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    15 August 2025, Volume 46 Issue 08
        
    • Fiber Materials
      Preparation and properties of collagen-based corneal repair materials reinforced with modified silk protein fibers
      GAO Wenyu, CHEN Cheng, XI Xiaowei, DENG Linhong, LIU Yang
      Journal of Textile Research. 2025, 46(08):  1-9.  doi:10.13475/j.fzxb.20240907301
      Abstract ( 240 )   HTML ( 54 )   PDF (9234KB) ( 225 )   Save
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      Objective Corneal repair materials refer to artificial or biological substitutes designed to restore damaged corneal tissue. An ideal corneal repair material must exhibit excellent biocompatibility, mechanical stability, and optimal optical characteristics. Current research indicates that while pure collagen-based scaffolds demonstrate promising biological properties, they often suffer from inadequate mechanical strength. Although this limitation can be partially addressed by incorporating polymeric components, such modifications may compromise other critical parameters, including optical clarity and controlled degradation behavior. To address these challenges, the present study proposes the use of natural silk fibroin(SF) fibers as functional reinforcing elements. This approach is expected to provide innovative solutions for the development of advanced collagen-based corneal repair materials with balanced performance characteristics.

      Method This study first carboxylated natural silk fibroin(CSF) fibers and then introduced it into collagen(Col) system. Col-CSF composite scaffold with "reinforced concrete" structure was successfully prepared by chemical crosslinking of 1-ethyl-(3-dimethylaminopropyl) carbodiimide hydrochloride (EDC) and n-hydroxysuccinimide (NHS). Through precisely designed chemical modification strategies, we aim to achieve molecular-level integration and synergistic interaction between silk fibroin and collagen molecules.

      Results The infrared spectra showed that the C—H telescopic vibrational absorption peak appeared at 2 930 cm-1 after carboxylation treatment was weakened compared with that of the filipin protein, and the telescopic vibrational absorption peak of C══O appeared at 1 730 cm-1, and the characteristic absorption peak of C—O—C appeared at 1 160 cm-1, indicating that modified silk fibroin had been prepared. In the blended film, the N—H stretching vibration absorption peak gradually approached from 3 310 cm-1 to 3 280 cm-1. It showed that hydrogen bond was formed between two macromolecules in the blended film, leading to redshift of absorption band. After the addition of CSF, the tensile strength as well as the elongation at break of the films reached (12.66±0.11) MPa and (49.80±0.52)%, respectively, which were significantly higher than that of the pure collagen material. Compared with SF, CSF has more —COOH and provides more cross-linking sites for the material, thus increasing the steric hindrance effect of the fiber molecular conformational change. The plots of water absorption, specific surface area change, and thickness change of the three films demonstrated that the Col-CSF film had higher water absorption (93.6 ± 0.9)% and CSF was with more —COOH, and the interaction between —COOH and collagen —NH2 led to an increase in the degree of cross-linking, which promotes water absorption. Transmittance was taken as one of the key parameters for evaluating the performance of corneal repair materials and it played an important role in assessing the compatibility between the molecules of the blends. It showed that the light transmittance of all materials increased with the increase of wavelength, which was similar to that of human natural corneal tissue. It is worth noting that the maximum transmittance of Col-SF was more than 80%, while the maximum transmittance of Col-CSF reached 95%. Col-CSF fibers with better ordered arrangement effectively improved the light transmittance, and the samples exhibited good optical properties on a macroscopic scale as a result. In addition, Col-CSF also showed good biocompatibility, which is favorable for cell growth, adhesion and proliferation on it.

      Conclusion In this study, filipin protein was carboxylated and dispersed in a collagen hydrogel system. The two were chemically crosslinked using EDC/NHS to form a composite scaffold with a reinforced concrete structure. The experimental results showed that the saturated water content of the target material was (93.6±0.9)% and the light transmittance was up to 95%, which were similar to or higher than that of the natural cornea. It was also found that the addition of CSF significantly enhanced the mechanical properties of the material, with the tensile strength and elongation at break reaching (12.66±0.11)MPa and (49.80±0.52)%, respectively, which endowed the material with stronger operability and stability. In addition to this, in vitro cellular experiments showed that the composites had good cytocompatibility, with corneal epithelial cells(HCECs) being able to adhere, proliferate and rapidly cover the entire material surface. Therefore, the artificial corneal repair materials with good biocompatibility and light transmission properties prepared in this study provide a new strategy to improve corneal injury and reduce corneal blindness, and have potential future applications in the field of corneal repair engineering.

      Preparation and mechanical properties of collagen-based fibers employing metal-polyphenol networks
      LIANG Feng, FANG Yan, ZHANG Weihua, TANG Yuling, LI Shuangyang, ZHOU Jianfei, SHI Bi
      Journal of Textile Research. 2025, 46(08):  10-17.  doi:10.13475/j.fzxb.20241004301
      Abstract ( 126 )   HTML ( 21 )   PDF (7146KB) ( 105 )   Save
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      Objective The textile industry generates a large amount of textile waste every year, which seriously pollutes the environment, and its overreliance on petroleum-based fibers, which are difficult to biodegrade, limits the sustainable development of the textile industry. Therefore, the development of durable and high-performance fibers with a circular economy effect is of great significance for the sustainable development of the textile industry.

      Method In this research, collagen-based composite fibers with excellent mechanical properties were successfully prepared by blending collagen with biodegradable poly(vinyl alcohol) (PVA) co-spinning, combined with the introduction of metal-polyphenol network (MPN) to construct a metal-ligand-hydrogen-bonded double crosslinked network.

      Results The results showed that when the n(TA)∶n(Al3+) molar ratio was 3∶1, the MPN assembly reduced the zeta potential from -2.83 mV to -38.58 mV, and the system stability was optimal. Infrared spectroscopy analysis indicated that the incorporation of MPN effectively cross-linked collagen with poly(vinyl alcohol) through the synergistic effect of metal-ligand bonding and hydrogen bonding. X-ray diffraction and small angle X-ray scattering/wide-angle X-ray scattering analyses showed that the MPN introduction improved the crystallinity and orientation of the composite fibers. When the MPN addition was 6%, the tensile strength of the composite fibers reached 243 MPa, and the protein retention rate was doubled.

      Conclusion Co-spinning of collagen with biodegradable PVA and the simultaneous introduction of metal-polyphenol network for the preparation of composite fibers can significantly improve the mechanical properties and protein retention rate of collagen-based composite fibers, which opens up a new way for the high-value utilisation of tannery waste and the sustainable development of the textile industry.

      Surface properties of polyimide fiber coated with modified epoxy resin
      LIU Xudong, SONG Zhengji, CHEN Shichang, CHEN Wenxing
      Journal of Textile Research. 2025, 46(08):  18-27.  doi:10.13475/j.fzxb.20241002901
      Abstract ( 115 )   HTML ( 26 )   PDF (13346KB) ( 110 )   Save
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      Objective Polyimide (PI) fibers are widely used in aerospace, military protection, and other special fields due to their excellent high temperature resistance, mechanical strength, and chemical stability. However, its shortcomings such as smooth surface and insufficient abrasion resistance limit its long-term performance in extreme environments. In order to improve the surface wear resistance of PI fiber materials and enhance their applicability in special environments such as high temperature and high friction, the present study innovatively adopts the method of grafting epoxy resin with silane coupling agent to functionalize the surface of PI fibers, with a view to significantly improving their surface wear resistance characteristics while maintaining their original excellent properties.

      Method The surface of PI fibers was hyperbranched by the chemical modification scheme of silane coupling agent (3-isocyanatopropyltrimethoxysilane, IPTMS) grafted with epoxy resin (EP), and hyperbranched-modified epoxy resin-polymide(HPS-EA-PI) fibers with high surface roughness and excellent abrasion-resistant properties were prepared. The effects of alkaline treatment concentration and treatment time on fiber surface activity were systematically investigated, and the concentration gradient of IPTMS modifier was optimized. The chemical structure, surface morphology and roughness of the fibers before and after modification were characterized by Fourier transform infrared spectroscopy, scanning electron microscopy and atomic force microscopy. The mechanical properties, thermal stability and wear resistance were evaluated by universal material testing machine, thermogravimetric analyzer and friction and wear testing machine, respectively.

      Results Surface activation treatment results were analysed. When treated with 4 mol/L NaOH solution for 5 min, the carboxyl group content on the fiber surface increased significantly, providing an ideal active site for the subsequent silane coupling agent grafting. Roughness evolution analysis revealed that with the increase of IPTMS concentration for 0%, 25%, 50%, 75% and 100%, the roughness of the modified fibers was enhanced by 104%, and SEM showed that the coating was successfully applied on the fiber surface. HPS-EA-PI fibers prepared under the optimal process (75% IPTMS) maintained the original mechanical properties and thermal stability while the abrasion resistance was improved by 190% compared with the unmodified sample. XPS confirmed the formation of Si—O—C bonds, indicating that the epoxy resin formed a solid chemical bond with the PI fibers via silane coupling agent, which was the key factor for the performance enhancement.

      Conclusion The epoxy resin/silane coupling agent hyperbranching modification technology developed in this study successfully optimized the synergistic "strength-toughness-wear resistance" of PI fibers by precisely regulating the chemical composition and microscopic morphology of the fiber surface. The prepared HPS-EA-PI fibers show significantly better service performance than traditional PI fibers in extreme environments, and their surface modification strategy provides a new idea for the functional design of high-performance polymer fibers, which has an important application prospect in the fields of spacecraft thermal protection system and special protective clothing. It is suggested that follow-up studies should focus on the long-term durability performance of the modified fibers under simulated real-world working conditions.

      Optimization of preparation technology for polyethylene terephthalate-based carbom dots and its application in polyamide 66
      MA Chaohui, CUI Tongran, BING Linhan, ZHU Zhiguo, WANG Rui, WEI Jianfei
      Journal of Textile Research. 2025, 46(08):  28-36.  doi:10.13475/j.fzxb.20241101401
      Abstract ( 96 )   HTML ( 12 )   PDF (8836KB) ( 70 )   Save
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      Objective Carbon dots (CDs) are a sort of zero-dimensional fluorescent nanomaterials that can be widely utilized across various fields due to their excellent biocompatibility and biosecurity. Research has demonstrated that carbon dots possess significant potential as flame retardants, but the current methods for preparing carbon dots are still limited to laboratory-scale production and have not yet achieved large-scale manufacturing. This limitation poses challenges for their application in flame retardant formulations that require substantial quantities. The objective of this study is to explore a method that not only enables the efficient recycling of waste but also facilitates the flame retardant modification of polyamide 66(PA66).

      Method In this study, polyethylene terephthalate (PET) carbon dots (PET-CDs) were synthesized using a hydrothermal method with PET oligomers, urea, and phosphomolybdic acid (PMA) as precursors. The optimal synthesis conditions were determined through orthogonal experiments, which allowed for the optimization of reaction temperature, reaction time, and loading volume. A series of characterization tests were conducted on the prepared carbon dots, including optical and morphological assessments. Additionally, CDs-PA66 was created by blending PET-CDs with PA66, and the thermal stability, flame retardancy, and combustion properties of CDs-PA66 were evaluated. The influence of PET-CDs on fluorescence anti-counterfeiting and fingerprint recognition was also investigated.

      Results Using PET oligomer, urea, and PMA as precursors, the optimal process conditions were determined to be 3 g of PET oligomer, 5 g of PMA, 4 g of urea, and 15 mL of H2O. The reaction was conducted in a drying oven at 260 ℃ for 18 h. It is observed that the loading volume had minimal impact on the fluorescence intensity of PET carbon dots (PET-CDs), which was prepared in a 5 L kettle in equal proportions. PET-CDs were characterized using a fluorescence spectrometer, among other techniques, and the results indicate that PET-CDs exhibited no dependence on the excitation wavelength. The optimal excitation wavelength was found to be 410 nm, while the optimal emission wavelength was 485 nm, resulting in a fluorescence quantum yield of 70.78%. PET-CDs possess a spherical structure with an average particle size of 1.37 nm and a lattice spacing of 0.25 nm. The surface of the particles was rich in functional groups, including hydroxyl groups. When PET-CDs were utilized for the flame retardant modification of PA66, with an addition of 4% PET-CDs, the limiting oxygen index indicating a refractory level reached 28%. Additionally, the combustion time following the initial flame ignition decreased significantly from 188.7 s to 5.2 s. The fluorescence of PET-CDs can be specifically quenched by Fe3+, allowing for the quantitative detection of Fe3+ through the linear relationship between the degree of quenching of PET-CDs and the concentration of Fe3+ within the range of 0.00 to 10 μmol/L. Furthermore, fluorescent inks containing PET-CDs produced patterns that was invisible under natural light but become visible under ultraviolet light, demonstrating their anti-counterfeiting capabilities. Starch containing 1.5% PET-CDs can also be employed for fingerprint identification.

      Conclusion PET oligomer, urea, and PMA serve as precursors with excellent fluorescence properties and a high fluorescence quantum yield. These materials can be utilized in PA66 flame retardants, fluorescent anti-counterfeiting applications, and fingerprint recognition technologies.

      Preparation and performance study of copolymerized polyimide nanofiber membrane
      JIA Lin, YANG Aojie, ZHANG Fangcheng, WANG Xixian, ZHANG Haixia
      Journal of Textile Research. 2025, 46(08):  37-44.  doi:10.13475/j.fzxb.20240903301
      Abstract ( 110 )   HTML ( 29 )   PDF (10112KB) ( 75 )   Save
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      Objective As the industrialization process continues, human activities such as transportation, industry, and power plants emit large amounts of air pollutants. Particulate matter pollution was the main air pollution problem. Direct filtration of particulate matter at the emission source is considered the most effective method. Polyimide (PI) is one type of polymer possessing imide ring structure, good thermal stability, high heat resistance, and its products are characterized by high strength and high modulus, radiation resistance, corrosion resistance. It is an ideal polymer appliled in high temperature air filtration. Copolymerized PI can be obtained by two-step method by using two dianhydrides or two diamines to react in polar solvent. It can change the molecular structure, intersegment force and crystallinity of PI, which is a modification method of PI. In this paper, copolymerized PI nanofibrous membranes with higher tensile property and filtration performance were prepared through electrospinning technology.

      Method Rigid monomer p-phenylenediamine (PPDA) was introduced and dissolved into dimethylaceta-mide (DMAc) with 4,4'-diaminodiphenyl ether (ODA) and homophenyltetramethylanhydride (PMDA), to prepare polyamide acid (PAA) solution. The copolymerized PI nanofiber membranes with different molar ratio of PPDA were prepared by electrospinning and thermoimide treatment. The fiber morphologies, chemical group, tensile property, and filtration performance were characterised and analyzed through scanning electron microscope, Fourier infrared spectrometer, fiber tensile instrument and automatic filter detector.

      Results The diameter of PI10∶0 nanofibers without PPDA was smaller, with an average diameter of 579.65 nm, and the fiber diameter distribution was relatively uniform. The introduction of PPDA into ODA and PMDA promoted the rigidity of polyamide acid (PAA) molecular, and increased the viscosity of PAA solution. The diameter of copolymerized PI nanofibers with PPDA were relatively larger, with an diameter range of 645.38-1 050.31 nm. When the molar ratio of PPDA were larger, the fiber diameter distributions of PI7∶3 and PI6∶4 nanofibers became uneven, especially in the case of PI6∶4 nanofibers. the smallest fiber diameter was 207.35 nm, while the coarsest fiber diameter was 1 739.09 nm. This is mainly because that PAA molecular chain was relatively rigid when the molar ratio of PPDA were higher. The stretching force on the jet during electrospinning were not uniform, resulting in uneven distribution of fiber diameter. The FT-IR of PAA and PI nanofibers expressed that PAA nanofibers showed characteristic C—N stretching and vibration peak and C═O vibration absorption peak at 1 403 cm-1 and 1 625 cm-1.Compared to PAA nanofibers, PI nanofibers with different PPDA molar ration all expressed characteristic symmetric contraction vibration peak of aromatic imide C═O at 1 776 cm-1 and 1 723 cm-1, these results indicated that all PAA nanofiber were transformed into PI nanofiber films after thermal imide treatment. The stretching curves of all PI nanofiber films were consistent with the stretching of the fiber assembly, and the curves showed three stages. The first stage was the elongation of the fiber, the second stage was the elongation of the fiber macromolecular chain, and finally the fiber slipped-off and fractured, their stretching phenomenon were similar to that of other randomly arranged nanofiber membranes. Comparing the tensile curves of different PI nanofiber films, the PI10∶0 nanofiber membrane without rigid monomer PPDA had the smallest tensile strength (4.91 MPa) and the largest fracture elongation (60.5%). In contrast, the tensile strength of the copolymerized PI nanofibers increased significantly, while the fracture elongation decreased slightly, and the tensile strength of PI nanofibers increased with the increase of PPDA mole fraction. When the molar ratio of PPDA was 30%, the maximum tensile strength of PI7∶3 nanofiber membrane was 8.65 MPa, mainly because the addition of PPDA increased the rigidity of the PAA molecular chain, resulting in the improvement of the mechanical properties of copolymerized PI nanofibers. The filtration performance under the flow rate of 32 L/min and 85 L/min were tested. At the flow rate of 32 L/min, the filtration efficiencies of different PI nanofiber membranes ranged from 98.56% to 99.86%, and the resistance pressure drops ranged from 143 Pa to 185.6 Pa. When the mole ratio of ODA to PPDA was 8∶2, the filtration efficiency of PI8∶2 nanofiber film was the highest, reaching 99.86% and the resistance pressure drop reaching 185.3 Pa. Compared the filtration performance of PI nanofibers at different flow rates, it can be seen that the filtration efficiencies at different flow rates were very close, but the resistance pressure drops were quite different. The resistance pressure drops at the flow rate of 85 L/min were significantly higher than that at the flow rate of 32 L/min.This was mainly because the increase in flow rate can cause particles to collide with the nanofiber membrane quickly and fiercely. Blocking particles through the nanofiber membranes resulted in a significant increase in pressure drop.

      Conclusion The copolymerized polyimide (PI) nanofiber membranes were prepared by introducing rigid monomer p-phenylenediamine (PPDA), using two-step method and electrospinning technology. The copolymerized PI nanofiber membranes possessed higher fiber diameter, increased tensile strength and filteration performance, had better application in the field of high temperature filtration materials.

      Design of porous and crosslinked nanofiber-based supercapacitor separator
      SHI Hu, WANG He, WANG Hongjie, PAN Xianmiao
      Journal of Textile Research. 2025, 46(08):  45-52.  doi:10.13475/j.fzxb.20241001501
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      Objective As a key component of supercapacitors, the separator's main function is to prevent direct contact between the positive and negative electrodes, avoid short circuits, and ensure the safe and stable operation of supercapacitors. The separator also plays a role in providing a transport channel for electrolyte ions in supercapacitors, which facilitates the rapid movement of ions and improves the charging and discharging efficiency and performance of supercapacitors. The performance of the separator directly affects the cycle life, charge and discharge performance, energy density, and power density of supercapacitors. However, in practical applications, nanofiber-based supercapacitor separators still face the following problems. It's difficult to balance ion permeability and mechanical strength. Costs are increased while improving the performance of fiber membranes. It's difficult to meet environmental adaptability and durability requirements in specific applications. Therefore, the development of polyacrylonitrile (PAN) nanofiber-based supercapacitor separator materials with low cost and high performance is of great research significance.

      Method Porous and crosslinked electrospun nanofibers were prepared using polyacrylonitrile, high amylose starch, and polyvinylpyrrolidone (PVP) as precursors followed by water dissolution and glutaraldehyde cross-linking treatment. PVP dissolves in water to form a porous structure, while glutaraldehyde crosslinks with starch to form a bonding structure within fibers. During electrospinning, the voltage, distance, extrusion speed, and rotary speed were set as 15 kV, 15 cm, 1.0 mL/h, and 250 r/min, respectively. The electrospun nanofibers were immersed in deionized water for 5 h under room temperature. Then, the treated nanofibers were placed in a vacuum reactor and crosslinked in glutaraldehyde vapor for 5 h to obtain a porous and crosslinked nanofiber membrane.

      Results It was found that the addition of starch and glutaraldehyde crosslinking had a great effect on the morphologies of nanofibers. After adding a certain amount of starch and crosslinking with glutaraldehyde, obvious bonding points appeared at the fiber intersections, with the increase of starch content, the average fiber diameter increased from 290 nm to 310 nm. For the blended nanofiber membrane, all characteristic absorption peaks of the three polymers PAN, starch, and PVP were observed on its FT-IR curve. The above results prove the successful preparation of ternary polymer nanofibers. As the temperature increased, none of the five samples showed shrinkage, and the original square size was maintained even when the temperature was raised to 200 ℃. The results demonstrate that the prepared nanofiber membrane exhibits excellent heat stability, providing a guarantee for the subsequent application of supercapacitor separators. After adding starch and performing vacuum glutaraldehyde cross-linking treatment on the fiber membrane, bonding points were formed between the fibers to reinforce the fiber network, resulting in an increase in the tensile strength and thickness of the fiber membrane. With the addition of PVP and starch, the contact angle of the fiber membrane decreased, further improving the hydrophilicity of the fiber membrane. With an increase in starch content, the hydrophilic properties of the fiber membrane were improved, resulting in more complete dissolution of PVP. However, excessive starch content and cross-linking led to a further decrease in porosity. The supercapacitor device was prepared using nanofiber membrane as separator and tested under cyclic voltammetry and galvanostatic charge-discharge in a two-electrode system. Under a current density of 0.25 A/g, the specific capacitance of device was 25.72 F/g, retaining 47.1% at a high current density of 2 A/g. In addition, after 5 000 charge and discharge cycles, the capacitance retention rate was as high as 96.22%, showing excellent cycle durability.

      Conclusion After adding PVP, the fiber membrane thickness decreased to 0.03 mm, resulting in a decrease in tensile strength to 8.15 MPa. Addition of starch improved, the effect of PVP on the tensile strength of the fiber membrane, and with the increase of starch content, the contact angle of the fiber membrane decreased, indicating improvement the hydrophilic performance. By sequentially dissolving in water and crosslinking with glutaraldehyde, the thickness of the fiber membrane was decreased from 0.15 mm to 0.12 mm, while its tensile strength increased from 9.22 MPa to 11.86 MPa. When m(PAN)∶m(starch)∶m(PVP)=5∶4∶1 (mass ratio), the fiber membrane had a high porosity (88.02%). The assembled supercapacitor had a specific capacitance of 25.72 F/g at a current density of 0.25 A/g, an energy density of 3.57 W·h/kg at a power density of 124.45 W/kg, and a specific capacitance retention rate of 96.22% after 5 000 charge discharge cycles, demonstrating potential applications in supercapacitor separator materials.

      Study on crystallization kinetics of titanium polyester for industrial yarns
      JIANG Tingguo, KUANG Jun, SI Hu, ZHANG Yumei, CHEN Ye, WANG Huaping
      Journal of Textile Research. 2025, 46(08):  53-61.  doi:10.13475/j.fzxb.20241104401
      Abstract ( 72 )   HTML ( 13 )   PDF (6554KB) ( 17 )   Save
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      Objective In this paper, two crystallization kinetics were used to analyze the crystallization behavior of titanium and antimony series high viscosity polyesters, and the effects of different catalytic systems on the crystallinity of high viscosity polyester chips were discussed. The differences and improvement measures of titanium polyester industrial yarn in production and other aspects compared with antimony polyester industrial yarn were deduced, and the application of titanium polyester industrial yarn in related fields was finally expanded.

      Method The thermal stability of polyester chips for industrial yarns was characterized by thermogravimetry and differential scanning, and the crystallization performance of the chips was tested by combining XRD with differential scanning. In addition, the isothermal crystallization and non-isothermal crystallization tests were carried out by differential scanning calorimeter, and the Avrami equation was used to analyze and fit them.ResultsThrough the thermal stability test, it was found that polyester chips catalyzed by titanium and antimony for industrial yarns had only one weight loss step, and the initial decomposition temperatures of the two were very close. The crystallization performance test was characterized by the combination of differential scanning and XRD. Both differential scanning and XRD showed that the crystallinity of the titanium system was higher than that of the antimony system. In addition, in terms of differential scanning, the cooling crystallization peak of the titanium system is narrower and sharper than that of the antimony system, which preliminarily proves that the crystallization rate of the titanium system is faster. In the XRD test, there were four crystal planes (0,-1,1), (0,1,0), (-1,1,0), (1,0,0), which proves that there is no significant difference between the crystal plane structure and the conventional polyester. From the perspective of slicing, the production of industrial yarns was only related to its own intrinsic viscosity. In the isothermal crystallization test, as the temperature continues to increase, the crystallization peak continued to shift to the right and the peak shape gradually became wider. The molecular chain movement appeared more intense, the crystal nucleus was not conducive to formation, and the crystallization time became longer. Through the analysis and fitting of Avrami equation, it was found that ln(-ln(1-Xt)) (Xt means relative crystallinity) has a good linear relationship with lnt. With the continuous increase of temperature, the n value showed a decreasing trend. It is speculated that with the increase of crystallization temperature and the increase of melting time, the structure of microcrystalline nucleus is greatly destroyed, the growth point of crystallization is greatly reduced, and the molecular chain is difficult to achieve large-scale diffusion and adjustment.. In the non-isothermal crystallization test, the peak value was constantly shifted to the left and the peak shape is gradually widened with the increase of the cooling rate, due to the fact that the polyester molecular chain is too late to crystallize. Through the analysis and fitting of the Avrami equation, it is found that the semi-crystallization time of the titanium system was shorter, leading to the upward movement of the curing point in the spinning and cooling process, the increase of the stress gradient and the velocity gradient, which may cause uneven spinning and drawing. Therefore, in the follow-up, the first roller speed would be appropriately reduced to alleviate this problem.

      Conclusion Both differential scanning and XRD tests show that the crystallinity of the titanium system is higher than that of the antimony system. Isothermal crystallization and non-isothermal crystallization were used to characterize the crystallization kinetics. It can be found that the crystallization rate of the titanium system is faster, and the crystallization performance is better. The activation energy of non-isothermal crystallization of titanium system is lower, and non-isothermal crystallization activation energy is usually related to the activation energy required for nucleation stability and the activation energy required for segment diffusion into the crystal plane, so the previous relevant conclusions can be verified. Finally, due to the shorter half crystallization time of the titanium system, there may be some problems in the spinning process, so the subsequent drafting process will be adjusted by appropriately reducing the drafting speed of the first roller.

      Textile Engineering
      Method for tensile strength prediction of bast fibers
      YUE Hang, LU Chao, WANG Chunhong, LI Hanyu
      Journal of Textile Research. 2025, 46(08):  62-70.  doi:10.13475/j.fzxb.20241105501
      Abstract ( 86 )   HTML ( 15 )   PDF (3249KB) ( 16 )   Save
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      Objective In order to improve the efficiency of evaluating the mechanical properties of bast fibers, wet chemical analysis and single fiber strength testing methods were used to determine the chemical composition content and fiber strength of 27 kenaf and hemp fiber samples. The differences in chemical composition content and mechanical properties of these bast fibers were analyzed.

      Method The feasibility of replacing the overall chemical composition with three main chemical components to achieve strength response of bast fiber was analyzed using principal component analysis and cluster analysis. The overall chemical composition and three main chemical components (cellulose, hemicellulose, and lignin) were used as independent variables, and support vector regression model was used to predict fiber strength. The prediction effect of bast fiber strength was evaluated.

      Results The results of principal component analysis showed that when the number of principal components was 3, the cumulative contribution rate of principal components reached 94.48%, which basically reflects the response of fiber chemical composition to fiber mechanical properties in the original population sample data. Cluster analysis was conducted on bast fiber samples using all chemical components, principal components, and the main chemical components of cellulose, hemicellulose, and lignin as indicators. After classification, significant differences were observed in the mean mechanical properties of each type of fiber. The consistency between the clustering results based on principal components and those based on all chemical components was 96.3%. The consistency between the clustering results obtained based on the main chemical components cellulose, hemicellulose, and lignin as indicators and the clustering results obtained based on the classification of all chemical components was 92.3%. A support vector regression model was constructed with the overall chemical composition and three main chemical components as input variables, and bast fiber strength as output variable. The model performed well in internal cross validation of the corrected sample set, with mean relative prediction errors of 1.78% and 2.19% for unknown bast fiber samples, respectively.

      Conclusion The research results proved that cellulose, hemicellulose, and lignin as the three main chemical components, are able to replace all chemical components to reflect the mechanical properties of bast fibers. The use of the three main chemical components of bast fibers can replace the overall chemical composition to achieve the prediction of bast fiber tensile strength based on support vector regression model.

      Preparation and properties of optical and electric double response yarn strain sensor
      WANG Qingqing, LIAO Shiqin, WEI Qufu
      Journal of Textile Research. 2025, 46(08):  71-79.  doi:10.13475/j.fzxb.20241106201
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      Objective Conventional flexible wearable sensing devices had typically operated on a single sensing mode, providing only one type of signal output. Their sensitivity to changes in multiple environmental factors had been insufficient, and their application scope had remained limited, failing to meet the diverse and evolving demands of the market. To overcome these limitations, this study had aimed to develop a yarn strain sensor with a dual-mode response mechanism of optics and electricity that would improve its sensing performance in the field of flexible wearable monitoring.

      Method The photoelectric double response yarn strain sensor (L-E yarn strain sensor) had been fabricated through wet-spinning processing, heterogeneous structure construction, twisting into yarn, and functional material loading techniques.Scanning electron microscopy (SEM) was utilized to characterize the micromorphology of the L-E yarn strain sensor. The nano measurer tool was employed to measure the particle size of ZnS:Cu. X-ray energy spectrometry (EDS) was used to analyze the positional relationships between different components and the distribution of elements. A tensile testing machine and a digital source meter were used to test and record the changes in electrical signals of the sensor under different stretching conditions, to assess the sensor's electromechanical performance. An optical fiber spectrometer was used to measure the ML behavior of the L-E yarn strain sensor under various ZnS:Cu contents, different stretching strains, and different joint movements in a darkroom.

      Results SEM characterization exhibited the non-uniform phase polydimethylsiloxane (PDMS) liquid droplets loaded on the L-E yarn strain sensor, the sensor's twisted structure, the successful loading of polydopamine/polypyrrole (PDA/PPy), and the tight wrapping of the PDMS/ZnS:Cu layer. By measuring the exposed ZnS:Cu particles on the cross-section of the sensor, the average particle size of ZnS:Cu was determined to be 16.9 μm. EDS measurements of characteristic elements such as Zn and S on the sensor further confirmed the presence of PDMS/ZnS:Cu. Analysis of the sensor's electromechanical properties indicated that the PDMS/ZnS:Cu soft matrix provided excellent protection for the sensor, preventing oxidation and enhancing sensor stability. Due to the presence of the PDMS non-uniform phase structure and the twisted yarn structure, the sensitivity value of the L-E yarn strain sensor gradually increased to 5.45, 19.18 and 48.93 when the tensile strain was in the ranges of 0%-62%, 62%-146%, and 146%-160% respectively. The response time was 100 ms, and the lowest detectable strain limit was 0.1%, exhibiting high sensitivity and a wide strain range. The L-E yarn strain sensor showed a broad applicability, maintaining stable curve changes under different strain magnitudes or different activity frequencies, meeting the needs of various application scenarios. Furthermore, in terms of durability and stability, the L-E yarn strain sensor passed a 2 000-cycle tensile test. ML testing of the sensor showed varying ML effects under different ZnS:Cu contents and different tensile strains, and considering both mechanical applicability and cost-effectiveness, a ZnS:Cu content of 30% was determined. To further demonstrate the wearable effect of the sensor, it was fixed on the test subject's fingers and wrists, and as the degree of joint bending increased, the corresponding ML optical fiber spectral curve peaks gradually increased. In terms of electrical signal sensing, the L-E yarn strain sensor was able to accurately recognize strain signals from fingers, wrists, elbows, knees, pulses, and facial expressions.

      Conclusion The L-E yarn strain sensor has shown high sensitivity, broad strain range (0%-160%), and excellent cyclic stability. When the sensor was stretched, it could simultaneously generate both resistive and fluorescent signals, which intensifies as the strain increased. The sensor was applied to the field of wearable health monitoring, and through its optical-electric dual-mode response mechanism, not only was the visual sensing effect enhanced, but it could also accurately identify human physiological activities and joint movements, providing a reliable basis for doctors' health diagnoses.

      Preparation of woven fabrics from polyvinyl chloride fiber and their composite film structures and properties
      LI Han, QIAN Jianhua, WENG Kexin, WANG Ao, DAI Hongxiang, SHAN Jiangyin
      Journal of Textile Research. 2025, 46(08):  80-88.  doi:10.13475/j.fzxb.20241107101
      Abstract ( 77 )   HTML ( 9 )   PDF (15638KB) ( 19 )   Save
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      Objective In order to improve the mechanical properties and acid and alkali corrosion resistance of the separation membrane, polyvinyl chloride(PVC)/chlorinated polyvinyl chloride(CPVC) composite membrane with PVC mechanism mesh as the support layer was prepared. Membrane separation technology is widely used in petrochemical, biomedical, environmental protection, seawater desalination and other fields. Improving the mechanical properties and acid and alkali corrosion resistance of separation membranes would broaden the application range of separation membranes, improve the service life and save cost.

      Method The polyvinyl chloride/chlorinated polyvinyl chloride flat sheet membrane was prepared by submerged phase separation method using PVC as raw material, CPVC as blended membrane material, N,N-dimethylacetamide (DMAc) as solvent, and polyethylene glycol (PEG) 2000 as pore-former. The melt spinning process parameters were optimized for the preparation of polyvinyl chloride fibers filament, which was then made into PVC woven fabric. A composite membrane with asymmetric characteristics was constructed using polyvinyl chloride/CPVC flat sheet membrane as hydrophilic layer, and polyvinyl chloride braid as support layer.

      Results The test results show that PVC-W-P (laminating film with PVC woven fabric as support body) has a dense microporous filtration layer, and the surface layer is closely connected to the support layer, forming a mechanical interlocking structure that enhances the interfacial bonding force, and the PVC support layer is successfully bonded to the bottom of the composite membrane. The surface roughness of the composite membrane increased, and the surface hydrophilicity improved. The water contact angle was reduced to 50°, the pure water flux was increased by 1.5 times, and the protein retention rate was increased by 4.6%. Under the condition of 6.25 mol/L NaOH and 2.55 mol/L H2SO4 solution treatment for 96 h, the mass loss rate of PVC fiber filament was more than 1% point, and the loss of breaking strength was 17% for 72 h. The PVC fibers were only partially hydrolyzed or degraded, and still retained most of the structural integrity. The breaking strength of PVC-W-P (laminating film with PVC woven fabric as support body) combined with PVC mechanism mesh was 17.6 times of that of PVC/CPVC-P (membranes without binding support bodies), and it was corroded by 2.55 mol/L H2SO4 and 6.25 mol/L NaOH solution for 72 h. Its breaking strength was 15.1 times and 15.6 times of that of PVC/CPVC-P (membranes without binding support bodies), respectively, and the PVC/CPVC-P after acid and alkali treatment had a retention rate decreased less. Comprehensively analyzing the influence of PVC/CPVC-P on the performance of PVC-W-P, the corrosion resistance to acid and alkali is greatly improved, and the composite membrane still has a greater strength after treatment with different concentrations of acid and alkali.

      Conclusion PVC-W-P based on PVC woven mesh exhibits strong interfacial bonding, which significantly improves the hydrophilicity, mechanical properties and acid and alkali corrosion resistance of the composite membrane. Under acid and alkali conditions, PVC-W-P still maintains excellent mechanical properties and good filtration performance, which extends the service life of the composite membrane. This study provides a theoretical basis and reference for the preparation of composite membrane supports with excellent performance.

      Plaid fabric image retrieval method based on deep feature fusion
      ZHANG Xiaoting, ZHAO Pengyu, PAN Ruru, GAO Weidong
      Journal of Textile Research. 2025, 46(08):  89-95.  doi:10.13475/j.fzxb.20240902301
      Abstract ( 98 )   HTML ( 9 )   PDF (20969KB) ( 46 )   Save
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      Objective Fabric image retrieval is useful to search for similar fabric images already existing in a factory to obtain corresponding process parameters to guide production, and save manpower and material resources in repeated trial weaving process. The existing fabric image retrieval methods have not combined the characteristics of plaid fabric images, and the retrieval performance needs further improvement.

      Method To improve the accuracy of plaid fabric image retrieval, a convolutional neural network (CNN) model that combines attention mechanism and hash coding was proposed based on the characteristics of plaid fabrics. By introducing attention mechanism into the CNN branch to focus on key information of fabric images, global and local depth features were extracted and fused by the feature fusion module. A hash encoding layer was built to compress the fused features to balance the retrieval precision and retrieval efficiency.

      Results The proposed method was tested by establishing a new plaid fabric image retrieval dataset. Results showed that the average precision (P5) and recall(R5) of four categories were up to 77.3% and 55.2%, respectively, indicating the system's capability of retrieving the relevant images effectively. The average mean average precision (mAP) of 0.759 demonstrated the robustness of the system across all queries. In addition, there was a positive correlation between P5, R5, and mAP. The retrieval precisions of color block and academic were up to 83.1% and 86.5%, respectively. The retrieval precisions of the window and Welsh were relatively low, being 71.8% and 67.4%, respectively. The reason was that some window and Welsh plaids had a cycle period exceeding the image acquisition size of this study, which resulted in differences between images of the same fabric sample collected in different areas. The average P5 reaches 77.3%, suggesting that 3.865 out of the ranked top-5 images are correct. The requirement for enterprises to conduct fabric image retrieval is to quickly find similar images, and the proposed method was proven to meet the requirements of fabric manufacturing enterprises. Different low-order feature extraction methods and deep feature extraction methods were compared with the proposed method. Various types of plaid fabrics were with significant intra-class and inter-class differences. These low-level features heavily relied on manual design and the parameters were not universally applicable for different types of plaid fabrics. Although deep features could achieve good performance, the retrieval performance was still lower than the proposed method due to the lack of integration with the characteristics of plaid fabric images. The comparative experiments proved the adaptability and superiority of the proposed method for plaid image retrieval.

      Conclusion A plaid fabric image retrieval method based on deep feature fusion was proposed. The attention mechanisms and hash encoding layer were involved into the CNN models to realize feature extraction, feature fusion and feature compression. Plaid fabric image retrieval was achieved by similarity measurement using the hamming distance. The results showed that the average P5, R5, and mAP could reach 77.3%, 55.2%, and 0.759, respectively, demonstrating the feasibility and effectiveness of the method. By comparing existing fabric image retrieval methods, the adaptability and superiority of the proposed method for plaid image retrieval are verified. The proposed method can help enterprises quickly search for existing product process parameters to guide production and improve design, production, and operational efficiency.

      Construction and color rendering characteristics of jacquard structure model with double warps and quadruple wefts for single-weft color gradation
      LU Shuangyi, CHEN Si, ZHOU Jiu
      Journal of Textile Research. 2025, 46(08):  96-101.  doi:10.13475/j.fzxb.20241100301
      Abstract ( 71 )   HTML ( 6 )   PDF (8937KB) ( 8 )   Save
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      Objective In order to realize the color gradation effect for face layer through the interlacement of single warp and single weft in jacquard structure model with double warps and quadruple wefts, single-weft color gradation jacquard structure model with double warps and quadruple wefts were proposed based on the construction principle of double-ply weave, including 8 structural series. This study serves as a significant part of the construction and color rendering characteristics analysis of jacquard structure model with double warps and quadruple wefts and provides methods to jacquard fabric development.

      Method First, two groups of warps and four groups of wefts were placed for the construction of jacquard structure model with double warps and quadruple wefts. Then, face weave-database was built based on shaded weave construction principle. What's more, warp and weft intersection diagram for back layer construction, as well as face and back layer relationships were configurated for developing single-weft color gradation coloring weaves, with their quantities calculated simultaneously. Finally, the structural coloring characteristics of jacquard structure with double warps and quadruple wefts for single-weft color gradation were analyzed through specimen simulation.Results 48 types of color thread configurations were obtained when two groups of achromatic warp threads and four groups of chromatic weft threads are employed, while 288 series of that were realized when two groups of achromatic weft threads replacing two groups of chromatic weft threads. Then, 8 structural coloring varieties of jacquard structure model with double warps and quadruple wefts for single-weft coloring gradation were established. The maximum of warp and weft intersection diagram for jacquard structure model with double warps and quadruple wefts is 2 to the 8R squared power. Further, more than 8.4×1029 single-weft color gradation weaves were calculated when weave repeat R (weave repeat) equals to 5, while more than 1.6×1060 warp and weft intersection diagram for jacquard structure model with double warps and quadruple wefts were obtained. What's more, specimen simulation was carried out under specific technique parameters, 12-threads 5-steps satin shaded face weave-database as well as warp and weft float were employed, with the interlacement of achromatic color threads, though influenced by the thread density and the density of face warp and weft, the black, white and the gray transition were obtained, besides, texture changed when warp or weft floats varied on the surface of specimen. In addition, on one hand, lightness and saturation adjustment of chromatic color gradation achieved through the interlacement of single achromatic warp and single chromatic weft on the fabric surface, on the other hand, the color of the ground part expressed a specific hue tendency. Last but not least, the figured part and the ground part of each specimen are able to be realized via independent regulation of warp and weft selection on the fabric surface layer simultaneously, presenting that the jacquard structure model with double warps and quadruple wefts for single-weft color gradation proposed is effective.

      Conclusion Jacquard structure model with double warps and quadruple wefts for single-weft color gradation is able to realize the independent control of the face and back warp and weft. If weave repeat outnumbers 5, more than warp and weft intersection diagram generates under jacquard structure model with double warps and quadruple wefts, while the quantity of single-weft color gradation coloring weaves exceeds. Besides, structural coloring of specimen simulation not only achieves lightness transition of achromatic color, but also realizes saturation transition of single chromatic color. Thus, this study contributes to the construction of digital weave-database and product development of jacquard structure model with double warps and quadruple wefts for single-weft color gradation.

      Fabric texture regularity characterization based on contrast perception of texture primitives
      GUO Yanchi, PAN Ruru, ZHOU Jian
      Journal of Textile Research. 2025, 46(08):  102-110.  doi:10.13475/j.fzxb.20240903001
      Abstract ( 67 )   HTML ( 8 )   PDF (11436KB) ( 19 )   Save
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      Objective Regularity (periodicity), as one of the most important attribute features of texture images, is a key index for classifying and describing texture images. Relating to the unique production process of woven fabrics, the texture of woven fabric images exhibits a high degree of regularity, which is a typical structural texture. Therefore, utilizing regularity to describe the surface attributes of fabric textures is of great practical significance in the fields of fabric classification, fabric retrieval, and fabric apparent quality detection and evaluation.

      Method This paper first proposes four metrics for characterizing the regularity of fabric textures based on the spatial arrangement of primitive elements and human visual perception factors (grey scale contrast, structural symmetry and edge consistency). Then, significant peaks and valleys are extracted by threshold division on autocorrelation Pearson coefficients and distance matching function curves, and the relationship between peaks and valleys is used to achieve the characterization of the above metrics. Finally, the weighted summation is used to perform the comprehensive characterization of texture regularity.

      Results The overall regularity metrics are validated using different types of fabric samples and some structured textures from the Brodatz Album. The results show that for fabric texture, the proposed metric is able to achieve the characterization of the regularity of fabric texture and distinguish effectively textures with different degrees of regularity. In addition, the comparison with other methods shows that the proposed metric is more in line with the visual perception law of the human eye and has a higher accuracy rate. Under the understanding that the textures in the Brodatz Album usually show a high degree of regularity and have a relatively large and unique size of the periodic unit, two different combinations of the weights are discussed in order to find the most suitable weights, and calculate the overall degree of regularity of the texture with the proposed metric under the weight. It is concluded from the discussion that the proposed metric can also achieve the characterization of the regularity of fabric textures. The results show that the proposed metrics are capable of extracting structural textures other than near-regular fabric textures.

      Conclusion The texture regularity index is subdivided from the perspective of the visual perception of the human eye, so as to achieve the characterization of texture regularity in a more comprehensive and detailed way. The experimental results show that the proposed metrics are not only applicable to fabric textures with small and soft sizes, but can also characterize the regularity of various specific types of texture images by combining the importance of different metrics and applying different weights. In the future, the proposed metrics can be considered to be combined with other attribute features of texture images for practical applications such as texture classification and defect detection.

      Detection and classification of jacquard knitted fabric defects based on gray statistics and improve arithmetic optimization algorithm classifier
      ZHANG Yongchao, SHI Weimin, GUO Bin, TU Jiajia, LI Yang
      Journal of Textile Research. 2025, 46(08):  111-119.  doi:10.13475/j.fzxb.20240703101
      Abstract ( 104 )   HTML ( 7 )   PDF (6140KB) ( 24 )   Save
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      Objective Jacquard knitting fabric with its diversified pattern design can meet consumers’ personalized fashion and pursuit. However, defects in the production process would seriously damage the integrity of the pattern and reduce the aesthetics of products. Due to the pattern color and edge texture, it is difficult to distinguish the normal fabric texture from the minor defects by the traditional detection method, which increases the detection difficulty and complexity. Therefore, strengthening the quality monitoring of jacquard knitting products and identifying the defects on the fabric quickly and accurately become the key link to ensure product quality.

      Method Based on the obvious difference between the defect area and texture area of jacquard knitted fabric in the gray value and its distribution, the information entropy and statistics were introduced into the two-dimension feature extraction technology. The weighting fusion mechanism was designed to integrate the multi-source features, so that the optimal reconstruction of features and the geometric outline and statistical feature framework for capturing defects were achieved. These features were used as input data for the support vector machine(SVM) classifier. To optimize the performance of SVM, a new algorithm integrating arithmetic optimization and Levy flight strategy was introduced.

      Results The information entropy feature and feature quantity feature were used to represent the defect image on the gray scale. The location of defects was determined by analyzing the difference between texture and defect in spatial distribution. The detection process was mainly composed of three modules. The image pre-processing module was responsible for the preliminary processing of the input jacquard fabric image, including noise removal, contrast enhancement and other steps, so as to improve the image quality and lay a foundation for the subsequent feature extraction. The feature extraction module was the algorithm using information entropy feature and statistical feature to divide the texture area and defect area by weighting fusion dual feature area, and extract information that can represent defect characteristics. The classification module was based on the feature data provided by the feature extraction module, using the improved SVM classification algorithm to classify the defects and mark the position of the defects. High detection rate was achieved for broken yarns and holes, but low detection rate was obtained for low strength defects such as knot and yarn jumping. The combined algorithm significantly improved the detection rate after image pre-processing. Single-feature algorithm was efficient for specific defects, but the algorithm in this paper maintained a high detection rate for all kinds of defects, and verified the effectiveness and robustness of its pretreatment and detection algorithm for complex texture and defects of jacquard knitted fabric. Under the input condition of multiple characteristic parameters combination, the Levy optimization algorithm-support vector machine(LAOA-SVM) classification algorithm and its comparison algorithm designed in this paper showed the highest classification accuracy. The LAOA-SVM classifier performed well on the independent test set, with an accuracy rate of 99.4%, and the time of 0.93 s was less than that of other methods, indicating that the algorithm was efficient and accurate in the fabric defect classification task. The LAOA-SVM classifier showed good classification performance after training, with only a little misjudgment between yarn jumping and knot. Up to 100% accuracy was reached for other fabric defect classifications. Especially for the regional defects with obvious similarity in characteristics, such as yarn breaking and hole breaking, the advantage of LAOA-SVM was highlighted. Other classification algorithms demonstrated a high misclassification rate when dealing with different types of defects. This result strongly demonstrated the high efficiency of LAOA-SVM classifier in fabric defect recognition.

      Conclusion The image pre-processing stage effectively enhances the contrast between the defect and the texture through grayscale and filter denoising. Then, the information entropy and statistical features are used to extract the defect information, and the feature optimization is achieved by double-feature weighting fusion. The designed LAOA-SVM classification algorithm and its comparison algorithm show the highest classification accuracy. The LAOA-SVM classifier performs well on the independent test set, with an accuracy rate of 99.4%, and the time of 0.93 s is less than that of other methods, which indicates that the algorithm is efficient and accurate in the fabric defect classification task. The experimental results show that, compared with the prior art, the method performs excellently in the detection of defects such as holes, flying sparks, yarn jumping, greasy dirt and yarn breaking, with a detection rate of up to 99%, and a classification accuracy of 99.4%, especially when dealing with defects with similar characteristics.

      Preparation and performance study of carbon fiber reinforced cement-based grouting material
      CHEN Qingyu, LU Chunhong, ZHANG Bin, JIN Yikai, HUANG Qiwei, WANG Chao, DING Bin, YU Jianyong, WANG Xianfeng
      Journal of Textile Research. 2025, 46(08):  120-126.  doi:10.13475/j.fzxb.20240501401
      Abstract ( 68 )   HTML ( 5 )   PDF (4911KB) ( 14 )   Save
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      Objective The cement-based grouting material is widely used in secondary grouting, equipment installation, prefabricated construction, anchor bolt anchoring, and grouting repair. However, it has been found that the impact resistance and crack resistance of grouting material will gradually deteriorate after long-term use. Therefore, improving the crack resistance and toughness of grouting material is crucial for its applications in the engineering field.

      Metheod The length of carbon fiber had a significant impact on the flowability of cement matrix, in order to reduce the influence of carbon fiber on the fluidity of grouting material, short cut carbon fiber with a length of 1 mm was used to reinforce cement-based grouting material. In order to improve the dispersion uniformity of carbon fiber in the cement matrix and the performance of grouting material, the carbon fiber was pre dispersed with Sodium polyacrylate (PAAS) before adding to grouting material. The proportion of water reducing agent was increased, and the preparation process was adjusted during the process of making the carbon fiber reinforced cement-based grouting material. After curing and shaping grouting material, the influence of carbon fiber on the flexural strength and compressive strength of grouting material at different ages was studied. SEM was used to study reinforcing mechanism of carbon fiber reinforced cement-based grouting material.

      Results It was found that water reducing agent can effectively reduce the influence of carbon fiber and PAAS on the flowability of grouting material. but with the increase of carbon fiber content, the flowability of grouting material still gradually decreased. Meanwhile, with the increase of carbon fiber content, PAAS and water reducing agent enhanced the retarder effect on grouting material, resulting in an extension of its initial setting times. The research also revealed that the addition of carbon fiber significantly improved the 1-day, 3-day, 28-day compressive strength and 28-day flexural strength of grouting material, and the flexural and compressive strength of grouting material showed a trend of first increasing and then decreasing with the proportion increase of carbon fiber. When the carbon fiber content was low, uniformly dispersed carbon fiber effectively enhanced the cement matrix. However, when the carbon fiber content was too high, PAAS can't effectively disperse carbon fiber, and incompletely dispersed carbon fiber formed many clusters in the grouting material, resulting in a significant decrease in the mechanical strength of grouting material. In addition, its compressive and flexural strength respectively reached its peak when the volume fraction of carbon fiber was 0.4% and 0.3%. By observing the microstructure of grouting material with different proportion of carbon fiber, it was found that the increasing proportion of carbon fiber significantly reduced the number of cracks in the cured grout and delayed crack propagation. After adding carbon fiber to grouting material, the viscosity of the grouting material was increased, which played an effective connecting role on the cement matrix. The interface of carbon fiber observed in the microstructure indicated that carbon fiber had fractured and slid when subjected to internal forces in the grouting material, thus proving that carbon fiber shared the pressure borne by grouting material inside the material. Through studying the working performance, mechanical properties, and microstructure of the high-performance grouting material with carbon fiber, it was found that the comprehensive performance of the carbon fiber reinforced cement-based grouting material was optimal when the volume fraction of carbon fiber was kept at 0.3%.

      Conclusion The experimental results show that the addition of carbon fiber disperses the pressure and bending force borne by grouting material, improves the cohesion of grouting material, and transforms brittle failure into flexible failure, ultimately significantly improving the compressive and flexural strength of grouting material.

      Improvement of thermal dimensional stability properties of polylactic acid meltblown nonwovens
      ZHANG Xinyu, JIN Xiaopei, ZHU Jintang, CUI Huashuai, WU Pengfei, CUI Ning, SHI Xianning
      Journal of Textile Research. 2025, 46(08):  127-135.  doi:10.13475/j.fzxb.20240805901
      Abstract ( 86 )   HTML ( 9 )   PDF (9470KB) ( 12 )   Save
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      Objective Polylactic acid (PLA) meltblown nonwoven fabric has poor heat resistance and a large shrinkage rate after heating, which seriously restricts its application in the field of filter materials. PLA meltblown nonwoven fabric cannot meet the disinfection requirements under 50-60 ℃ during mask production. Research has found that increasing the crystallinity of PLA meltblown nonwoven fabric can improve its heat resistance, thereby enhancing its dimensional stability.

      Method This article solves this problem by increasing crystallinity and the number of grains, thereby increasing physical cross-linking points and limiting polymer relaxation. Non isothermal crystallization kinetics of PLA and diphenylhydrazide sebacic acid(PLA/TMC-300) were studied using DSC. The cooling crystallization process of PLA and PLA/TMC-300 was observed using a polarizing microscope. The effect of nucleating agent on the crystallinity of PLA meltblown nonwoven fabric was studied by XRD, and the effect of nucleating agent on the dimensional stability of PLA meltblown nonwoven fabric was studied by hot water shrinkage rate.

      Results A comparative study on the non isothermal crystallization kinetics of PLA and PLA/benzoylhydrazine sebacate (TMC-300) showed that TMC-300 can significantly improve the crystallization ability of PLA. Polarized microscopy observation of the cooling crystallization process of PLA and PLA/TMC-300 also revealed that the addition of TMC-300 increased the crystallization temperature, crystallization rate, crystallinity, and grain number of PLA. XRD studies have found that compared to PLA meltblown nonwoven fabric, PLA/TMC-300 meltblown nonwoven fabric has increased crystallinity and more complete crystals. The study on the thermal dimensional stability of two types of meltblown nonwoven fabrics found that TMC-300 can effectively improve the dimensional stability of PLA meltblown nonwoven fabrics, whether by extending the heat treatment time or increasing the heat treatment temperature. After heat treatment at 50 ℃ for 1 h, the area shrinkage rate of PLA meltblown nonwoven fabric was 19%, while the area shrinkage rate of PLA/TMC-300 meltblown nonwoven fabric was 4.9%, and the length shrinkage rate was only 0.98%.

      Conclusion Whether by extending the heat treatment time or increasing the heat treatment temperature, TMC-300 can effectively improve the dimensional stability of PLA meltblown nonwoven fabrics. After heat treatment at 50 ℃ for 1 hour, the area shrinkage rate of PLA/TMC-300 meltblown non-woven fabric is 4.9%, and the length shrinkage rate is only 0.98%, which fully meets the production requirements of masks. TMC-300 heterogeneous nucleation can improve the crystallization ability of PLA, increase the crystallinity and the number of grains, and act as physical cross-linking points in the aggregated three-phase structure of grains, limiting the thermal relaxation ability of amorphous polymer segments. Therefore, PLA meltblown nonwoven fabric can maintain better dimensional stability at high temperatures macroscopically.

      Fabrication and characterization of wearable flexible strain sensors based on three-dimensional braided structures
      QUAN Ying, ZHANG Aiqin, ZHANG Man, LIU Shuqiang, ZHANG Yujing
      Journal of Textile Research. 2025, 46(08):  136-144.  doi:10.13475/j.fzxb.20241006301
      Abstract ( 73 )   HTML ( 8 )   PDF (11264KB) ( 28 )   Save
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      Objective Wearable flexible strain sensors are widely used in fields of healthcare, public health, and human-computer interaction, among which textile-based flexible strain sensors have attracted great attention due to the advantages of high flexibility, comfort, and easy integration with clothing. However, the preparation of strain sensors with both high sensitivity and wide workable strain range remains a challenge. In this work, a flexible strain sensor with high stretchability and sensitivity is prepared by choosing polyurethane filament (PUF) to form a net-like three-dimensional braided fabric, and constructing a synergistic conductive network with one-dimensional tubular carbon nanotubes (CNT) and two-dimensional graphene sheets (GNP).

      Method The three-dimensional (3-D) braided fabrics were prepared by four-step braiding process using PUF as raw material. The conductive fillers, CNT and GNP, were loaded onto the fabric surface in different ratios with the aid of ultrasound-assisted impregnation-drying. To enhance the fastness of the conductive coatings, the fabric was then immersed in dopamine solution for 6 h to obtain the 3-D braided flexible strain sensors. The sensors were characterized in terms of morphology, mechanical-electrical property and sensing performance. The effects of braided structures and CNT/GNP mass ratio on the performance of the prepared strain sensors were investigated.

      Results Flexible strain sensor was prepared by loading CNT/GNP on the surface and forming a synergistic conductive network. Results showed that the sensing range of 3-D braided strain sensor was much higher than that of the PUF sensor. Under the same treatment conditions, the workable strain range of 3-D braided strain sensor was up to 280%, while the PUF was up to 126% in comparison. Thus the introduction of braided structure increased the workable strain sensing range significantly. The decrease in mass ratio of CNT in the impregnating solution led to the increase in the mass ratio of GNP, decrease in the workable strain range and significant increase in sensitivity. Consequently, in the conductive network of the strain sensor, CNT mainly played the role of circuit bridging to provide a large strain monitoring range for the sensor, while GNP sheets provided higher sensing sensitivity for the sensor through the significant change of the contact surface under strain. In addition, the surface polymerization of polydopamine(PDA) made the conductive coating firmer, enhancing stability and repeatability of the prepared strain sensor. Considering both of the sensitivity and strain range, the 3-D braided flexible sensor with CNT/GNP mass ratio of 1∶1 demonstrated better sensing performance, with a sensitivity coefficient as high as 249.8 and a strain sensing range of not less than 154%. Meanwhile, the electrical signal output was stable after more than 6 000 cycles of 50% stretching, and the water washing resistance was also proved well. It exhibited stable transmission signal in the motion monitoring of human face, neck, elbow, wrist, knuckle, knee and other parts of the body. The consistency and reliability of the signal were maintained for repeated movements with different speeds and amplitudes, proving the great potential of the prepared braided strain sensor for application in the fields of health assessment and rehabilitation training.

      Conclusion CNTs/GNP/PDA-PUF flexible strain sensors were prepared with a flexible 3-D braided fabric as the substrate, and the introduction of braided structure increased the workable strain sensing range significantly. As the mass ratio of CNTs decreases and the mass ratio of GNP increases, the sensitivity of the braided strain sensor increases and the workable strain range decreases. Surface PDA-PUF improves the coating fastness, resulting in a significant increase in sensor stability. The prepared CNTs/GNP/PDA-PUF flexible braided strain sensor has both high sensitivity and large workable strain range, proving the potential in fields of human motion and health monitoring applications.

      Dyeing and Finishing Engineering
      Preparation and properties of high-efficient flame-retardant Lyocell fabrics with tannic acid based flame retardants
      XU Yunkai, SONG Wanmeng, ZHANG Xu, LIU Yun
      Journal of Textile Research. 2025, 46(08):  145-153.  doi:10.13475/j.fzxb.20250103001
      Abstract ( 99 )   HTML ( 12 )   PDF (12192KB) ( 30 )   Save
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      Objective Lyocell fabrics are used in the clothing and home decoration industries because of their excellent comfort, soft handle and easy coloring. However, the limiting oxygen index (LOI) of Lyocell fabrics is only 19.0%, and it is very easy to be ignited, causing fire accidents. Some of traditional halogenated flame retardants can produce toxic gases and seriously harm to the environment in the process of using, and people are more inclined to choose efficient, green and pollution-free bio-based flame retardants. It is, therefore, necessary to design a biomass flame retardant to improve the flame retardancy of Lyocell fabrics.

      Method Tannic acid (TA) and Diethylene triamine pentakis (methyl phosphonic acid) (DTPMPA) were used to prepare flame retardants (named TD). Flame-retardant Lyocell fabrics were prepared by pad-dry-cure finishing method. For comparison,flame-retardant Lyocell fabrics were prepared by 50 g/L and 100 g/L flame-retardant finishing solutions, which were named as L-TDa and L-TDb, respectively. The flame retardancy, mechanical properties and air permeability were investigated for LOI, vertical flame tests (VFT), micro-scale combustion calorimetry test (MCC), universal testing machine and fully automated permeability instrument.

      Results The scanning electron microscopy (SEM) results showed that TD adhered to Lyocell fabrics, but the flame retardants did not block the spaces between the fibers, hence the air permeability of flame-retardant Lyocell fabrics was not affected. Due to the lower thermal stability of the flame retardants, TD facilitate the premature dehydration and carbonization of TD, reducing the thermal stability of flame-retardant Lyocell fabrics in low-temperature regions, while improving their thermal stability in high-temperature regions both in nitrogen and air atmosphere. The VFT results indicated that flame-retardant Lyocell fabrics achieved self-extinguishing after ignition, and the after-flame time and the after-glow time were 0 s. The damaged length of L-TDa and L-TDb were only 54 mm and 51 mm, and the LOI values of L-TDa and L-TDb increased to 38.6% and 48.2%. It can be obtained that flame-retardant Lyocell fabrics had better flame retardancy compared with that of control Lyocell fabrics. Meanwhile, the MCC results presented that TD had a significant inhibitory effect on the heat release of flame-retardant Lyocell fabrics. The peak heat release rates of L-TDa and L-TDb were decreased by 76.0% and 94.1% compared with that of control Lyocell fabrics. The retention ratios of breaking force in both the warp and weft direction of L-TDa and L-TDb were over 70%, meeting the daily use expectation. The air permeability results indicated that the air permeability of flame-retardant Lyocell fabrics were not negatively affected, but was even enhanced compared with that of control Lyocell fabrics. The results of anti-ultraviolet tests showed that the UVA and UVB of flame-retardant Lyocell fabrics were significantly lower than those of control Lyocell fabrics, having better anti-ultraviolet properties. The antibacterial results showed that the flame-retardant Lyocell fabrics had certain antibacterial effect on S. aureus and E. coli, in which the antibacterial rate of L-TDb to S. aureus and E. coli reached 97.4% and 93.3%, respectively.

      Conclusion It can be concluded that TD treatment improved the flame retardancy of Lyocell fabrics and conferred certain antibacterial and anti-ultraviolet properties on Lyocell fabrics. However, the warp and weft breaking force of these flame-retardant Lyocell fabrics had been decreased, calling for further improvement in the future to reduce the damage of flame retardants to the mechanical properties of Lyocell fabrics. Meanwhile, the handle and whiteness of flame-retardant Lyocell fabrics also need to be further studied. Considering the better performance of flame-retardant Lyocell fabrics in VFT and LOI, it can be concluded that phosphorous-containing biomass flame retardants have excellent flame-retardant effect and give Lyocell fabrics better flame retardancy.

      Preparation of polylactic acid fabrics modified with phosphonic acid and their properties
      CHEN Zhanyu, YU Senlong, ZHOU Jialiang, ZHU Liping, ZHOU Zhe, XIANG Hengxue, ZHU Meifang
      Journal of Textile Research. 2025, 46(08):  154-163.  doi:10.13475/j.fzxb.20241201901
      Abstract ( 103 )   HTML ( 7 )   PDF (16068KB) ( 30 )   Save
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      Objective As a type of promising biodegradable materials, polylactic acid (PLA) has been widely used in making textile fibers, commodity plastics, packaging materials and biological materials due to its excellent biocompatibility and considerable degradability. However, PLA still exists diverse problems such as high brittleness and poor heat resistance. Especially, PLA is easily burned with serious melt droplets at high temperature, limiting the further applications in automotive interior and building decoration. Therefore, development of a simple and eco-friendly flame-retardant PLA modification method is significant and necessary.

      Method The efficient flame-retardant modification of PLA fabrics was carried out via a dipping treatment. To start with, PLA fabrics were rinsed with anhydrous ethanol and then impregnated in a 150 g/L solution of methylphosphonic acid/methylphosphonate for 30 s. The fabrics were subsequently dried in a 60 ℃ oven for 15 min to complete the flame retardant treatment. The treated fabrics were denoted as FR-PLA-xC, where x represented the number of dipping. The morphology, chemical composition, thermal stability and flame retardant property were characterized by means of scanning electron microscope, EDS, Fourier transform infrared spectroscopy, thermogravimetric analyzer, cone calorimetry and limiting oxygen index.

      Results The SEM of fabric surface morphology showed that methylphosphonic acid/methyl methylphosphonate flame retardancy was evenly distributed on the PLA fabrics after surface flame-retardant modification. The mass fraction and phosphorus content of flame-retardant fabrics were the highest with 4-time dipping treatment. Thus, the FR-PLA-4C fabric showed the most significant improvement in flame retardancy with the limiting oxygen index (LOI) of 30.8% and the vertical burning classification of V-0. Furthermore, the flame retardancy of FR-PLA-4C fabrics was characterized by cone calorimeter test and microcalorimetry test. The peak heat release rate (PHRR) and total heat release (THR) dropped to 259.92 kW/m2 and 10.4 MJ/m2, representing deceases by 8.9% and 10.4%, respectively. This indicates that FR-PLA-4C fabric generated less flammable volatile substances and produced more carbon-containing residues when it was exposed to high-temperature radiation. Under the nitrogen atmosphere, the initial degradation temperature (T5%) of pure PLA fabric was 342.8 ℃, the maximum thermal degradation rate (Rmax) was 18.2%/min, and the high-temperature residue was 0%. After flame retardant modification, the T5% of FR-PLA-4C was 275.3 , the Rmax was 17.2%/min, and the residue was 12.0%. The flame-retardant mechanism was analyzed by TG-IR, SEM and Raman spectroscopy, incorporating both condensed phase and gas phase. Compared with PLA fabric, the graphitization degree of char residues was significantly improved by organic-phosphonic acid coating. Moreover, the FR-PLA-4C exhibited ideal service performance, the tensile strength increased from 135.7 N (PLA) to 260.8 N.

      Conclusion The flame-retardant PLA fabric (FR-PLA) was successfully fabricated by dipping surface treatment. The chemical structure, thermal stability, flame retardancy, tensile strength and service performance were studied. Specifically, the FR-PLA-4C fabric exhibited the most excellent flame retardancy (LOI 30.8%, UL-94 V-0). The PHRR and the THR were deceased by 8.9% and 10.4%, respectively as well as the residual carbon at 600 ℃ could reach 12.0%. Additionally, the mechanism of the FR-PLA fabric included both gas phase and condensed phase. Moreover, the tensile strength was significantly improved by flame-retardant modification, while the softness and breathability were slightly affected by coating. Besides, the visual appearance and color of the fabric had no obvious change as well as it expressed certain washing durability with LOI value of 25.0% after 30 min laundry. To sum up, the FR-PLA-4C fabric simultaneously exhibited ideal flame retardancy, mechanical property and service performance, which has a promising prospect in home textiles, indoor decoration, and industrial fabrics, etc.

      Preparation of solvent-responsive structural colored fabrics and their properties
      DUAN Yazhou, TAO Weihan, FANG Yinchun, LI Wei
      Journal of Textile Research. 2025, 46(08):  164-172.  doi:10.13475/j.fzxb.20250104401
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      Objective Compared with chemical color, photonic crystals (PCs) structural color is controlled by external stimuli, transforming stimuli signals to facilitate visible color change. Solvent-response PCs structural colors are easy to achieve and hence are popularly used with convenience, and hence are extensively studied. However, most of the solvent-responsive PCs structural colors are constructed on flat substrates and based on hydrogel material. There are few studies on constructing solvent-responsive structural colors on the flexible fabrics, because it is more difficult to obtain uniform and stable structural color coatings on the rough and deformable surface. In this paper, polystyrene-methyl methacrylate-acrylamide (P(St-MMA-AM))microspheres containing hydrophilic chains were synthesized to construct structural colors with solvent-responsive on fabrics, aiming for creation of smart responsive structural color textiles.

      Method P (St-MMA-AM) microspheres containing hydrophilic chain were synthesized by soap-free emulsion polymerization using styrene (St), methyl methacrylate (MMA) and acrylamide (AM) as monomers. The influence of monomer ratio on particle size of the microspheres was studied. P(St-MMA-AM) microspheres were atomized and deposited on polyester woven fabric to form structural color with solvent responsiveness. The color properties and solvent response properties of different solvents of the structural colored fabrics were studied. The color fastness and physical properties of the structural colored fabric were also studied.

      Results P(St-MMA-AM) polymer microspheres with hydrophilic chains were successfully synthesized through soap-free emulsion polymerization. By changing the mass ratios of the monomers, P(St-MMA-AM) microspheres with different particle sizes of 392.7, 384.1, 358.6, 344.6 nm, and 322.4 nm were obtained, accordingly five different structural colors of pink, green, blue, light blue and purple were achieved on the fabrics by atomized deposition of these P(St-MMA-AM) microspheres. When wetted with water or ethanol, these structural colored fabrics could change their colors to fuchsia, yellow-green, dark green, cobalt blue, and dark blue, respectively, within 1-2 s. Once the solvent was evaporated, the five structural colors would revert to their original colors. The wavelengths corresponding to the maximum reflectance (λmax) of the five structural colors on the fabric were 590, 510, 460, 430 nm, and 410 nm respectively. After being wetted by water, the λmax of the five structural colors shifted to 390, 530, 490, 450 nm, and 440 nm, which could return to their initial values after the water evaporated, demonstrating excellent solvent-reversible response performance. Both single-color and multi-color patterned structural colored fabrics exhibited solvent responsiveness, showing potential for the preparation of patterned fabrics with special responsiveness. There was no obvious color change of the structural colored fabrics before and after rubbing, except for the decreasing of the maximum reflectance λmax by only 0.22% compared to that before rubbing. After washing, the colors of the structural colored fabrics remained almost the same as they were before, and the maximum reflectance decreased by only 0.33%, indicating good rubbing and washing color fastness, which could be attributed to the fixation of the microspheres on the fabric by the polyacrylate binder. Compared with the original fabric, the wrinkle recovery performance of the structural colored fabric remained unchanged, and there was a slight decrease in softness and air permeability, demonstrating that the physical properties of structural colored fabrics were slightly influenced.

      Conclusion In this study, P(St-MMA-AM) microspheres with five different particle sizes were successfully prepared by adjusting the monomer mass ratio, which formed five different structural colors i.e. pink, green, blue, light blue and purple on polyester fabrics through atomized deposition. The structural color fabrics showed fast solvent-responsive performance, changing color within 1-2 s after wetting by water and ethanol. After solvent evaporation, the five structural colors restored to their original colors, showing the excellent solvent reversible response performance. The structural colored fabrics also had good rubbing and washing colorfastness. The physical properties of the structural colored fabrics were slightly influenced compared with the original fabrics. This study provides an experimental basis for the development of smart responsive structural color textiles.

      Integrated treatment and resource recovery technology of desizing wastewater through pre-oxidation and flocculation
      SHEN Chensi, WANG Xinyue, LI Fang
      Journal of Textile Research. 2025, 46(08):  173-182.  doi:10.13475/j.fzxb.20250201801
      Abstract ( 61 )   HTML ( 7 )   PDF (9009KB) ( 15 )   Save
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      Objective In China, over 20% of polyvinyl alcohol (PVA) is utilized as a sizing reagent in the textile industry, with virtually all of it being discharged into wastewater during the desizing process in fabric printing and dyeing. Traditional PVA wastewater treatment methods face significant challenges due to PVA's high degree of polymerization, electrical neutrality, and strong intramolecular/intermolecular hydrogen bonds, which collectively impede degradation and precipitation. These characteristics typically necessitate substantial chemical inputs and complex treatment processes. Therefore, developing an integrated technology that combines pre-oxidation and flocculation processes is particularly crucial for efficient PVA wastewater treatment.

      Method A "pre-oxidation flocculation precipitation" technology based on Fe2+/CaO2 was developed. The system releases H2O2 through CaO2 hydrolysis, generates oxidative species under Fe2+ catalysis, enhances PVA flocculability, and achieves precipitation via Fe3+ and Ca2+ ions. Effects of reagent dosage, pH value, initial PVA concentration, and reaction time were investigated. X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) techniques were used to analyze precipitates for mechanism elucidation. The sludge was evaluated as an adsorbent and catalyst for Reactive Black 5 degradation.

      Results The integrated treatment of PVA technology has been successfully achieved. The optimal conditions were determined to be 20 mmol/L Fe2+ and 2 mmol/L CaO2, with a pH value of 3 for the pre-oxidation stage, pH value of 10 for the flocculation for sedimentation stage, and a pre-oxidation time of 60 minutes. When treating PVA within a concentration range of 0.5-2 g/L, the removal rates for PVA and chemical oxygen demand (COD) reached over 97.1% and 92.2%. The process also demonstrated effective treatment of actual desizing wastewater containing modified starch, achieving over 90% removal efficiency. XPS C1s spectra showed an increase in C—O bond proportion after treatment, with O—C═O bonds shifting to higher binding energy (289.3 eV) and the emergence of a new ketone (C═O) peak at 288.1 eV, indicating PVA chain breakage and oxidation to form oxygen-containing groups that improved flocculation. SEM revealed that precipitates consisted of irregularly stacked nanoparticles with compact structures, while EDS mapping showed Fe and Ca atomic percentages of 24.65% and 75.35%, respectively. TEM images displayed typical amorphous flocculent structures with localized lattice fringes, confirming the formation of CaFe5O5 ferrite complexes. Additionally, the integrated treatment technology produces sludge containing a significant amount of iron/calcium organic complexes and ferrites. This sludge can be repurposed for the treatment of difficult-to-degrade pollutants in wastewater. Specifically, when 0.10 g of sludge was added to 100 mL of wastewater containing 10 mg/L of Reactive Black 5, a removal rate exceeding 94.3% was achieved after 30 min.

      Conclusion This study developed an Fe2+/CaO2 system for treating PVA-containing desizing wastewater and investigated the resource utilization of generated sludge. The system functions by producing H2O2 through CaO2 hydrolysis, generating oxidative species under Fe2+ catalysis, while Fe3+ and Ca2+ ions act as flocculants. Optimal conditions (20 mmol/L Fe2+, 2 mmol/L CaO2, pH value 3 for pre-oxidation, pH value 10 for flocculation, 60 min reaction time) achieved removal efficiencies exceeding 97.1% for PVA and 92.2% for COD in 0.5-2 g/L PVA concentrations. The resulting sludge, rich in iron/calcium-organic complexes and ferrites (CaFe5O7), demonstrated exceptional value for treating recalcitrant pollutants, achieving 94.29% removal of Reactive Black 5 within 30 min.

      Apparel Engineering
      Classification and recognition of human head-neck-back curvature morphology for personalized curved-pillow design
      LIU Jinling, HE Yating, GU Bingfei
      Journal of Textile Research. 2025, 46(08):  183-190.  doi:10.13475/j.fzxb.20250202401
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      Objective People are paying increasing attention to sleep quality, for which the scientific design of pillow shapes becomes more important. The shape of a pillow closely relates to the head, neck, and back of the human body. However, people of different ages have different body shapes, so existing pillows on the market hardly meet everyone's needs. This study focused on young adults and investigated the curved shape differences in their heads, necks, and backs.

      Method The study adopted a point-line-surface-curvature classification approach. First, [TC]2 NX-16 non-contact 3-D scanner was used to capture human body point cloud data. Point cloud registration and iterative closest point (ICP) algorithm then extracted the head-neck-back median sagittal plane. Key points were marked according to surface morphological characteristics. After extracting horizontal and coronal planes based on feature point locations, a 3-D coordinate system was established to measure intersection coordinates. The study then performed data classification by integrating coordinate measurements with curvature parameters.

      Results Three-dimensional scanning captured head-neck-back morphological data from 252 university male and female students aged 18-25. The posterior median sagittal plane revealed nine feature points, which are posterior occipital point, posterior neck point, axillary-sagittal intersection point, superior occipital peak point, intersection point of the cervical-occipital contour, inferior occipital peak point, and three cervicodorsal points. The spatial distribution of feature points guided the extraction of 11 curved surfaces (8 transverse, 3 longitudinal) across the head-neck-back regions. These surfaces formed 24 external contour intersection points in three-dimensional space.

      A 3-D coordinate system was established with its origin at the center of the posterior neck point's horizontal cross-section, integrating spatial coordinates of all intersection points and median sagittal plane curvature parameters. Principal component analysis (PCA) revealed that the first four principal components achieved a cumulative variance contribution rate of 0.8, effectively reducing data dimensionality while preserving most information. The PCA algorithm identified four characteristic factors. K-means clustering analysis sequentially calculated sum of squared errors values between each sample and its cluster center for different K values. Optimal clustering occurred at K=4, leading to the final classification of head-neck-back surface morphology into four characteristic types, which are rounded, deep-necked, flattened, and forward-leaning.

      The results showed that the occipital bone line of the round type was smooth and natural with a uniform transition. The neck depression of the deep-necked type was relatively deep, forming an obvious drop compared with the surrounding areas. The curvature change of the occipital bone of the flattened type was small and almost flat. The entire head-neck-back of the forward-leaning type demonstrated a forward leaning trend, deviating from the normal physiological curve. According to the morphological discrimination rules, they re-determined the initial sample data as a whole, and the accuracy rate reached as high as 95.58%, showing a remarkable effect.

      Conclusion The study utilized the median sagittal plane as the anatomical reference for head-neck-back morphological analysis, establishing a three-dimensional Cartesian coordinate system. Principal component analysis combined with K-means clustering of spatial coordinates and curvature parameters classified the samples into four distinct morphological types: rounded, deep-necked, flattened, and forward-leaning, demonstrating a classification accuracy of 95.58%. The curved pillow design incorporated personalized parameters for different morphological types. The rounded type was characterized by its smooth and curvilinear contour, and an increased groove depth is essential. This enhancement allows the pillow to cradle the head's curvature snugly during sleep, reducing pressure points and promoting a more relaxed rest. The deep-necked type with pronounced cervical concavity benefits significantly from an elevated pillow apex height. This adjustment ensures that the pillow aligns perfectly with the natural curve of the neck, providing crucial support and preventing strain. The flattened type presents a relatively even surface, an expanded contact surface area is imperative. This design feature distributes pressure evenly across the occipital region, minimizing discomfort and enhancing sleep quality. For the forward-leaning type, a raised front section with a gradual slope is incorporated into the pillow design. This unique structure gently corrects spinal alignment during rest, helping to restore the natural posture and alleviate potential back pain.

      Space extension of clothing materials based on diamond-shaped pleating structure
      MO Yanting, ZHOU Li, CHEN Siyu
      Journal of Textile Research. 2025, 46(08):  191-198.  doi:10.13475/j.fzxb.20240901701
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      Objective Through in-depth study and analysis of the extension characteristics of the diamond-shaped pleating structures in space, an innovative and controllable shaping method is developed. This technology aims to improve the pleat modeling effect associated to traditional pleat design methods and to overcome the difficulty in accurately estimating the amount of fabric required in the design process. This research would not only improve the accuracy of the design, but also optimize the efficiency of fabric use, providing designers with a more efficient and accurate design approach.

      Method Through diamond-shaped pleat-making and digital simulations, the impact of the spatial extension function of diamond-shaped pleats on pleat shaping and fabric consumption was clarified, highlighting the necessity of this research. The single modeling analysis of the key structure of the diamond-shape space extension function was carried out. Through sample experiments and digital models, the influence of key structural values on the spatial extension function of diamond-shaped pleat and the numerical control method in the manufacturing process were discussed. Three groups of diamond-shaped pleat samples were tested to collect the key structures in the samples. On the one hand, the maximum spatial extension prediction and the pleats area fabric usage prediction of the samples were calculated by the modeling method proposed in this paper. On the other hand, the maximum spatial extension measurement value and pleats area fabric usage measurement value were obtained by actual measurement. The correlation between the predicted and measured values of the two sample groups was compared by SPSS to verify the accuracy of the proposed method. Finally, shaping method based on the spatial extension function was proposed after an integrated shaping analysis. Different design cases were studied to prove the feasibility in clothing design.

      Results The numerical settings for valleys, ridges, and amounts of diamond-shaped pleat were crucial for the spatial extension function. Wider pleat wings provided more ease for movement, increasing the spatial extension. The experimental results showed that the diamond-shaped pleat wing was equal to the first step of the double pleat method. The relationship between diamond-shaped pleats ridges and wings worked to determine the maximum spatial extension. When pleat ridge > pleat wing, maximum spatial extension amount = wing width×2×number of pleats, and when pleat ridge ≤ pleat wing,maximum spatial extension amount = ridge length×2×number of pleats. It was also found that when more diamond-shaped pleats were used, more ease for spatial extension in clothing was created. The experiment showed that the amount of diamond-shaped pleats was equal to the pleats amount of double pleat, which is described as (diamond-shaped pleats + 1)×2. Based on the research of the above key structural elements and the clothing design process, the diamond-shaped pleat structure modeling method based on the spatial extension function' is proposed on the basis of the double pleat method. The method was created step by step according to the three steps of setting requirements, quantifying structure and making forming, and the diamond wrinkle data was integrated into the garment making steps. Three groups of diamond-shaped pleat samples were made according to the method proposed in this paper. By comparing the expected value of the maximum spatial extension amount with the measured value, the correlation coefficient between the expected value and the measured value of the fabric consumption in the pleats area, it was seen that the modeling method proposed in this research was accurate. Through the practice of clothing design, the feasibility of this method in practical application was verified.

      Conclusion Compared with the previous traditional methods, this newly developed method can control and adjust more accurately the wrinkle structure according to the specific needs at the early stage of garment production. It can also accurately predict and calculate the amount of fabric required, thereby effectively reducing the cost of conducting experiments and sample preparation. This study provides a more scientific, efficient and practical method for the creative process of pleat design in the field of fashion design.

      Development and performance research of saw-resistant clothing
      WANG Xu, WAN Tengshu, CUI Jing, ZHAO Chunwang, LIU Junwei, HU Kuncai, ZHANG Yichun, XIAO Chaojie
      Journal of Textile Research. 2025, 46(08):  199-208.  doi:10.13475/j.fzxb.20241206201
      Abstract ( 68 )   HTML ( 11 )   PDF (12759KB) ( 8 )   Save
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      Objective The research and development of special protective clothing is of vital importance for ensuring the safety of personnel in high-risk industries. Currently, most of the saw-resistant clothing in China are developed by imitation, which have problems such as poor wearing comfort. To effectively protect the occupational health of practitioners of hand-held electric chain saws, a series of saw-resistant clothing that meet the requirements of both protection and comfort and conform to ergonomics have been developed.

      Method The characteristics of saw-resistant clothing were analyzed and summarized by 86 types of saw-resistant clothing collecting from both domestic and foreign. 6 types of clothing fabric and 6 types of saw-resistant interlayer fabric were selected to compare and analyze their air permeability, moisture permeability, insulation, abrasion resistance, tear strength and saw-resistant performance respectively. The comprehensive performances evaluation of the saw-resistant materials were conducted by the gray near-optimal method in order to select the best garment fabric. 10 male volunteers with body type close to 175/92A were invited to complete the ergonomic evaluation for four types of self-design saw-resistant suit.

      Results It was found that the style variations of the saw-resistant jackets mainly focus on the aspects such as silhouette, collar type, sleeve type, cuffs, pockets and opening design, while the style variations of the saw-resistant pants are mainly reflected in the functional designs such as waist, pockets and knees. To ensure the protective performance of saw-resistant clothing, the outer fabric of saw-resistant clothing usually adopts woven fabric with good wear resistance, and the protective interlayer between the fabric and the lining is made of multi-layer cut-resistant fiber fabric or blocking materials. The research conducts style and structure design based on the design principles of sportswear, and fully considers factors such as wearing occasions and working methods, improving the comfort, functionality and safety of saw-resistant clothing. The comfort and mechanical performance indicators of six kinds of outdoor sportswear fabric were compared in the experiments. It was found that the Cordura fabric had outstanding breathability, moisture permeability, wear resistance and tear resistance, the lowest heat preservation rate, and good heat dissipation effect. The performance of the six kinds of saw-resistant fabric were comprehensively evaluated. It was found that the UHMWPE fabric had the best comprehensive performance. The number of cutting layers of saw-resistant fabric is inversely proportional to its tightness. The greater the tightness of the fabric is, the fewer the number of cutting layers is, and the better the saw-resistant performance will be. The higher the breaking strength and elongation at break of the fibers are, the better the saw-resistant performance of the fabric will be. By comparing the ergonomic test results of four kinds of saw-resistant jacket and four kinds of saw-resistant pants, the movement freedom of saw-resistant jacket is higher than that of saw-resistant pants. Elastic fabric can provide sufficient movement freedom for clothing. The structural design method of continuous cutting of the shoulder and sleeve can reduce the restrictions on arm movement. The comprehensive score of the third type of saw-resistant suit is the lowest which indicates that this type of suit can better meet the ergonomic requirements, and has good sport comfort and activity freedom. This type of saw-resistant suit is almost unrestricted during movement and has a relatively reasonable structural and style design.

      Conclusion This paper focuses on product design from aspects such as functionality, practicality and comfort, and develops saw-resistant clothing that meets the needs of electric chainsaw operators, minimizes potential occupational hazards for practitioners. It provides a theoretical basis for improving the safety protection effect and wearing comfort of anti-cutting clothing, which is conducive to promote the healthy development of the domestic saw-resistant clothing market and provide theoretical support and technical references for saw-resistant clothing manufacturers.

      Pattern generation from 3-D scanned garments for virtual display
      HU Anni, WANG Jie, YANG Wushi, ZHONG Yueqi
      Journal of Textile Research. 2025, 46(08):  209-216.  doi:10.13475/j.fzxb.20241105201
      Abstract ( 91 )   HTML ( 17 )   PDF (6784KB) ( 28 )   Save
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      Objective In the process of performing virtual display-oriented reconstruction based on 3-D scanned garments, pattern generation is crucial for ensuring the accuracy of the 3-D reconstruction model, and it is influenced by the flattening and curve-fitting methods. Therefore, the selection of appropriate methods is pivotal in enhancing the accuracy of the generated 2-D patterns, which in turn enables the reconstruction of highly faithful 3-D garment models.

      Method The study was focused on three types of garments, i.e., the suit jacket, trousers, and skirt. 2-D patterns were generated through a digital process, including scanning, cutting, flattening, and pattern modification. In the flattening process, the optimal flattening algorithm was selected based on the comparison of changes in length and area during the flattening process. Subsequently, comparative experiments were conducted to determine the most effective approach for curve optimization. Building upon these results, the geometric discrepancies between virtual reconstruction results and the original scanned garment results were analysed using 3-D reconstruction techniques.

      Results In the context of flattening methods, the pattern shapes obtained using least squares conformal mapping, boundary-first flattening, and garment flattening(GF) were found generally similar. To quantify the differences, the flattening error was assessed using two metrics, namely, the average relative area difference and the average relative edge length difference between the flattened pieces and the original 3-D surfaces. GF was found to be the superior choice, achieving the lowest average relative area difference and edge length difference values for the right sleeve under panel and the back panel of the suit jacket, indicating minimal flattening deformation. During the pattern optimization process, comparative experiments were conducted on feature point selection and curve-fitting methods. For feature point selection, the vector angle method (sine/cosine) and the Ramer-Douglas-Peucker(R-D-P) algorithm were compared, while for curve fitting, elliptic Fourier descriptors, B-spline curves, and Bezier curves were evaluated. The combination of the R-D-P algorithm and Bezier curves yielded optimal curve-fitting results. In the armhole area of the under panel of the right sleeve of the suit jacket, as well as the armhole and hemline areas of the back panel, the feature points extracted by the R-D-P algorithm were reasonably distributed and demonstrated higher accuracy in capturing curve characteristics, effectively reflecting the curve fluctuations. Additionally, Bezier curves achieved optimal smoothness in the armhole regions of the right sleeve under panel and back panel of the suit jacket. Based on the experimental results, GF was adopted as the flattening method, with feature points extracted using the R-D-P algorithm. Bezier curves were applied to fit pattern edge curves and reconstruct interrupted curves in the pattern symmetry processing, enabling the generation of suit jacket, trousers, and skirt patterns. In the evaluation of 3-D reconstructed model, the virtual reconstruction obtained using CLO3D was overlapped with the original scanned garment model to measure the average deviation of their contours. For simpler styles, such as the trousers and the skirt, the average error between the virtual fitting result and the original scan was approximately 0.3 cm. In contrast, for more structurally complex garments, such as the suit jacket, the average error was 0.774 cm. Overall, these results indicate that the 3-D reconstructed garment models achieve high accuracy.

      Conclusion This paper presents a process for generating high-precision patterns from 3-D scanned garments for virtual display. The experimental results show that it can be successfully applied to the suit jacket, trousers, and skirt, and the reconstructed models obtained through virtual sewing of these patterns exhibited high accuracy, which validates the practical applicability of this approach. Hence, the effectiveness of the proposed method for 3-D garment flattening and 2-D curve optimization was confirmed. The 2D patterns generated through the proposed workflow, can accurately reconstruct garment appearance after undergoing physical engine simulation. This approach provides high-quality virtual garment models for diverse applications, including digital preservation of cultural heritage, film and costume production, and virtual fitting scenarios.

      Machinery & Equipment
      Design and optimization of multi-tip serrated electrospinning nozzle
      LIU Jian, PAN Shanshan, LIU Yongru, YIN Zhaosong, REN Kangjia, ZHAO Qinghao
      Journal of Textile Research. 2025, 46(08):  217-225.  doi:10.13475/j.fzxb.20250100101
      Abstract ( 72 )   HTML ( 7 )   PDF (14498KB) ( 10 )   Save
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      Objective A serrated electrostatic spinning jet exciter has been developed to overcome the problems of easy clogging in conventional electrostatic spinning tips and unstable position of the Taylor cone formation. By increasing the number of tips to excite more spinning jets, this research aims to increase the electrospinning rate to industrial production levels. The sawtooth shape is to be optimized to improve the uniformity of the electric field to ensure stability of the spinning process and uniformity of fiber quality.

      Method The study is based on the theory of jets originating from wave crests and the theory of tip-collected charge, combined with the existing spinning methods. The serrated jet exciter is designed and 3-D models were established using SolidWorks software and electric field simulation using COMSOL software. The effect on the uniformity of the electric field was analyzed by changing the shape and size of the sawtooth. Laser cutting was used to fabricate the serrated nozzle and the spinning solution was formulated using polyacrylonitrile (PAN) powder and N,N-dimethylformamide (DMF) solvent for spinning experiments to verify the spinning.

      Results The electric field simulation results showed that there is a significant ‘End-effect’ in the distribution of electric field intensity in the straight-toothed saw nozzle. Specifically, the electric field intensity was higher at the tips of both sides of the saw and relatively lower in the middle region, and this uneven electric field distribution can lead to resulted in instability in the spinning process and variability in fiber quality. The initial electric field distribution of the nozzle shows a trend of being high at both ends and low in the middle. To make the electric field uniform, the height of the middle sawtooth was increased while reducing the height of the sawtooth at both ends. By using the principle of a circle formation using three points, an arc was drawn through the outer endpoints of the sawtooth at both ends and the tip vertex of the middle sawtooth. The field strength at the tips was reduced by optimizing the design of the circular arc serrated nozzle. The optimized circular-arc serrated nozzles showed generally 2% to 4% lower CV value than that of straight serrated nozzles. Simulation was carried out for different parameters to find the arc model with the best CV value performance, i.e. when the arc height S=13 mm, the number of teeth n=11 and the tooth width c=15 mm, the CV value of the electric field was 6.09% and the electric field intensity was more uniform. Experimental comparison made by observing the jet morphology verified that the number of straight teeth sawtooth for 5 mm jet was less. However, with the ‘end-effect’ fiber whipping entanglement, the phenomenon of flying silk was obvious. The optimized nozzle jet morphology was better and the edge effect problem was greatly improved, evidenced by no flying silk phenomenon and high fiber quality. The Phenom Pure Plus desktop scanning electron microscope was used to observe the appearance of the fibers, and it was found that the fibers were distributed relatively uniformly. Image processing software was used to randomly select fibers for diameter analysis, which showed that the average diameter of the spun fibers was 163 nm with smooth fiber surface, and the diameter of the distribution area is more concentrated. The experimental and simulation results agree to each other, and the simulation data and experimental phenomena have high accuracy and consistency.

      Conclusion In this study, a multi-tip serrated electrostatic spinning nozzle was successfully designed and optimized to improve spinning efficiency and fiber quality by improving electric field uniformity. The optimized circular-arc serrated nozzle has better electric field uniformity compared to the straight-arc serrated nozzle, solves the problem of easy clogging in conventional needles, the jet position is fixed and the shape is more uniform, which provides strong support for large-scale production of electrostatic spinning.

      Consistency detection method for precision parts based on machine learning
      ZHANG Qingyang, ZHU Shigen, BAI Yunfeng, DONG Weiwei, LUO Yilan
      Journal of Textile Research. 2025, 46(08):  226-235.  doi:10.13475/j.fzxb.20250105901
      Abstract ( 64 )   HTML ( 8 )   PDF (3858KB) ( 12 )   Save
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      Objective A large number of precision parts used in knitting machinery, such as main needles and auxiliaries, have irregular shapes and fine structures, but the consistency requirements are extremely high. In order to tackle the inefficiency of manual detection of the consistency of precision parts in the past, as well as the shortcomings of machine vision in the detection of the consistency of precision parts, such as excessive program calculation, sensitivity to image stains, and incomplete overview of effective features of images, a consistency detection method for fine, thin and long parts based on machine learning was proposed.

      Method Based on the principle of machine learning, on the existing glass disc detection device, taking model 104 knitting needle as an example, and two computer languages of LabVIEW and Python were used to design the detection algorithm, and three machine learning algorithms, which are the support vector machine model, the decision tree model, and the K-nearest neighbor model, were used to improve the detecting consistency of the overhead direction of the knitting needle. The aforementioned glass disc detection system consists of the following functional modules: automatic positioning unit, position sensing unit, image acquisition and processing unit, sorting unit.

      Results For the training results of the above three machine learning models, the accuracy of the support vector machine model is 93%, the accuracy of the support vector machine model is 97%, and the accuracy of the KNN model is 88%. The number of sample images required to train the above three models is 600, including 300 qualified sample images and 300 unqualified sample images, and the ratio of the training set to the test set is 7∶3. For validation of the machine learning algorithm's performance in top-view orientation consistency detection of knitting needles, implementation and operation of the ML-based detection program on the target inspection system is mandatory. First, 700 knitting needles were tested once by manual detection, and the qualified needles and unqualified knitting needles were distinguished by a qualified template, and then the machine learning method was used to detect and compare the effects of manual detection and machine learning algorithm. Of the 700 needles manually tested, 272 were qualified and 428 were unqualified, with a detection speed of 10 needles per minute. The 700 needles were inspected in a single pass using machine learning. 271 qualified knitting needles were detected, of which there was no unqualified knitting needle mixing, and the false detection rate was 429 unqualified knitting needles were detected, of which 1 qualified knitting needle was mixed, the missed detection rate was 0.37%, the missed detection rate was low, and the detection speed was 60 needles per minute. According to previous research, the accuracy rate of using machine vision to detect knitting needles is 99%, and the average detection rate of qualified products is 84% in one progressive inspection, that is, the missed detection rate is 16%, and the detection speed is 70 pieces per minute. Compared with manual detection, machine vision detection, and machine learning detection, the missed detection rate of machine learning is greatly improved compared with machine vision, and the detection speed is greatly improved compared with manual inspection, but the detection speed of machine learning is not as good as that of machine vision.

      Conclusion Using the machine learning based fine thin and long parts sorting method, the knitting needle detection consistency is carried out, the false detection rate of unqualified knitting needle is 0, and the missed detection rate of qualified knitting needle is 0.37%, which can better meet the requirements of industrial production detection, and has a great improvement in the detection speed compared with manual detection, and has a great improvement compared with machine vision in terms of missing detection rate, wherein the better model obtained during training is the decision tree, and the model accuracy is 97%. In conclusion, in order to further improve the detection efficiency of fine and long parts, a sorting method of fine and long parts based on machine learning was studied, and the machine learning model was used to reduce the missed detection rate of consistency detection and improve the accuracy of detection, which provided an effective method for the consistent sorting of fine thin and long parts.

      Compreshensive Review
      Research progress in color construction of polypropylene fibers and its products
      LIN Ke, HU Wanjin, WANG Xiaofeng, ZHOU Sijie, XIA Liangjun, XU Weilin
      Journal of Textile Research. 2025, 46(08):  236-244.  doi:10.13475/j.fzxb.20250106902
      Abstract ( 90 )   HTML ( 15 )   PDF (3428KB) ( 26 )   Save
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      Significance Polypropylene (PP) is widely used in industries such as textile and clothing due to its excellent properties such as light weight, wear resistance, and low cost, and it occupies an important position in the development of the national economy. For the purpose of expanding the application fields of PP and promoting the development of its products, the demand for the color structure of PP fibers has become a crucial impetus for the development of a colorful society. Reports show that in the future, PP fibers will pervade and thrive in different fields of life for a long time, which is an indispensable part of social progress. The integrated color construction of PP fibers represents an ideal way to achieve high flexibility and adaptability. In order to clearly understand the development and application of PP fibers and break through the bottleneck of dyeing technology, this paper reviews the research progress in the fields of color structure and products of PP fibers.

      Progress Based on the structural characteristics, physical and chemical properties of PP fibers, innovations have been made in aspects such as the molding process, dyeing medium, fiber modification, and dyeing process, so as to achieve color processing and construction. Based on the progress made in chemical coloring technologies such as dope dyeing, non-aqueous medium dyeing, modified dyeing, and special dye dyeing, endowing PP fibers with good color display is fundamental for color construction on the premise of maintaining the mechanical properties of PP fibers. However, many promising coloring methods have obvious limitations in industrial production. Due to the high crystallinity and high chemical inertness of PP fibers, conventional dyeing methods cannot effectively color them. Currently, dope dyeing is the most commonly used coloring method for PP fibers. This dyeing method is simple to operate and cost-effective, being suitable for industrial production. However, it has the defect of incomplete chromatography. In addition, the non-aqueous medium (supercritical carbon dioxide, scCO2) dyeing method is also a relatively commonly used coloring method for PP fibers, and its advantages lie in fast coloring speed and good coloring effect, but the relatively stringent dyeing conditions have restricted its development. Modified dyeing and special dye dyeing methods have promising prospects and can significantly improve the dyeing performance of PP fibers. However, they are still in the stage of laboratory research and face some difficulties in large-scale production.

      Conclusion and Prospect PP, as a widely used polymer material, has been extensively applied in numerous fields due to its excellent physical and chemical properties. However, the difficulty in dyeing has always been a key factor restricting the expansion of its application fields. Aiming at the problem of difficult dyeing, coloring methods such as dope dyeing, non-aqueous medium dyeing, fiber-modified dyeing, and special-dye dyeing have been improved. Based on the current PP coloring technologies, the future development trends will focus on enhancing dyeing efficiency and deepening color depth performance, such as using more efficient non-aqueous dyeing systems, developing specialized dyes and exploring innovative modification process paths. Meanwhile, further theoretical research on the color construction of PP fibers is still needed. By integrating chemical structure, surface physical properties, and chemical reactivity, innovations in color formation mechanisms can be achieved. Specifically, this is done by designing dyes with higher reactivity towards PP or employing nanoparticle blending technology for PP modification to enhance dye absorption efficiency. This framework provides theoretical guidance for the rational preparation of colored PP fibers. Building upon this, the paper mainly summarizes the basic principles and research progress of the above-mentioned PP fibers, and points out the main challenges and research directions faced by this research field.

      Research progress in preparation, modification and application of polyphenylene sulfide film
      REN Tianxiang, CHEN Jiangbing, FANG Taorong, ZHAN Yingtao, HONG Yujie, XU Zhiqiang, XU Yudong, ZHAN Haihua
      Journal of Textile Research. 2025, 46(08):  245-253.  doi:10.13475/j.fzxb.20240900702
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      Significance Polyphenylene sulfide (PPS) film is an exceptional thermoplastic engineering plastic, characterized by a macromolecular chain structure that combines rigid phenylene rings with flexible thioether linkages. This unique combination endows the material with outstanding thermal resistance, flame retardancy, dielectric properties, and mechanical strength. Consequently, the application of PPS films has become increasingly widespread in high-end technological fields such as new energy vehicles, electronics, and aerospace. In recent years, driven by the inherent electrical insulation properties and relatively low surface chemical reactivity of PPS films, as well as the demand for high-performance functional film materials, researchers have conducted extensive studies on the preparation, modification, and application of PPS films.

      Progress The raw material used for PPS film fabrication is a linear-structured resin with higher molecular weight and enhanced thermal stability. This study systematically elucidates the effects of extrusion casting and extrusion blow molding on the structure and properties of PPS films and provides a comparative analysis of the performance of uniaxially and biaxially stretched films. The influence of carbon nanotubes, graphene, and their derivatives as nanofillers on the electrical conductivity of PPS films is investigated, along with a detailed discussion of the conduction mechanisms of carbon-based materials within the PPS matrix. From the perspective of modification mechanisms, the effectiveness of plasma treatment in enhancing surface roughness and chemical activity is analyzed in depth. A comparative analysis is conducted on the principles and effects of low-temperature plasma modification and atmospheric-pressure plasma modification. Additionally, recent advances in the functional modifications of PPS films, including antibacterial, UV-resistant, and superhydrophobic properties, are explored. A comprehensive review is provided on the applications of PPS films in capacitors, sensors, and composite materials. Specifically, the dielectric breakdown resistance and self-healing characteristics of PPS films are analyzed, and their applications in phosphorescent oxygen sensors, fiber-optic acoustic sensors, and biomedical sensors are further introduced. PPS-based composite materials are further categorized into lightweight metal/PPS film composites, glass fiber/PPS film composites, and carbon fiber/PPS film composites. Finally, the future research directions and development prospects of PPS films are discussed.

      Conclusion and prospect As a high-performance specialty engineering plastic, PPS has become a critical strategic material for the modernization of traditional industries and the advancement of high-end technologies worldwide. Given the challenges associated with PPS resin, including its high melting temperature, rapid crystallization rate, and relatively low melt viscosity stability, the combination of extrusion casting and biaxial stretching has been established as a mature technology for the large-scale production of high-performance PPS films. To further enhance the properties of PPS films and expand their application scope, extensive research efforts have been directed toward their electrical conductivity modification, surface activity modification, and multifunctional enhancement. The incorporation of carbon-based fillers, such as carbon nanotubes and graphene, has been demonstrated to effectively improve the electrical conductivity of PPS films, while the uniform dispersion of these carbonaceous materials within the PPS matrix is crucial for ensuring the long-term stability of the film’s electrical properties. Plasma treatment has shown significant potential in enhancing the hydrophilicity and chemical reactivity of PPS film surfaces. Future research could explore the application of atmospheric-pressure plasma modification techniques in PPS film surface engineering, thereby accelerating its industrialization. Additionally, achieving a balance between material performance and sustainability is essential when pursuing multifunctional modifications of PPS films. Currently, PPS films have found widespread applications in advanced fields such as capacitors, sensors, and composite materials. Future research should focus on enhancing the high-temperature resistance, dielectric breakdown strength, self-healing capabilities, and overall stability of PPS films. Furthermore, greater attention should be given to the development of glass fiber/PPS film composites and carbon fiber/PPS film composites for applications in sports equipment, electronic devices, and new energy vehicles. As a next-generation material for both traditional industry modernization and cutting-edge technology development, PPS films hold significant potential for future applications.

      Review and future perspectives of waterproof and moisture permeable nanofiber composite fabrics
      MA Xiaoyuan, BAO Wei
      Journal of Textile Research. 2025, 46(08):  254-262.  doi:10.13475/j.fzxb.20241103802
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      Significance Popular participation in outdoor activities has led increased demand of outdoor jackets. In various environments, waterproof and moisture permeable fabric plays an important role in maintaining a comfortable micro-environment between human body and clothing. A variety of technologies has been developed for manufacturing waterproof and moisture permeable fabrics such as high-density fabrics, coated fabrics and laminated fabrics. As laminated fabrics, the traditional materials like GoreTex have dominated the market but still face the environmental challenges due to fluorinated compounds and high production costs. Nanofiber composite fabrics have the advantages of simple production process, high porosity, and light weight, and the multi-layer structure offers a solution by enabling simultaneous water resistance and rapid moisture transport. Nanofiber composites fabrics (NCFs) with fluorine-free materials also enhances sustainability, aligning with the demands for eco-friendly outdoor apparels.

      Progress The preparation of nanofiber composite fabrics (NCFs) involves the preparation of nanofiber membranes (NMs), the composite of membranes and base fabrics. All various nanofiber membranes, fabrics and composite methods could affect the performance of NCFs. NMs present microporous structures with controllable pore size. However, many conventional NMs show low water resistance due to their poor hydrophobicity. To solve this problem, fluorinated compounds were introduced onto the nanofibers to achieve low-surface-energy surfaces. However, fluoropolymers are harmful to the environment and the biological systems, because of this they have been restricted in recent years. As a result, researchers have been increasingly studying on fluorine-free low-surface-energy additives. For example, SiO2 nanoparticles were introduced on the NMs and enhance the waterproofness, but the durability performance was also needed to improve. In fact, to optimize the composite process of NMs and base fabric can enhance the durability the NCFs, but the waterproof property and moisture permeability could be lowered. It was reported that a heat thermal induction process could increase the adhesive structure in the membrane, but the waterproof property was decreased. To summarize, the current research usually solves local problems of NCFs, and it is difficult to achieve the balance of waterproof, moisture permeability, sustainability and durability. In recent years, electrospinning technology was developed for application. For example, Ecobreath prepared NCFs using PFCs-free NMs, which has good waterproof property and moisture permeability. Besides the properties mentioned above, additional functions such as antibacterial, stain resistance and UV resistance were also studied in recent years.

      Conclusion and Prospect Waterproof and moisture permeable nanofiber composite fabrics have the potential for application in outdoor functional clothing, but its development and application are limited due to its poor durability and mechanical properties, fluoropolymer pollution. To be waterproof and moisture permeable, green, multifunctional, and durable is the developing trend of NCFs for outdoor functional clothing in the future. Most of the current studies only focused on optimizing a specific performance, but it is difficult to balance the waterproof, moisture permeability and the properties mentioned above. Therefore, the future study should consider the integrity of the NCFs system to achieve balanced optimization and multi-scenario applications. Briefly, the further study could be developed based on the integrity of the NCFs system from the following aspects. One thing is to improve the mechanical properties of NMs by polymer doping modification and surface coating treatment. The second is to replace fluoropolymer with Fluorine free materials such as silicon-based materials to make it cleaner production and application. Thirdly, the base fabric of NSFs is scientifically designed to achieve moisture permeability, and to finish the fabrics to achieve multi-functions such as waterproof, anti-ultraviolet and anti-bacterial properties. The last thing is to optimize the composite process of NMs and base fabric to enhance the durability of NSFs. The application of improved NCFs would be helpful for the enhancement of outdoor clothing comfort and functionalities.

      Research progress in clothing resistance moment for assessment of human performance and ability
      CUI Wen, WANG Yunyi, DAI Yanyang, LI Jun
      Journal of Textile Research. 2025, 46(08):  263-271.  doi:10.13475/j.fzxb.20240802102
      Abstract ( 65 )   HTML ( 13 )   PDF (3885KB) ( 14 )   Save
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      Significance Protective clothing is used to resist the threat of external flames, ammunition and other threats. However, the bulkiness of the protective clothing will hinder wearer’s mobility and hence performance. The existing evaluation methods for human performance and ability are vulnerable to individual differences in physical fitness and muscle strength, and there is a lack of objective and stable evaluation indicators. Clothing resistance moment refers to the hindrance of clothing to human joint movement, relevant research of which has made remarkable progress. This paper reviews and analyzes the existing evaluation methods and their shortcomings, as well as discusses the influencing factors and applications of clothing resistance moment in research of human performance and ability.

      Progress At present, collecting job progress and physiological load index when performing simulated job tasks are the most common evaluation methods for human performance and ability. Job progress and difficulty evaluation are a direct evaluation method for the job itself. Physiological load assessment reflects a person's ability to continue working and potential occupational health risks. The clothing resistance moment is connected with each evaluation metrics. It is mainly affected by the mechanical properties of material, the weight, looseness and detailed structure of clothing. Previous research in functional clothing has led to two types of measurement methods for clothing resistance moment, namely the calculation method based on contact force and measurement method based on the use of equipment. The former uses mechanical sensors or simulation software to measure the contact force between the wearer and clothing, and then convert it to resistance moment, and this method is widely used in tight and stiff clothing. The latter uses test equipment that simulates human activity to measure the clothing resistance moment directly. There are two types of clothing resistance moment test equipment, one is dummy/hand test device and the other is a single joint test device. The dummy device could only test one single size garment, but simulate the contact process between human and clothing. The single joint test device could match various sizes of protective clothing, but the results can only represent the torque required to bend the joint of garment through external forces in an unmanned state. Some studies established the coupling model of human body and clothing to predict the muscle force based on reverse dynamics simulation. Researchers also used clothing resistance moment to predict personnel performance based on statistical analysis.

      Conclusion and Prospect At present, due to the limitations of evaluation methods and numerous factors of clothing affecting human performance and ability, the current research is still in the qualitatively exploratory stage. In order to build a stable and reliable evaluation method, further research orientations are proposed. Firstly, clothing resistance moment is a physical clothing characteristic parameter and closely related to all indicators of human performance and ability. Therefore, it can be used as a representative index of clothing mobility for unified judgment of human performance and ability. Secondly, the existing research on the impact of protective clothing are limited to the discussion of a single variable, hence lacking in analysis of the comprehensive effect of multiple factors. As a numerical intermediate variable, the clothing resistance moment can quantitatively guide the ergonomic performance design of protective clothing from the perspective of reducing the resistance moment. Thirdly, it is necessary to put forward more accurate and operable evaluation methods for clothing resistance moment. As for the contact force based calculation method, soft matrix pressure sensors can be considered for measuring distribution of pressure. Regarding the device based measurement method, the compression and friction characteristics of human skin should be simulated to optimize the existing measurement dummies. Finally, due to different experimental conditions and subjects set up in research, it is difficult to quantitatively estimate the influence of protective clothing on job effectiveness. The application of nonlinear models or other empirical formulas and statistical methods can be explored in the prediction of physical exertion or fatigue, so as to avoid the influence of individual differences on the prediction accuracy. Musculoskeletal model with the clothing resistance moment as the external load can also be constructed to analyze the dynamic response of wearers.