properties of DPUF and socks, and it was indicated that, compared with polyurethane filaments(PUF), the ammonia deodorization rate (ADR) of DPUF was increased by 85% and acetic acid deodorization rate (AADR) was increased by 66%. After the wrapping process, the ADR of DPUF/polyamide fiber covered yarn was reduced by 16% and AADR by 2%, and it still met the deodorization standard (≥70%). When the DPUF content was 0%, the ADR of polyamide fiber socks, Modal socks and cotton socks were between 40% and 65%, respectively. This showed that the yarn itself has a certain odor absorption capacity, but none of them met the deodorization standard (≥70%). When the DPUF content reached 4% level, the ADR of polyamide fiber socks, Modal socks and cotton socks were 72%, 83% and 90%, and the AADR were 77%, 83% and 88%, all of which reached the deodorization standard (≥70%), and the effect was still noticeable after laundering 30 times. For every 2% increase in DPUF content, the average ADR increased by 12.67% and AADR by 9.89%. When the DPUF content was 6% level, the ADR growth rates of polyamide fiber socks, Modal socks and cotton socks were 110.00%, 67.27% and 50.77%. The growth rates of AADR were 79.57%, 35.29% and 37.14%. Therefore, the application of DPUF in polyamide fiber socks had the highest growth rate of deodorant performance. Through sensory evaluation, the odor intensity level of deodorant polyamide fiber, Modal and cotton socks were 1, 0.5 and 0, respectively, which were 4, 2.5 and 1 odor levels lower than that of ordinary socks. The air permeability of deodorant socks was better than those of ordinary sports socks.

      Conclusion DPUF had good deodorant performance and DPUF/polyamide fiber covered yarn provided excellent deodorization, elasticity and abrasion resistance to socks. By using a small amount (≥4%) of DPUF, the deodorizing performance of sports socks were markedly improved. Moreover, the deodorization effect of DPUF was most significant when applied to polyamide fiber socks.

      Aging properties of acoustic-absorbing composites from palm fiber
      ZHANG Yi, SHEN Yin, GAO Jinxia, YU Chongwen
      Journal of Textile Research. 2025, 46(06):  127-134.  doi:10.13475/j.fzxb.20240706601
      Abstract ( 104 )   HTML ( 11 )   PDF (3861KB) ( 52 )   Save
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      Objective Since 2022, the production of jute-based acoustic-absorbing composite materials has declined due to reduced imports of raw jute materials. Automotive interior manufacturers are actively exploring new types of fibers that can either be blended with or partially replace jute in the production of acoustic materials. Through a comparative study on the aging properties of palm fiber acoustic-absorbing composites and widely used jute fiber acoustic interior panels in the market, this research further investigates the feasibility of substituting jute-based panels with palm fiber composites while improving the durability of such acoustic-absorbing interior components.

      Method Palm fiber felt/ceramic/poly(3-hydroxy-butyrate-co-3-hydroxy-valerate) (PHBV) acoustic-absorbing composite and jute fiber felt/PHBV acoustic-absorbing interior panels were studied under the natural light aging, hot-humid aging and ultraviolet light aging with the average values of tensile strength, bending strength, un-notched impact strength and sound absorption coefficient, bacteriostatic rate under natural light aging and hot-humid aging process. The water absorption rate and thickness-direction expansion rate of the acoustic-absorbing composite were analyzed. The lignin content, the composite's appearance change, the tensile section morphology and the chemical junction of the two fibers were tested under ultraviolet irradiation. The residual strength model was used to predict the mechanical properties under natural light aging.

      Results Under natural light aging process, the average values of tensile strength, bending strength, unnotched impact strength and acoustic absorbing coefficient of the two kinds of acoustic-absorbing composite materials decreased gradually with extended treatment time. The water absorption rate and thickness expansion rate of the two types of acoustic-absorbing composites increased rapidly with the increase of the humidity and heat temperature, but the bacteriostatic rate decreased rapidly. According to the water transport dynamics equation, for the palm acoustic composite material at 65 ℃, which could initially determine that it conformed to the Fickian water absorption model. With the increase of aging times under the ultraviolet light, the tensile strength, bending strength and unnotched impact strength all increased first and then decreased, and the mean value of acoustic-absorbing coefficient decreased gradually. The lignin content of the two fibers decreased with the increase of irradiation times. It had certain antibacterial effect on staphylococcus aureus and escherichia coli. At the same time, the surface of the two composite materials were discolored and cracks appeared, the appearance of the treated palm fiber acoustic-absorbing composite material became darker, and the surface became rough and uneven. Under the condition of 4 000-500 cm-1 band, there were five characteristic absorption peaks of palm fiber acoustic composite, which are 3 280, 1 731, 1 376, 1 158 and 709 cm-1. Among them, 3 280, 1 158 and 709 cm-1 were speculated as O—H bond vibration, C—O ether bond stretching vibration and C—H group vibration after degradation of PHBV. The residual strength model was used to predict the tensile strength and bending strength under natural light process. After 1 095 d (3 a), the tensile strength and bending strength of the material was 24.97 MPa and 44.93 MPa respectively. After 1 825 days (5 a), the tensile strength was 22.51 MPa and the bending strength was 41.94 MPa.

      Conclusion Under the natural light aging, hot-humid aging and ultraviolet light aging, the palm acoustic composite could replace the jute acoustic interior panel completely. The water absorption rate and thickness expansion rate of the composite increased with the increase of temperature and tended to balance in the later stage. The decrease of fiber lignin content was an important reason for the degradation of properties of ultraviolet light aging composites. According to the residual strength model, under the natural light aging process, the tensile strength and bending strength of the palm acoustic absorbing composite material after 1 095 d and 1 825 d could also reach the tensile strength and bending strength of the standard specified in QC/T 906—2013 ″Technical Requirements and Test Methods for Bast Fiber Composite Panels for Automotive Interior Parts″.

      Research on content-based interactive fabric image recommendation
      MING Yuhao, ZHANG Ning, XIANG Jun, PAN Ruru
      Journal of Textile Research. 2025, 46(06):  135-142.  doi:10.13475/j.fzxb.20240600501
      Abstract ( 116 )   HTML ( 8 )   PDF (8885KB) ( 52 )   Save
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      Objective With rapid development of textile industry, the types of fabrics are increasingly diversified. Facing a huge fabric library, it is difficult for the traditional retrieval method to carry out accurate search particularly when the user needs are not defined clearly enough. The popularity of e-commerce platforms has promoted the application of recommendation algorithms. The main idea of recommendation algorithms is to proactively recommend relevant content that users may be interested in by analyzing their preferences. Therefore, this paper proposes a content-based interactive fabric image recommendation algorithm, which considers the color and texture characteristics of the fabric based on the user's interest, aiming to accurately capture the user's preference, recommend the fabric for the user's needs, and provide certain reference value for the research of personalized fabric recommendation algorithms.

      Method This research considers the visual features such as fabric color and texture, and links the user's preferences with the characteristics of fabric, and proposes a content-based interactive fabric image recommendation algorithm. First, the main color set of the image is extracted from HSV color space, and the fabric texture is classified using the transfer learning algorithm based on ResNet18 network model. On this basis, an interactive feature preference recommendation model is established. The model calculates the interest value of each feature attribute according to the user's preference score for the fabric. Used to predict user ratings for potential fabrics. The 9 fabrics with the highest rating are recommended to the user, and the performance of the recommendation model is evaluated according to the user's rating for the recommendation results.

      Results The obtained data set was divided into training set, verification set and test set according to the ratio of 8∶1∶1. In this paper, the transfer learning algorithm based on the ResNet18 network model was used to classify fabric textures, and the highest accuracy of the test set was 0.936. It is shown that the ResNet18 network model has a good performance for fabric image texture classification. According to the rating preferences of 30 testers for the 9 recommended fabrics, the average score of these 30 users is above 5.5 points, in line with the range of 4-7 points (generally interested), and most of the scores gather in the range of 7-10 points (very interested), among which 19 people have an average score of more than 8 points, and 4 people have an average score of more than 9 points. The percentage of users who are very interested in the recommendation results as a whole is as high as 93.3%, among which 18 users score at least 7 of the 9 recommended fabrics above 8 points, which indicates that the overall performance of the recommendation model proposed in this paper is good.

      Conclusion In view of the fact that traditional recommendation algorithms fail to consider the influence of visual features of fabric on users' interest in fabric recommendation, this paper classifies fabric color and texture based on hand-extracted features and higher-order features respectively. Experimental results show that the transfer learning algorithm based on ResNet18 network model has achieved good results in fabric texture classification. The highest accuracy of the test set reached 0.936. Subsequent experiments will continuously optimize the accuracy and reduce the impact of classification errors on the recommendation results. In this paper, an interactive feature preference recommendation model is established by means of interactive scoring. The model calculates the interest value of each feature attribute according to the user's preference rating, so as to predict the user's rating on potential fabrics, and then recommend fabric images with high predictive ratings for users. Users' preferences for the recommendation results can be used as a standard to evaluate the performance of the recommendation model. The experimental results show that most users are satisfied with the recommendation results, which indicates that the overall performance of the recommendation model proposed in this paper is good, and it can capture users' interests and preferences more accurately, providing certain reference value for fabric image recommendation.

      Textile manufacturing carbon emissions analysis method based on holographic process model
      GAO Jun, BAO Jinsong, ZHANG Dan
      Journal of Textile Research. 2025, 46(06):  143-150.  doi:10.13475/j.fzxb.20240706901
      Abstract ( 117 )   HTML ( 3 )   PDF (4992KB) ( 31 )   Save
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      Objective Textile manufacturing is reported to be the most energy-intensive in the entire lifecycle, and is associated to high energy consumption. However, existing methods to carbon emissions analysis in textile manufacturing focus on temporal dynamics while not adequately addressing the importance of critical factors like material circulation and energy usage. Therefore, it is essential to fully utilize neglected information in order to conduct a multi-perspective carbon emissions analysis of textile manufacturing.

      Method To enable accurate carbon emissions analysis, this paper proposed a carbon emissions analysis method based on a holographic process model (HPM). The system boundary in the textile manufacturing was defined as the first step, followed by an analysis of the characteristics related to carbon emissions. A HPM based on the objective/centric petri net (OCPN) was constructed to simulate three different in the textile manufacturing of polyester-cotton blended fabrics.The constructed HPM was utilized to achieve a multi-perspective analysis of carbon emissions, and the feasibility of the method was verified using the polyester/cotton fabric production data from a textile enterprise.

      Results By extracting and processing textile manufacturing data, a thorough dataset for the HPM was compiled. Utilizing the OCPM mining tool, the HPM was constructed and used to simulate actual textile manufacturing. By using the established HPM, it was possible to carry out carbon emissions analysis from three perspectives, i.e., entire process, each procedure, and influencing factors. From the perspective of the entire process, product 2(a standard polyester/cotton blended fabric) showed the lowest average carbon footprint at 4.74 kg CO2e/kg, while product 3(a dark-colored polyester/cotton blended fabric) demonstrated the highest at 8.48 kg CO2e/kg, nearly double that of product 2. Product 1(a light-colored polyester/cotton blended fabric) showed an average carbon footprint of 7.58 kg CO2e/kg. From the perspective of each procedure, dyeing process was found to be the stage with the largest percentage of carbon emissions in the production of various fabrics. Carbon emissions from dyeing accounted for 50%-55% of the total energy consumption, with differences varying by product. From the perspective of influencing factors, the carbon emissions generated by the electricity consumed in fabric production showed the highest proportion, around 50%. After conducting an accurate carbon emissions analysis, a series of targeted clean production strategies were developed. Both product 1 and product 3 were fabrics in dark color, and the carbon emissions from the dyeing process accounted for a high proportion, nearly 55%. By implementing a single-step dyeing process for these two products, reducing the number of dyeing cycles, the carbon emissions were reduced by 20% while ensuring product quality. Compared to the traditional production process, the carbon emissions of product 1 decreased by 77 537.15 kg CO2e, and the carbon emissions of product 3 decreased by 62 724.42 kg CO2e. For product 2, a light-colored fabric, carbon emissions were decreased by streamlining unnecessary processes and reducing equipment downtime, which improved energy efficiency. The carbon emissions of product 2 decreased by 17 278.61 kg CO2e, representing a reduction rate of 10%.

      Conclusion This paper proposed a carbon emission analysis method based on HPM. This method first defined the system boundary in the textile manufacturing and analyzed the characteristics of carbon emissions. Subsequently, HPM based on OCPN was constructed to simulate the textile manufacturing process. Furthermore, the constructed HPM has been utilized to achieve a multi-perspective analysis of carbon emissions. This method was applied to a textile enterprise, and the feasibility of the method was verified using production data of polyester/cotton fabrics from three different scenarios. The results show that HPM outperforms traditional process model based on petri net. And proposed method is conducive to an all-encompassing carbon emissions analysis in textile manufacturing, offering robust support for the eco-transition of textile enterprises. Future work will focus on expanding the application scope of the holographic process model to accommodate a wider variety of textile manufacturing processes.

      Dyeing and Finishing Engineering
      Yak wool decolorization using homogeneous advanced oxidation technology and its mechanism
      WEI Xuanxiang, FENG Yang, FAN Xiangyu, WU Minghua, YU Deyou
      Journal of Textile Research. 2025, 46(06):  151-159.  doi:10.13475/j.fzxb.20241103201
      Abstract ( 101 )   HTML ( 3 )   PDF (7346KB) ( 49 )   Save
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      Objective The yak wool fibers are inherent in colors primarily including black, purple and brown, failing to meet the demand for multi-color varieties for applications. Hence, the fibers need to be bleached prior to dyeing with target colors. However, the traditional bleaching process has limitations in oxidant selection and elusive mechanism remained in conventional yak wool decolorization. Herein, the bleaching capacity and environmental impact of homogeneous advanced oxidation processes with three typical oxidants were compared. Meanwhile, the mechanism of hydrogen peroxide(H2O2)-driven efficient decolorization was also investigated.

      Method Inspired by the homogeneous advanced oxidation technology for organic pollutants degradation, a comparative study was conducted to examine the effects of three typical oxidants H2O2, peracetic acid (PAA), and potassium peroxymonosulfate (PMS) on decolorization of yak wool fibers using ferrous sulfate as the catalyst. Using the whiteness index and breaking strength as evaluation indicators, the most suitable oxidant was identified and the decolorization parameters were optimized. The reactive oxygen species were identified and analyzed using the electron spin resonance(EPR) technology and quenching experiment. Finally, the environmental impact of the decolorization process was assessed via the life cycle assessment (LCA).

      Results The results of single-factor experiments indicated that hydrogen peroxide is the most suitable green oxidizing agent for decolorizing yak wool. The optimal decolorization conditions were determined to be an H2O2 concentration of 25 g/L, a temperature of 60 ℃, and a solution pH value of 8.5. Under these conditions, the whiteness of yak wool fibers reached up to 68%, with a fiber breaking strength loss of approximately 12%. Mechanistic analysis of the H2O2 decolorization process revealed the presence of hydroxyl radicals (·OH) and singlet oxygen (1O2) in the system. Further quenching experiments demonstrated that ·OH and 1O2 are the main reactive oxygen species responsible for decolorization, with ·OH playing the primary role and 1O2 having a secondary effect. Scanning electron microscope images revealed that yak wool fibers treated with H2O2 or PAA for decolorization exhibited surface damage, including roughened cuticle scales and unclear scale edges. Fibers treated with PMS showed even more severe damage, with cuticle scales becoming indistinct or completely detached in some areas. LCA results showed that the PMS decolorization process had the highest environmental impacts on global warming potential, terrestrial ecotoxicity, non-carcinogenic human toxicity, and fossil resource scarcity, while both PMS and PAA decolorization processes had significant negative impacts on environmental ecology and human health. Therefore, compared to the other two oxidants, decolorization using H2O2 was more environmental-friendly and low-carbon.

      Conclusion Inspired by the advantages of the homogeneous advanced oxidation technology for organic pollutants degradation, three typical oxidants including hydrogen peroxide, peracetic acid, and hydrogen persulfate were screened and compared for yak wool fiber decolorization using ferrous sulfate as the catalyst. The results revealed that hydrogen peroxide is the most suitable oxidizing agent for practice. The optimal decolorization condition was identified to be H2O2 concentration of 25 g/L, temperature of 60 ℃, and solution pH value of 8.5. After being decolorized by hydrogen peroxide, the whiteness of yak wool fibers reached 68%, and the loss of strength was relatively small. The decolorization mechanism of hydrogen peroxide bleaching system showed that both the hydroxyl radical and singlet oxygen contributed to the yak wool fiber decolorization, in which hydroxyl radical played the primary role and singlet oxygen served a secondary function. Life cycle assessment showed that, compared to PMS and peracetic acid, the use of H2O2 for decolorization had the lowest environmental impact, which aligns better with the green and low-carbon development trend for yak wool decolorization processes.

      Synthesis and properties of novel porous dispersed dye composite nanospheres
      ZHANG Shuai, WANG Jinkun, FANG Kuanjun, MA Junzhi, SONG Yan
      Journal of Textile Research. 2025, 46(06):  160-167.  doi:10.13475/j.fzxb.20240901601
      Abstract ( 102 )   HTML ( 6 )   PDF (4878KB) ( 50 )   Save
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      Objective Disperse dye/polymer nanospheres, as an emerging class of nanopigments, exhibit superior self-curing capabilities and demonstrate broad applicability in dyeing both hydrophilic and hydrophobic textiles. To address the challenge of low dye loading capacity in conventional systems, this study reports on the synthesis of composite nanospheres using novel internally porous polymer nanospheres as carriers. These were subsequently employed to construct vibrant hydrophobic coatings on cotton fabric surfaces.

      Method The morphological and physicochemical properties of porous composite nanospheres were systematically analyzed through transmission electron microscopy, X-ray photoelectron spectro-scopy (XPS), and differential scanning calorimetry. Furthermore, the surface morphology, chromatic characteristics (quantified by K/S values), and hydrophobicity (evaluated via contact angle measurements) of coated cotton fabrics were investigated to elucidate the influence of coating layer numbers on performance enhancement.

      Results Analysis of porous poly(styrene-butyl acrylate-acrylic acid) (PSBA) nanospheres revealed a direct correlation between toluene volume and pore architecture. While increasing toluene volume enlarged the internal pore size, pore size uniformity deteriorated significantly when the volume exceeded 10 mL. Dye adsorption studies demonstrated that Disperse Red 60 and Blue 60 loading capacities were maximized at intermediate pore sizes, with adsorption levels inversely linked to pore structural heterogeneity. Spectroscopic characterization confirmed successful dye incorporation. Distinct FT-IR absorption bands at 3 451, 3 298, and 1 270 cm-1 corresponded to amine, hydroxyl, and aryl ether functionalities, while XPS detected nitrogen signatures from dye molecules. Thermal analysis identified a glass transition temperature of 94.5 ℃ for disperse dye/porous poly(styrene-butyl acrylate-acrylic acid) (DPSBA) nanospheres, enabling effective film formation upon heating. Coating layer optimization studies revealed that increased spray layers enhanced film continuity on cotton fibers, with elevated curing temperatures further promoting structural consolidation. Hydrophobicity progressively improved with coating layers, achieving a maximum contact angle of 139.2°. Additionally, coated fabrics exhibited robust mechanical durability, with dry/wet rubbing fastness grades of 4-5 and 4, respectively, alongside a sunlight fastness grade of 7-8.

      Conclusion This work successfully engineered internally porous disperse dye composite nanospheres and implemented ultrasonic spraying to fabricate multifunctional hydrophobic coatings on cotton textiles. The toluene volume serves as a critical modulator of PSBA nanosphere pore morphology, enabling tunable dye adsorption capacities. DPSBA nanospheres exhibit autonomous film-forming behavior, generating uniform coatings through thermal curing. The chromatic intensity and hydrophobicity scale positively with coating layers, achieving optimal performance at five-layer deposition. The resultant coatings demonstrate exceptional fastness properties, meeting practical durability requirements. This approach provides a sustainable pathway for expanding disperse dye applications in textile functionalization.

      Preparation and properties of flame retardant polyacrylonitrile filament fabrics by layer-by-layer self-assembly method
      DING Yuan, ZHAO Yunxia, JIN Gaoling, YANG Tao, XU Jing, KE Fuyou, CHEN Ye
      Journal of Textile Research. 2025, 46(06):  168-177.  doi:10.13475/j.fzxb.20241201101
      Abstract ( 130 )   HTML ( 10 )   PDF (11486KB) ( 16 )   Save
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      Objective Polyacrylonitrile (PAN), is widely used in high-value-added applications, particularly in the development of domestically produced PAN filaments for the shielding covering layer of cable core materials. Cables are predominantly installed in buildings and densely populated areas, making them vulnerable to fire caused by factors such as increased loads, wire short-circuiting, and other electrical faults. During combustion, toxic gases, including hydrogen cyanide (HCN) and carbon monoxide (CO), are released, posing significant risks to human life and property safety. Consequently, enhancing the flame retardant properties of PAN filament fabrics has become a critical research focus in the industry.

      Method In order to obtain the environmentally friendly flame retardancy of PAN fabrics, flame retardant polyacrylonitrile filament fabrics were prepared by using PAN filament fabrics as the substrate and constructing on it a ternary self-assembled flame retardant system using phytic acid (PA)/polyethyleneimine (PEI)/3-aminopropyltriethoxysilane (APTES), adopting the layer-by-layer self-assembly method. The surface morphology and macromolecular structure of the flame retardant modified fabrics, as well as their thermal stability and flame retardant properties were investigated.

      Results The results showed that after self-assembly of PA/PEI/APTES layers, the flame retardant elements such as phosphorus (P), nitrogen (N) and silicon (Si) were effectively introduced on the surface of the PAN fabric, whereas the untreated PAN fabric had only the presence of C, N and O elements on its surface. The new P element was added on the surface of PAN-PEI fabrics, and the P content was increased to 8.81%, and the H2PO4/PO4 characteristic peaks at 133.8 eV were observed after self-assembly. The characteristic signal of Si element appeared in the XPS spectra when increasing APTES from 1.0% to 3.0%. The characteristic peak of H2PO4/PO4 was also observed. After further introduction of APTES, the Si element was increased from 1.13% to 3.78% when increasing APTES concentration from 1.0% to 3.0%, while the N and P elements were slightly decreased. The residual carbon of the fabrics before and after flame-retardant modification increased from 0 to 13.1% at 900 ℃, the limiting oxygen index (LOI) of the fabrics increased from 17.4% to 27.5%, the sustained ignition and negative ignition time of the fabrics reached 0 s. The total smoke release was decreased by 63.6% from 1.1 to 0.4 m2, and the heat release rate was reduced by 18.9%. The fabrics exhibited excellent performance after PA/PEI/APTES alternating assembly.

      Conclusion A ternary flame retardant system of PA/PEI/APTES was constructed using layer-by-layer self-assembly technology, and the flame retardant polyacrylonitrile filament fabrics were successfully prepared, which is expected to be applied to shielding wrapping layers of internal cores of cables as well as to some application environments that do not need to be washed. Compared with the untreated PAN fabrics, the self-assembled flame retardant modified fabrics showed an increase in LOI value from 17.4% to 27.5%, a decrease in the maximum value of heat release rate by 18.9%, and a decrease in the total smoke release by 63.6%, which demonstrated that the flame retardant and smoke inhibition properties of the flame retardant modified fabrics were greatly improved.

      Preparation of Fe-Co bimetallic organic framework/rice husk composite material and its performance in dye decolorization
      XIANG Wenlong, YANG Jingran, XIAO Xiaozhen
      Journal of Textile Research. 2025, 46(06):  178-186.  doi:10.13475/j.fzxb.20241000601
      Abstract ( 120 )   HTML ( 12 )   PDF (3971KB) ( 20 )   Save
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      Objective With the progression of the global textile industry, a substantial quantity of wastewater containing toxic and non-biodegradable synthetic dyes may impose considerable threats to public health and the environment. Peroxymonosulfate (PMS)-based advanced oxidation processes have garnered significant attention in the remediation of organic dye wastewater because of their high degradation efficiency and non-selective oxidation. As promising catalysts for PMS activation, metal-organic frameworks (MOFs) often face limitations because of particle agglomeration and challenges in recovery during liquid-phase reactions, attributed to their powdery nature. Therefore, constructing macroscopic structures from powdered MOFs is highly significant for expanding their practical applications.

      Method FeCo-benzenedicarboxylate/rice husk (FeCo-BDC/RH) composite material was fabricated via solvothermal in-situ growth strategy. The morphology and structure of FeCo-BDC/RH were analyzed by scanning electron microscopy, X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), and X-ray photoelectron spectroscopy (XPS). The decolorization performance of the composite material for activating PMS on Rhodamine B (RhB) was evaluated, and the key active species in the decolorization process were revealed through quenching experiments and electron paramagnetic resonance (EPR) spectroscopy.

      Results The scanning electron microscopy images confirmed that the FeCo-BDC, which was grown in-situ on the surface of RH, exhibited a highly dispersed state. This is significantly different from the spindle-shaped morphology of pure FeCo-BDC, thereby highlighting the importance of the carrier. Moreover, the composite material FeCo-BDC/RH was of centimeter-scale size and easily recovered from the liquid phase after the reaction. The analytical results of FT-IR, XPS, and XRD further confirmed the successful preparation of the FeCo-BDC/RH composite material. FeCo-BDC/RH was capable of efficiently activating PMS and facilitating rapid decolorization of RhB. The decolorization rate of RhB by the FeCo-BDC/RH+PMS system reached as high as 99% within 5 min. The FeCo-BDC/RH+PMS system demonstrated stable decolorization effects under various solution pH volues and natural water quality conditions and possesses universality for the decolorization of multiple dyes. In a fixed-bed reactor with a continuous reaction for 300 min, the decolorization rate of RhB by the FeCo-BDC/RH composite material remained nearly 100%, indicating the potential for large-scale continuous treatment of organic dye wastewater. The results of quenching experiments and EPR technology indicated that the degradation of RhB included both radical (S${O}_{4}^{-}$O4-·) and non-radical (1O2) pathways, with 1O2 being the dominant one. In addition, the results of the EPR spectra confirmed the existence of these key reactive oxygen species. The variable valence state of iron and cobalt metal sites plays an indispensable role in the process of activating PMS to generate these key species. The interaction between the bimetals accelerates the redox process of Fe(Ⅲ)/Fe(Ⅱ) and Co(Ⅲ)/Co(Ⅱ) through electron transfer between metals, thereby promoting the generation of reactive oxygen species.

      Conclusion The FeCo-BDC/RH composite catalyst was successfully prepared through the in-situ growth of FeCo-BDC on waste RH. This composite material demonstrated outstanding performance in activating PMS. The decolorization rate of the RhB dye reached 99% within just 5 min. Additionally, the FeCo-BDC/RH composite catalyst showed good recoverability and remarkable anti-interference ability in the face of different pH values and natural water matrices. The composite material demonstrated versatility in degrading a range of organic dyes and achieved continuous and efficient dye decolorization in a fixed-bed reactor. This study offers a low-cost waste biomass carrier for the construction of three-dimensional macroscopic structures of MOFs, thereby helping to lower the economic cost of wastewater treatment. The fabricated composite material significantly expands the potential for large-scale continuous treatment of organic dye wastewater.

      Apparel Engineering
      Optimization of trousers patterns for men with protruding abdomen based on three-dimensional fitting
      JI Mengqi, HE Ying, MA Yongqian
      Journal of Textile Research. 2025, 46(06):  187-195.  doi:10.13475/j.fzxb.20241103001
      Abstract ( 149 )   HTML ( 10 )   PDF (9826KB) ( 43 )   Save
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      Objective In order to solve the problem of insufficient fit of men's trousers with protruding abdomen, a method for optimizing the trousers patterns for this group of men is proposed with the purpose of optimizing the structure of men's pants and improving the fit and comfort of the trousers based on three-dimensional fitting technology. Parametric modeling of men's trousers patterns with CLO-3D technology for men with protruding abdomen was carried out. This parameter optimization design provides useful reference for the structural design of men's trousers with special body type in the production process.

      Method CLO-3D was used to construct seven virtual models with different waist sizes for men, and the regression analysis of waist circumference and critical circumference of lower limbs of men with abdominal obesity was carried out through model body surface standing cut and paper pattern fitting, and the method was verified through the virtual try-on experiments and real-life try-on experiments.

      Results By constructing a model with a protruding belly and performing surface draping and pattern fitting, it was observed that the contours of the front and back pieces change proportionally as the degree of the belly protrusion increases. Specifically, the front center point, back center point, and the circumference change at one-third of the front crotch depth (belly allowance) showed significant and balanced variations in circumference. The side waist points exhibited noticeable and proportional changes in height, while both the front and back center points displayed clear proportional changes in both circumference and height. Treating the front waist measurement as a dependent variable and the back waist measurement as an independent variable, the regression coefficient for the back waist measurement was solved, revealing a distribution ratio of 5∶4 between the front and back waist measurements. Using the hip measurement as the independent variable and six key adjustment parameters and four key structural parameters as dependent variables, regression analysis showed a significant linear relationship between these parameters and the hip measurement, with a high degree of fit for the regression model. Based on this, a total of six key regulating parameters and six key structural parameters were derived as the rules for the variation. Considering the characteristics of men's trousers structural design, the regression equations were appropriately simplified to derive optimization rules for men's suit trousers tailored to protruding bellies. Using CLO-3D software for virtual fitting of the optimized trouser patterns, the results indicated that the stress area on the front waist and abdomen, as well as the front hip, was reduced, with pressure values approaching 0 kPa, resulting in reduced pressure sensation and improved comfort. Static and dynamic fitting trials on real individuals with protruding bellies showed high evaluations from participants regarding comfort and aesthetics.

      Conclusion To address the issue of poor adaptability of men's suit trousers for individuals with protruding bellies, this study utilized three-dimensional virtual fitting technology to construct a model of a male with a severe protruding belly. Surface draping was employed to obtain the model's surface data, and through the analysis of two-dimensional pattern fitting, parametric optimization rules for men's suit trousers tailored to severe protruding bellies were established. The accuracy and feasibility of these optimization rules were verified through virtual fitting experiments and real-life fitting trials. The research content and results hold significant implications for shortening product production cycles, reducing energy consumption, and improving the accuracy and fit of pattern adjustments for suit trousers designed for individuals with protruding bellies.

      Research on movement comfort of clothing sleeve based on human kinetic theory
      YU Xiaokun, YI Ping, XIE Guanjing, CAI Lingxiao
      Journal of Textile Research. 2025, 46(06):  196-202.  doi:10.13475/j.fzxb.20240804701
      Abstract ( 158 )   HTML ( 14 )   PDF (4454KB) ( 58 )   Save
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      Objective The clothing structure design methods based on human kinetic theory proposed by Lindqvist can greatly improve the movement comfort of clothing. However, the principles of the methods are not yet clear and are failed to popularize and spread to use. This paper represents an attempt to explore the principles and ideas of its structural design, as well as the influencing mechanism on the improvement of clothing movement comfort, aiming to stimulate new ideas for movement comfort of clothing.

      Method The leisure suit designed by Lindqvist was taken as a control experimental sample. Through the step-by-step structural adjustment experiment, the sleeve was firstly separated from the whole piece of leisure suit template to obtain the sleeve structure of scheme 1, and then the unconventional one-piece sleeve was divided and reorganized into two-piece sleeve to obtain the sleeve structure of scheme 2. Subjects were recruited and were asked to evaluate subjectively the fit and movement comfort of the three sleeve structures through human wearing experiment to analyze the movement comfort of the three sleeve structures.

      Results The fit of the control experimental sample was found better than that of scheme 1 and scheme 2 in the whole garment, shoulder, armpit, elbow and back, and the former offered more suitable clothing tolerance. Compared with other parts, the mean score of fit of scheme 1 at the armpit and elbow is significantly higher than that of scheme 2, indicating that the way of sleeve dividing affects the fit of the sleeve and sleeve dividing following the direction of arm movement is better than the traditional two-piece sleeve dividing. When picking up luggage from a height, the comfort levels of shoulder joint and armpit are follows from the best to the worst: the control experimental sample, scheme 2, scheme 1. The bend of the sleeve elbow of scheme 1 is larger, so it is easier to pull the bottom of the sleeve than scheme 2 which is a two-piece sleeve divided by straight line when the arm raises upward nearly straight, resulting in shoulder and armpit pulling discomfort. The control suit exhibited the same elbow structure as scheme 1, but there is enough loose at sleeve bottom to meet the motion of the arm elevation. When making a phone call or looking at a watch, the comfort levels of each part are as follows from the best to the worst: control experimental sample, scheme 1,scheme 2. The two-piece sleeve of scheme 2 which has approximately straight dividing line is not set enough slack at elbow. When the arm is bent, the sleeve presses the elbow and pulls the fabric at the bottom of sleeve, causing discomfort at elbow and armpit. The dividing line of scheme 1 follows the direction of arm movement and the elbow is set with enough loose, so its comfort of elbow and armpit is better than scheme 2. The sleeve structure of control experimental sample is the same as that of scheme 1, but its one-piece structure makes the armpit looser and more comfortable. When shaking hands and carrying things, the range of arm movement is small and the amount of active tolerance required in each part is also small. The subjects scored more than three points on the comfort of each part. The binding degree of the three sleeve structures is lower in the three parts. However, it could still be seen that the comfort level of the control experimental sample is better among the three sleeve structures.

      Conclusion In summary, the movement comfort of the sleeve structure based on the principle of human kinetic is obviously better than that of the traditional two-piece sleeve structure. There are following two main reasons. First, the sleeve is connected to the back body as a one-piece structure, so there is no armhole line under back arm and there is a suitable amount of fabric accumulation for arm movement, providing movement slack for back shoulder and armpit. Second, dividing line of the sleeve is in line with the direction the arm moves. The forward angle of the formed sleeve is larger than the forward angle of the arm in the natural state. At the same time, a flexible allowance is set at the elbow. In addition, the fabric is oblique in the sleeve, so the sleeve has better ductility at underarm and elbow when the arm extends and bents. Then, the above two aspects can be combined to adjust the structural design of two-piece sleeves in order to obtain new sleeve structure with better movement comfort.

      Cross-pose virtual try-on based on improved appearance flow network
      LUO Ruiqi, CHANG Dashun, HU Xinrong, LIANG Jinxing, PENG Tao, CHEN Jia, LI Li
      Journal of Textile Research. 2025, 46(06):  203-211.  doi:10.13475/j.fzxb.20241200401
      Abstract ( 124 )   HTML ( 6 )   PDF (10576KB) ( 23 )   Save
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      Objective Current research on virtual try-on predominantly focuses on single garments under simple poses, with its efficacy heavily reliant on frontal garment images, thereby limiting practical applications. In contrast, cross-pose virtual try-on demonstrates enhanced practical applicability by transferring complete outfits to target individuals, yet faces substantial challenges in achieving optimal results due to distortions caused by pose variations and garment complexities. To address the issue of suboptimal cross-pose virtual try-on performance under challenging poses, this paper proposes an improved global appearance flow network to achieve enhanced cross-pose virtual try-on technology.

      Method First, a Co-Attention attention module is introduced to optimize the global style vector, guiding the modulated convolutional network in estimating the global appearance flow. Next, a channel attention mechanism is employed to enhance the clothing feature information, effectively reducing information loss during cross-pose try-on. Finally, deformable convolutions replace traditional convolutions in the global appearance flow optimization module, improving the global appearance flow and better preserving clothing details.

      Results Quantitative experimental results on the DeepFashion dataset show that the model proposed in this paper significantly outperforms the baseline model in two key indicators, i.e., structural similarity index Measure (SSIM) and frechet inception distance (FID). Specifically, the SSIM value is increased by approximately 4.8%, indicating a higher similarity in structural features between the generated images and the real images. Meanwhile, the FID value is increased by 23.5%, further validating that the distribution features of the generated images are closer to those of the real images. Qualitative experimental results on the DeepFashion dataset show that compared to CoCosNet, CT-Net and FS-VTON models, CoCosNet and CT-Net do not incorporate global information, making them face significant challenges when dealing with model images that only contain local regions. As a result, they often generate unrealistic clothing. Moreover, due to the inability of TPS to handle large deformations, CT-Net generated images contain numerous artifacts. Although FS-VTON incorporates global information, it performs poorly in handling local clothing deformations. The proposed model can reasonably estimate clothing warping in cross-posture scenarios by combining the global and local information.

      Conclusion This paper proposes an improved appearance flow prediction network aimed at enhancing the realism and practicality of virtual try-on systems, thereby creating more possibilities and opportunities for the fashion industry and e-commerce. By introducing a Co-Attention module to optimize global style feature vectors, the network is better equipped to handle large-scale deformations during virtual try-on. Additionally, the integration of deformable convolutions in the local refinement network for appearance flow further enhances the network's ability to preserve clothing details. Extensive experiments on the DeepFashion dataset demonstrate that the proposed method significantly outperforms other approaches. Although the model proposed in this paper has achieved relatively satisfactory experimental results, there is still room for optimization. In the future, research on the virtual try-on for high-resolution images can be carried out, and data of outdoor scenes can be added to the dataset. In addition, the model can be further improved to make it independent of parsers and enable end-to-end training, thereby promoting the industrial application of the model.

      Machinery & Equipment
      Hierarchical positioning method for wireless signal clustering in winding machine assembly workshops
      DING Siyi, TONG Huihui, MAO Xinhua, ZHANG Jie
      Journal of Textile Research. 2025, 46(06):  212-222.  doi:10.13475/j.fzxb.20240606801
      Abstract ( 100 )   HTML ( 4 )   PDF (4285KB) ( 16 )   Save
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      Objective The objective of this research is to develop an efficient and accurate positioning method tailored for the complex environment of winding machine assembly workshops. These workshops present unique challenges due to their large size, intricate layouts, and the high precision required for the accurate placement and movement of materials and equipment. Effective positioning is crucial for optimizing production processes, improving resource allocation, and reducing operational costs. Traditional positioning methods have certain limitations: for instance, global positioning system has low positioning accuracy in indoor environments, while other methods (such as infrared or ultra-wideband (UWB)) can provide higher precision but are costly to deploy and complex to maintain. Therefore, this study selects wireless networks(WiFi) as the foundational positioning technology, as its signals are widely distributed in indoor environments, possess strong penetration capabilities, and offer a more cost-effective and deployable solution compared to other approaches. This research aims to develop a hierarchical positioning method based on WiFi to meet the specific needs of winding machine assembly workshops.

      Method The proposed method integrates three key algorithms, i.e., the XGBoost classification model, the K-means clustering algorithm, and the weighted K-nearest neighbors (WKNN) algorithm. The methodology is divided into several stages. ① Analysis of wireless network environment. A thorough analysis of the wireless network environment in the assembly workshop is conducted to understand its characteristics and specific positioning requirements. ② Initial fingerprint database construction. The workshop is divided into functional areas, such as assembly, testing, and processing zones. Reference points are strategically placed throughout these areas, and the received signal strength indicator (RSSI) values are collected to create an initial fingerprint database. ③ Clustering and database refinement: K-means clustering is used to segment the fingerprint database into smaller, more manageable clusters. This step ensures that the RSSI data within each cluster are more homogeneous, improving the accuracy of subsequent localization steps. ④ Model training. The XGBoost classification model is trained using the refined fingerprint database. This model is responsible for coarse localization, identifying the sub-region where the target is located. ⑤ Fine localization. Within the identified sub-region, the WKNN algorithm is applied to achieve precise positioning. This two-tiered approach, combining coarse and fine localization, enhances both the accuracy and efficiency of the positioning process.

      Results The proposed hierarchical WiFi positioning method was evaluated in a simulated workshop environment. The experimental results demonstrate significant improvements in both positioning accuracy and efficiency compared to traditional methods. Specifically, the method achieves a 143.82% improvement in positioning accuracy over conventional WKNN algorithms, with the average positioning error reduced to 0.89 m. Additionally, the average positioning time is shortened to 2.76 ms. Detailed performance metrics, including average positioning errors and cumulative distribution functions (CDF) for various algorithms, highlight the advantages of the proposed method. For instance, when positioning error thresholds are set at 3 m, the proposed method achieves a 100% success rate, significantly outperforming other methods such as RF and unclustered hierarchical algorithms. These results underscore the method's effectiveness in complex and dynamic workshop environments.

      Conclusion This study introduces a novel WiFi-based hierarchical positioning algorithm specifically designed for the winding machine assembly workshop environment. By integrating XGBoost, K-means, and WKNN algorithms, the proposed method significantly enhances positioning accuracy and system performance. The hierarchical approach not only improves precision but also reduces the computational load, making real-time positioning feasible in large-scale industrial settings. The improvements in positioning precision and efficiency are particularly beneficial for industrial applications, where accurate and timely location data are critical for optimizing operations and ensuring safety. Future research should focus on testing the algorithm in more varied and complex real-world environments to further validate its robustness. Additionally, strategies to mitigate the impact of environmental changes on positioning accuracy should be explored. A comprehensive cost-benefit analysis of implementing this system in actual industrial settings would also provide valuable insights for practical deployment. Overall, this research contributes to the advancement of wireless network positioning technologies, offering a practical and efficient solution for the challenges faced in winding machine assembly workshops. The proposed method aligns with the goals of Industry 4.0, supporting the transition towards smarter, more automated manufacturing processes.

      Key control technology for breakpoint fabric continuity in full-width warp knitting for extracorporeal membrane oxygenation
      WANG Han, ZHANG Qi, LIU Dong, SONG Jinlong, XI Lifeng, HAO Jiashu, PENG Shiyu, LI Kunlei, ZHANG Chao
      Journal of Textile Research. 2025, 46(06):  223-230.  doi:10.13475/j.fzxb.20240703201
      Abstract ( 101 )   HTML ( 4 )   PDF (4801KB) ( 10 )   Save
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      Objective Accidental power loss during the warp knitting of a full-width fabric with weft lining for high-value materials of extracorporeal membrane oxygenation (ECMO) could lead to formation of defective cloth and the loss of high valued raw materials. This research deals with this problem to eliminate the fabric discontinuity so as to maintain highquality of such important fabrics.

      Method Using the absolute coordinate mode of the servo motor and the slave axis electronic cam profile, the physical position information at the cam follower breakpoint was reverse-calculated. This position information was then used to identify the motion sequence intervals of the respective slave axes coordinating with the weft insertion mechanism. Subsequently, transition curves for each cam were designed using the key point data of the electronic cam. Finally, by utilizing cam table data streams, these transition curves were coupled with and switched to the original electronic cam curves, achieving accurate continuation of weaving from the breakpoint.

      Results Experimental validation was carried out using a KSM2/1EL full-width warp knitting machine as the structural foundation, furnished with 7 servo-driven electronic weft insertion sub-shafts, each specifically dedicating to driving individual weft insertion devices. The machine was used for end uses such as the production of ECMO membrane wire materials. The contemporary full-width warp knitting system employed in this machine integrated the key ECMO membrane full-width weft insertion system breakpoint continuation control technology mentioned previously. Once the control system was powered on, the servo initialization module successively memorized the positions of the 7 electronic weft insertion servo master and slave axes in absolute coordinate mode. Each weft insertion axis was engineered with specific electronic weft insertion action phase intervals, and the positions of the master and slave axes at the breakpoint within the cam curve intervals were ascertained. This was accomplished by employing a weft insertion breakpoint recovery algorithm to sequentially restore on-site data. The KSM2/1EL full-width warp knitting machine was operated at a low speed for the experiment. The main shaft was halted at random positions, resulting in the cessation of the weft insertion mechanism with electrical drive. After the system was shut down until all energy was exhausted, it was restarted and the main shaft was gradually operated once again. Through the process of breakpoint continuation and multiple tests involving power interruptions at various weft insertion points, as well as extensive production sampling and application testing, it was verified that the motion system effectively resumes weaving oxygenation membrane fabric from any arbitrary position after power interruptions. The weft insertion mechanism smoothly coordinated with the movement to accomplish the insertion process. This verification confirmed that the motion system of the KSM2/1EL full-width warp knitting machine can reliably solve the problem of power-off reweaving of oxygenation membrane fabrics in various operating environments, demonstrating its capabilities in both experimental and production scenarios.

      Conclusion The application of the absolute coordinate encoder mode of servo motor is proven to be the key to complete the physical information data recovery of the breakpoint continuation of the weft liner control system. The electronic computer-aided manufacturing(CAM) curve period of the weft laying system is the necessary information in the process of back pushing data, and the physical position information can be reversed when the power is interrupted by the application of the two. It is imperative to design the motion partition of the weft laying mechanism according to the motion time sequence requirements of the warp knitting spindle (chain) weft laying mechanism and the warp knitting slave axis (weft laying trolley, rake needle, side slip, etc.). The motion interval of the weft laying break point is reversely identified according to the physical position information of the main and slave axes at the break point. The data of the key point of the CAM is used to design the CAM transition curve of the algorithm. Finally, the transition curve and the original CAM curve are coupled and switched by the CAM table data flow application to realize the breakpoint continuous weaving of oxygenation membrane material.

      Broken yarn detection on warp beam zone of sizing machine based on machine vision
      XU Lunyou, ZOU Kun, WU Haonan
      Journal of Textile Research. 2025, 46(06):  231-239.  doi:10.13475/j.fzxb.20240504701
      Abstract ( 139 )   HTML ( 6 )   PDF (6764KB) ( 39 )   Save
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      Objective Sizing is one of the key processes before weaving in the textile industry, and it requires the use of a sizing machine. During the process of sizing, the yarn on the warp beam of the sizing machine often breaks, leading to yarn accumulation and wastage. Currently, inspections for broken yarn on the warp beam zone of sizing machines predominantly rely on manual patrols, which suffer from poor timeliness and low efficiency. To address this issue, an algorithm was proposed in this research for detecting broken yarn faults in the warp beam zone of sizing machines based on machine vision.

      Method By analyzing the image features captured by the cameras, an algorithm for determining the parameters of image recognition was investigated based on the theory of vanishing points, comprising an automatic vanishing point extraction algorithm, a warp roller axis calibration algorithm, and an automatic region of interest (ROI) selection algorithm. With the determined parameters of image recognition, the original images captured by the cameras was preprocessed, followed by edge detection and ellipse fitting. Subsequently, by assessing the positional relationship between the fitted ellipse and the top and bottom edges of the yarn roller, the recognition of broken yarn faults in the warp beam region was achieved.

      Results The results demonstrated the significant effectiveness of the image recognition algorithm based on the theory of the vanishing point. Firstly, the automatic vanishing point extraction algorithm, using exhaustive search, successfully and consistently identified the vanishing point within a coordinate variation range of 5 pixels, ensuring the accuracy of subsequent analysis. Secondly, the vanishing point-centerline calibration method improved the accuracy of the axle-centerline identification by addressing the deviation issue of the dual-ellipse centerline method, providing a crucial geometric reference for broken yarn detection. Additionally, by utilizing the vanishing point information, the automatic selection algorithm for the ROI could accurately partition the ROI region that varies with the roller even in cases of smaller roller radius and increased background interference, enhancing the robustness of the algorithm. Based on the comprehensive algorithm mentioned above, the broken yarn detection algorithm performed edge detection on the preprocessed image and used ellipse fitting to fit the contour of the formed protruding circular white yarn loop. The relationship between the fitted ellipse and the roller edge lines was used to determine broken yarn faults, and the algorithm accurately identified the intersection points between the fitted ellipse and the upper and lower roller edge lines, showing good performance in detecting broken yarn faults in the middle and end sections. The detection algorithm took approximately 700 to 800 ms to process a single image. By concurrently processing images from multiple cameras, the time required to handle multiple images was significantly reduced. Experimental results indicated a 0.91 accuracy of the detection algorithm.

      Conclusion Practical application shows that under most normal conditions in the sizing production process, the broken yarn fault identification algorithm for the warp beam zone can accurately and promptly detect broken yarn issues and trigger the corresponding alarms, meeting the needs of the project and actual industrial production. This detection system has been applied in relevant textile enterprises, confirming its feasibility.

      Comprehensive Review
      Research progress in alginate-based nonwoven medical dressings
      WANG Huiting, CHEN Yujian, LIU Shiyi, ZHANG Xiantao, LU Bin, ZOU Zhuanyong, WANG Jian, ZHANG Yinjiang
      Journal of Textile Research. 2025, 46(06):  240-249.  doi:10.13475/j.fzxb.20241000302
      Abstract ( 131 )   HTML ( 9 )   PDF (13714KB) ( 36 )   Save
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      Significance With the increasing of the aged population, common diseases such as bedsores and diabetic ulcers are seen more frequently, and market demand for new medical dressings effective in dealing with such problems is increasing. Traditional or single functional medical dressings are difficult to meet the needs of the public. Alginate is widely used for manufacturing medical dressings because of its good biocompatibility, hemostatic and bacteriostatic properties. Nonwoven materials can be processed in a wide range, and the material is soft, breathable and comfortable, suitable for use in medical dressing substrates. Therefore, alginate-based nonwoven medical dressings play an increasingly important role in the treatment of wound bedsores and body surface ulcers.

      Progress As a natural polymer polysaccharide, alginate has many carboxylic and hydroxyl groups and is suitable for ion exchange and functional modification. Meanwhile, it has good biocompatibility and degradability, which makes it show great potential in the application field of medical dressing. The nonwoven material has simple preparation process, soft, breathable and comfortable, and is suitable for medical dressing. At present, alginate-based nonwoven dressings can be roughly divided into pure alginate fiber dressings, alginate fiber and other fiber mixed dressings, alginate finishing modified dressings and alginate nanofiber nonwoven dressings. The preparation methods mainly include spinning (electrospinning, microfluidic spinning, centrifugal spinning), carding and strengthening (needling, spunlace), finishing and compound methods. The alginate-based nonwoven dressing has great hemostatic ability, but has insufficient antibacterial ability, which can be modified by alginate derivative or add antibacterial agents to solve the problem in the future. Secondly, the use of diverse nonwoven substrate structures for medical dressings can effectively improve wound healing. Thirdly, materials with specific functions are added to give alginate-based nonwoven medical dressings corresponding functions, expand the application range of medical dressings, and achieve intelligentization of the dressings. The development of multi-functional intelligent dressings (anti-seawater immersion, great water vapor transmission rate, improving immunity, monitoring wound pH value changes, reducing scars, moistening sores, promoting blood coagulation) is an important future development direction. As a new medical dressing, alginate-based nonwoven medical dressing has a favorable development prospect.

      Conclusion and Prospect At present, there are many types of alginate-based nonwoven medical dressings associated with various preparation methods. The new multi-functional and integrated alginate-based nonwoven medical dressings are the development direction of medical dressings. In the future, it should actively search for natural antibacterial agents or other new antibacterial agents with wide sources and great non-toxic bacteriostatic performance, or modify alginate to strengthen bacteriostatic performance. The structural design of the innovative alginate-based nonwoven medical dressing achieves the most suitable wound healing environment and maximizes patient convenience. At the same time, by adding specific functional components to medical dressings, the dressings have special functions and realize intelligence on the basis of basic functions, and meet the needs of special wounds.

      Technical research progress in functional speed skating suits
      SHI Jia, LI Mengzhu, XIAO Boxiang
      Journal of Textile Research. 2025, 46(06):  250-260.  doi:10.13475/j.fzxb.20241201802
      Abstract ( 96 )   HTML ( 5 )   PDF (7504KB) ( 30 )   Save
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      Significance Short-track and long-track speed skating is an important winter sports with strong competitive and ornamental value. As an important racing equipment, the professional speed skating suits have been supported by many high technologies in interdisciplinary fields such as aerodynamics, materials science, textile science, sports science, physiology, psychology, computer science and technology. Scientifically and reasonablly engineered sport suits are helpful to reduce exercise resistance, optimize technical movements, avoid muscle damage, improve exercise efficiency, and play an important role in promoting athletes' capability. The skating suits provide both sports and aesthetic artistic effects to athletes and spectators. In the past three or four decades, many studies have been conducted with both academic and industrial perspectives. With the popularization of speed skating, more and more professional athletes and ordinary enthusiasts are drawn into this sport. The requirement of professional speed skating suits has increased in past years. In order to clarify the functional characteristics and design requirements of professional speed skating clothing, and promote the professional application and development of speed skating functional clothing design and manufacturing, it is very important to systematically investigate and summarize the current status and development trends in technical research on speed skating suits.

      Progress As a professional sport equipment, speed skating suits use a lot of professional technical support. Dozens of research reports over the past 40 years were searched and retrieved and highly relevant literatures were selected. The important progresses in the research fields of speed skating suit design, production, and functional testing are made mainly in aerodynamic characteristics and resistance reduction, safety protection and cutting resistance, sports comfort and physiology, sports biomechanics, and clothing design and prototype production. The aerodynamic characteristics i.e., resistance reduction is the first design aim for speed skating suit, and this is because for high-level athletes, besides their own training and physical functions, reducing resistance is the most effective way to improve competition performance. This field attracted many famous and highly productive researchers, and the representative achievements include the mechanism of resistance formation in speed skating, techniques and processes for reducing resistance, as well as equipment and standardized experimental procedures and evaluation standards. The speed in speed skating is generally 13-16 m/s, and its aerodynamic characteristics have significant impacts on sliding speed and energy consumption. Research on the aerodynamic characteristics of speed skating started in the early 1980s. A large amount of research has been carried out on the aerodynamic characteristics of speed skating suits, and relatively mature theoretical and technical systems have been formed, mainly using wind tunnel simulation experiments and computational fluid dynamics (CFD) simulation calculations. In addition to the frictional resistance on the ice surface, the air resistance in speed skating mainly includes the pressure difference resistance and surface frictional resistance. The main ways to reduce resistance include using new fabrics with special surface roughness structures, vortex generators and other auxiliary devices, as well as optimized template structures and dividing line designs. Safety protection is another important design goal, especially for short track speed skating where there is a huge risk of injury to athletes during sliding.

      Conclusion and Prospect This paper provides a comprehensive review on investigation and analysis of the technological progress related to functional clothing for speed skating. Based on the functional requirements of speed skating and speed skating suits, the design elements of speed skating suits are discussed from five aspects: resistance reduction, protection, comfort, sports assistance, and appearance design. Furthermore, the research achievements and technological progress in the field of speed skating suit technology are summarized and analyzed, with focus on resistance reduction technology, fabric performance, structure, and pattern design. The research has led to the following progress. ① Drag reduction remains the main goal of speed skating and speed skating suit design research, and it continue to attach researchers'attention. The wind tunnel test and CFD simulation calculation mode for resistance reduction testing are basically mature, gradually forming standardized experimental testing processes and evaluation standards. The research focus is mainly on the development of new materials and new processes. ② New fabrics and textiles will play an increasingly important role, involving interdisciplinary design innovations in new materials, yarns, structures, and processes, as well as their applications in the field of functional clothing for speed skating, reflecting improvements in physiological indicators such as resistance reduction performance, comfort, physical and mechanical properties. ③ Clothing structure design and template generation technology, including exterior pattern design, will attract more attention to achieving standardization, digitization, and automation of the design and production process on the basis of meeting the personalized needs of athletes, and adapt to the new large-scale personalized customization production mode. ④ Emerging digital and artificial intelligence technologies would further empower the design and production process of speed skating suits. Based on big data on body shape and design, as well as generative artificial intelligence, artificial intelligence will play an important role in the new generation of interactive design patterns and intelligent manufacturing systems, thereby generating innovative growth points and driving forces. Intelligent development of personalized speed skating suit samples for athletes is an effective method to meet the functional requirements of speed skating suits. Taking into account resistance reduction, fabric performance, and personalized needs, achieving quantitative calculation and digital generation of speed skating suit samples is an inevitable development trend that can effectively improve the effectiveness and efficiency of pattern making.