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    15 September 2025, Volume 46 Issue 09
        
    • Academic Salon Column for New Insight of Textiles Science and Technology: Camouflage and Electromagnetic Shielding Technologies and Applications
      Preparation and properties of flexible infrared stealth films based on polyaniline
      WU Jinyao, ZHONG Yi, ZHANG Linping, XU Hong, MAO Zhiping
      Journal of Textile Research. 2025, 46(09):  1-8.  doi:10.13475/j.fzxb.20250304001
      Abstract ( 159 )   HTML ( 40 )   PDF (11198KB) ( 87 )   Save
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      Objective The continuous improvement of detection technologies presents significant challenges to stealth technology, getting more attention on the development of efficient infrared stealth technology. Polyaniline (PANI) offers an innovative approach with its unique electrochromic properties, low cost, low infrared radiation emissivity and easy processing. However, the practical application of PANI is hampered by problems such as poor flexibility, fragility, and easy peeling, and the application of its coatings is affected by high emissivity binder, which greatly limits its application in wearable devices. In order to realize the full potential of PANI, material properties must be optimised to address these limitations. In this research, the polyimide (PI) film and nanoporous polypropylene (nanoPP) films and were selected as the substrate to fabricate the flexible infrared stealth films.

      Method Intrinsic state polyaniline was synthesized by chemical oxidative polymerization and subsequently doped with camphorsulfonic acid (CSA) through sufficient grinding at a molar ratio of 1∶0.8. The mixture was then stirred in an m-cresol solution for 48 h to obtain low-emissivity polyaniline coatings (PANI-CSA). The selected PI film and nanoPP films with a thickness of 16 μm (nanoPP16), and a thickness of 25 μm (nanoPP25)) were thoroughly washed with anhydrous ethanol and dried. The PANI-CSA coatings were uniformly applied to the films at a controlled height of 42 μm using a spatula and dried naturally at room temperature, hence obtaining the flexible low-emissivity films: polyaniline coated PI film (PANI/PI), polyaniline coated nanoPP16 film (PANI/PP16), and polyaniline coated nanoPP25(PANI/PP25).

      Results The morphologies and structures of PI, nanoPP16, nanoPP25, PANI/PI, PANI/PP16 and PANI/PP25 films were analysed using SEM images. Among them, nanoPP16 shows flat, interconnected slit-like porous structure with concentrated and regular pore size distribution. According to the particle size of the PANI-CSA coating (45.06 nm), the polyaniline can follow the solvent to enter into the pores of the film, and through the synergistic effect of mechanical interlocking effect and intermolecular van der Waals' force, the PANI/PP16 film has smooth, low-emissivity surfaces without the use of high emissivity binders. Infrared reflectance and emissivity tests show that PANI/PI, PANI/PP16 and PANI/PP25 films all have low infrared emissivity and meet the requirements for infrared cloaking. Notably, PANI/PP16 has the lowest emissivity (0.21), which is attributed to its moderate pore size, which allows for deeper penetration of the polyaniline and avoids agglomeration during drying. In a 60 min infrared stealth monitoring experiment using an infrared camera, PANI/PI initially showed good stealth performance, but the effect became uneven over time, with the emissivity temperature rising to 30.2 ℃ after 20 min and losing its stealth capability completely after 30 min. In contrast, PANI/PP16 maintains excellent infrared stealth performance, with the surface radiation temperature stabilised at 23-24 ℃ in 60 min, which effectively masks the human body temperature and meets the requirement of long-time stealth. Thermal stability analysis shows that PANI/PP16 can be used in infrared stealth scenarios up to 240 ℃. The unique properties of nanoPP16, including its porous structure and flexibility, not only improve the adhesion and uniformity of polyaniline coatings without the use of binders, but also solve the brittleness problem usually associated with rigid polymers such as polyaniline. This combination of structural and functional advantages makes PANI/PP16 an ideal candidate for applications requiring long-lasting and effective infrared cloaking capabilities. These findings highlight the importance of substrate selection and structural design in optimising the performance of polyaniline coatings for advanced cloaking applications.

      Conclusion The results show that the PANI/PP16 film has an emissivity as low as 0.21 in the mid-infrared band (8-14 μm) and maintains excellent infrared stealth performance for up to 60 min, with a radiant temperature difference of 9-10 ℃ from the palm of the hand, which allows the human body to be hidden from the environment. It is also thermally stable and can be used for infrared cloaking in scenarios up to 240 ℃. Additionally, the film has excellent flexibility, which successfully overcomes the problems of poor flexibility, fragility and flaking of pure polyaniline film, and effectively avoids the influence of conventional high emissivity binders on the overall stealth effect of the material This study provides a new approach for the application of polyaniline in the field of wearable infrared stealth materials

      Structure and electromagnetic response properties of glass-coated magnetic amorphous alloy fibers
      JI Hui, XIAO Hong
      Journal of Textile Research. 2025, 46(09):  9-18.  doi:10.13475/j.fzxb.20250306301
      Abstract ( 129 )   HTML ( 13 )   PDF (11315KB) ( 68 )   Save
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      Objective With the rapid advancement of wireless communication technologies, radar systems and electronic devices, the development of high-performance electromagnetic absorbing materials has become a crucial research direction in the field of functional materials. Among various absorbing material systems, the intrinsic properties of wave-absorbing agents, as the core functional component, play a decisive role in determining the overall electromagnetic wave absorption performance of the materials. Glass-coated magnetic amorphous alloy fibers (GMAFs), as a material with a special structure and multiple loss mechanisms, has gradually attracted the attention of researchers. However, the current research work on GMAFs in the field of wave absorption is limited to the basic characterization of the electromagnetic properties of composite materials.

      Method Based on the analysis of the physical characteristics and electromagnetic properties of GMAFs, this paper reports the design of different configuration states, preparation of single-layer absorbing samples, and systematic studies of the physical properties of GMAFs and their electromagnetic response mechanisms under different conditions. It focuses on discussing the influence of factors such as the continuity of fibers, distribution state, line density parameters, core layer composition, structural features, and crystal state on the performance of the GMAFs. Meanwhile, by comparing and analyzing the absorbing performance of different fiber-based absorbing materials, the unique advantages of GMAFs are deeply revealed.

      Results This study systematically reveals the structure-activity relationship between the electromagnetic response characteristics and physical properties of GMAFs. GMAFs integrate the superior magnetic/dielectric properties of amorphous soft magnetic alloys, their distinctive amorphous microstructure, the insulating properties of the glass coating layer, and remarkable fiber anisotropy, demonstrating multiple electromagnetic wave dissipation mechanisms that reveal broad application prospects in microwave-absorbing materials. Experimental results indicate that chopped GMAFs not only exhibit outstanding electromagnetic absorption performance, but their random distribution characteristics also impart macroscopic isotropy to the material, highlighting significant potential for engineering applications. By precisely tuning the fiber diameter and composition, the resonance peak and absorption frequency band can be effectively adjusted. Both the glass coating and the soft magnetic amorphous alloy properties contribute to optimizing impedance matching and absorption efficiency. Further investigation into the electromagnetic response characteristics of GMAFs confirms their multi-mechanism attenuation capability, establishing them as high-performance microwave absorbers suitable for absorbing structures. These findings provide a crucial research foundation for tailoring the electromagnetic properties of GMAF-based composite absorbing fabrics.

      Conclusion The research indicates that orderly arranged C-GMAFs possess directional reflection characteristics and are suitable for electromagnetic shielding materials, while randomly distributed GMAFs exhibit macroscopic isotropic absorption behavior. By adjusting parameters such as fiber fineness and composition, the resonant peak and absorption frequency band can be precisely regulated, achieving tunable functionality of the material. The unique core-sheath structure of GMAFs effectively blocks electrical connections between fibers, optimizes impedance matching, and enhances loss efficiency. After annealing and crystallization of the amorphous structure, the absorption performance of GMAFs significantly declines, confirming the crucial role of the disordered atomic arrangement in amorphous state in dielectric/magnetic loss. At the same addition amount, the absorption efficiency of GMAFs surpasses that of the conventional stainless steel fibers and FeNi fibers, highlighting its lightweight advantage. With its tunable electromagnetic response characteristics and high compatibility with textile fibers, GMAFs offer the possibility of breaking through the performance limits of the conventional materials for next-generation smart textiles and electromagnetic protective textiles, and are expected to achieve engineering applications in military stealth, 5G/6G communication protection, medical electromagnetic safety, and other fields.

      Preparation and properties of thermochromic camouflage fabrics simulating color changing of leaves
      ZHAO Jieqing, WANG Zhen, QIN Xiaotian, WANG Chengcheng, ZHANG Liping
      Journal of Textile Research. 2025, 46(09):  19-26.  doi:10.13475/j.fzxb.20250301501
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      Objective Conventional camouflage is achieved by the use of camouflage net or camouflage clothing with static color patterns. Although it can provide a certain camouflage effect for specific environment, it is difficult for it to adapt to complex and changeable environment. In order to overcome the disadvantage that static camouflage is easy to be identified in a changeable background, a study on adaptive discoloration camouflage fabrics was proposed, aiming to respond quickly to external changes and intelligently adjust its own characteristics to achieve a high degree of integration with the background.

      Method In order to solve this problem, a new type of fluorane dye was designed and synthesized, and a highly sensitive two-component thermochromic system was prepared by physical blending of the fluorane dye and a phase change material. Microcapsule packaging technology was adopted to maintain the thermoal stability at high temperature, so as to provide the basis for realization of fast response discoloration camouflage. The thermochromic paste which can be used in natural environment camouflage was prepared by compounding discoloration microcapsules with ordinary disperse dyes in different proportions, and was screen printed on fabrics to produce thermochromic intelligent textiles.

      Results The molecular structure of the dye was characterized and analyzed by 1H NMR and high resolution mass spectrometry, and the apparent morphology and particle size of thermochromic microcapsules were observed by polarizing microscope and scanning electron microscope. The results showed that the sample was regular spherical, the surface was relatively smooth, and the average particle size was about 12 μm. The thermal stability and melting-crystallization properties of thermochromic microcapsules were also investigated. The thermogravimetric characteristic peaks of thermochromic microcapsules appeared at 220-340 ℃ and 360-500 ℃, corresponding to the thermal decomposition of core material composite and shell material polymethyl methacrylate (PMMA), respectively. The results showed that PMMA successfully encapsulated the thermochromic compound in the microcapsule and had a certain protective effect.

      The micromorphology of ordinary polyester/cotton fabric and thermochromic cotton fabric was characterized by scanning electron microscope. The surface of the original polyester/cotton fabric was smooth, while the surface of the polyester/cotton fabric after layer printing was rough and the surface morphology changed obviously. A large number of microcapsules was attached to the surface of the fabric. In addition, the color performance of the fabric was explored. With the increase of the amount of thermochromic paste in the compound color paste, the fabric gradually turned yellow, the K/S value gradually decreased. The fabric color demonstrated an obvious lighter trend, which was kept stable when it reached a certain proportion. Secondly, owing to the increase of thermochromic paste, the response of the fabric to temperature change became more sensitive and more obviously. The discoloration cycle of the fabric was also tested, and the fabric showed excellent reversible discoloration performance in 100 cycles of rising and falling temperature. The camouflage fabric designed by screen printing was compared with the vegetation in nature, showing a good camouflage effect.

      Conclusion A highly sensitive fluorane dye was designed and synthesized. The compound prepared by mixing with phase change material (tetradecyl alcohol) achieved color transformation at 2.5 ℃, and thermochromic microcapsules were prepared by solvent volatilization method. Using disperse dyes and thermochromic microcapsules as colorants, different proportions of green-yellow thermochromic pastes were prepared and finished on polyester/cotton fabrics by screen printing. With the increase of the ratio of thermochromic microcapsule pastes to disperse dye pastes, the color difference of the fabric before and after discoloration gradually increased. The discoloration range of the fabric is 35-37 ℃, still maintaining a narrow discoloration temperature range. After 100 discoloration cycles, the performance of the fabric kept consustancy, and the natural leaf color was successfully simulated. The material mainly realizes the change of its own color by adjusting the temperature, and has a color similar to that of different vegetation (such as green, yellow), which breaks the limitation of fixed color in traditional anti-reconnaissance methods and improves its applicability in different environments.

      Polyethylene-derived carbon fiber fabrics for electromagnetic interference shielding
      LIANG Rui, LI Zhong, TONG Weihong, YE Changhuai
      Journal of Textile Research. 2025, 46(09):  27-35.  doi:10.13475/j.fzxb.20250206201
      Abstract ( 134 )   HTML ( 16 )   PDF (16239KB) ( 52 )   Save
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      Objective In order to overcome the dual constraints of inefficient resource recovery and persistent ecological impacts from polyethylene textile waste, this study explores the recycling of polyethylene (PE) fabric waste, a low-cost and widely used polymer, into high-conductivity carbon fiber fabrics via a simple sulfonation-induced crosslinking reaction and high-temperature charring process. The resulting carbon fiber fabrics are designed to achieve enhanced EMI shielding performance, providing an eco-friendly solution that simultaneously addresses plastic waste reduction and EMI shielding.

      Method Polyethylene (molecular weight of 1 500 000) woven fabric was used as the carbon precursor. The sulfonation reaction was conducted using sulfuric acid at 130 ℃ for 3-9 h. After sulfonation, the fabric was thoroughly washed with deionized water and acetone, then vacuum-dried at 80 ℃. Charring was carried out in an argon atmosphere by heating the fabric at a rate of 10 ℃/min to 400 ℃, followed by further heating to 800-1 000 ℃. The morphology and structure of polyethylene-derived carbon fiber fabrics were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and Raman spectroscopy. The electrical conductivity was measured using a four-point probe method, while the EMI performance was evaluated through vector network analysis in the 8.2-12.4 GHz frequency range.

      Results The study revealed that sulfonation time significantly impacted the structural integrity of the fabric. An optimal duration of 6 h was identified, while prolonged sulfonation (up to 9 h) progressively loosened the woven structure and caused fiber breakage. This was attributed to the incorporation of sulfonic acid groups and subsequent fiber swelling. SEM observations showed that fibers treated for 3 h exhibited hollow interiors due to insufficient crosslinking, whereas 6-h sulfonated samples maintained their structural integrity. The prolonged sulfonation for 9 h caused deformation of the fabric structure, indicating excessive cross-linking. EDS mapping confirmed sulfur enrichment within the fabric, validating the successful sulfonation process. XRD analysis revealed a gradual attenuation of the characteristic PE crystalline peak at 2θ=21.5°, indicating the dissociation of the crystal structure due to molecular chain irregularity and solvent penetration. The charring process demonstrated strong dependencies on sulfonation duration and temperature. The carbon yield at 900 ℃ increased from 17% for the 3-h sulfonated fabric to 38% for the 9-h sulfonated fabric. However, a higher charring temperature of 1 000 ℃ led to reduced mass retention, likely due to the collapse of the carbon skeleton. Charring temperature significantly influenced the electrical conductivity, with the 1 000 ℃ charred sample achieving 321.8 S/m, compared to 36.2 S/m at 800 ℃. The EMI shielding effectiveness in the X-band also increased with higher carbonization temperatures. A 1 mm-thick sample exhibited a shielding effectiveness of 34 dB, while a 3 mm-thick sample reached 87 dB, demonstrating the material's enhanced electromagnetic wave attenuation capability. The improvement was attributed to the improved graphitic microcrystallites of the carbon fibers and the formation of robust conductive networks maintained by the well-preserved textile structure. The charred fabric exhibited excellent EMI shielding performance, effectively reducing electromagnetic wave transmission, making it a promising candidate for lightweight and flexible EMI shielding applications.

      Conclusion This study successfully demonstrated that polyethylene woven fabric can be transformed into high-performance carbon fiber fabric for EMI shielding through sulfonation-induced crosslinking and charring. The results highlight carbonization temperature, sulfonation time, and fabric thickness as key factors influencing electrical conductivity and shielding effectiveness. The excellent EMI shielding performance of the carbonized fabric is primarily attributed to the formation of highly conductive carbon fiber networks, which enhance the reflection and attenuation of electromagnetic waves. These findings present a sustainable and cost-effective approach for recycling polyethylene fabric waste into efficient EMI shielding materials. Future research could explore the mechanical property optimization and scalable fabrication of polyolefin-derived carbon fabrics to meet the growing demand for low-cost, high-performance, and flexible EMI shielding materials in modern society.

      Progress in structural design of cellulose-based composites for electromagnetic interference shielding
      TANG Chunxia, WANG Yifan, MAO Yunshan, LIU Jian, FU Shaohai
      Journal of Textile Research. 2025, 46(09):  36-45.  doi:10.13475/j.fzxb.20250206802
      Abstract ( 238 )   HTML ( 15 )   PDF (9381KB) ( 46 )   Save
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      Significance This study focuses on the development of cellulose-based composite materials for electromagnetic interference (EMI) shielding, addressing the growing demand for lightweight and high-performance shielding materials in the era of 5G and beyond. With the rapid advancement of electronic technologies, including 5G communication, wearable devices, and autonomous driving, electromagnetic pollution has become a significant concern, posing risks to both human health and the functionality of electronic devices. Conventional metal shielding materials are limited by their high density and susceptibility to corrosion, making the development of alternative, sustainable, and multifunctional materials of utmost importance. Cellulose nanofibers (CNFs) offer a promising solution by virtue of their low density, high strength, flexibility, and renewable nature. This review highlights the structural design strategies of CNF-based composites and their impact on EMI shielding performance, providing new insights for the development of next-generation shielding materials.

      Progress This paper comprehensively reviews the latest research progress in the structural design of CNF-based composites for EMI shielding. Single-layer, bilayer, and gradient structures of films and porous materials are discussed, along with their impacts on EMI performance. Single-layer structures have been widely studied for their simplicity and ease of fabrication. However, they often face limitations in achieving optimal impedance matching and high absorption efficiency by virtue of their uniform material distribution. In order to overcome these limitations, bilayer designs have been developed, which strategically combine conductive and magnetic layers to improve impedance matching and absorption capabilities. These designs leverage the synergistic effects of different material layers to enhance overall shielding performance. Gradient structures, inspired by natural systems, introduce gradual impedance transitions and multiple reflection/absorption pathways. By varying the composition and arrangement of materials within the structure, these designs can achieve ultra-low reflection coefficients and excellent shielding efficiency across broad frequency ranges. Porous materials, particularly aerogels, have also been extensively explored for their high porosity and lightweight nature. These materials enhance EMI shielding by extending the propagation path of electromagnetic waves through multiple reflections and absorptions within the porous network. Research has shown that optimizing the pore structure and incorporating conductive fillers can significantly improve the shielding effectiveness of aerogels while maintaining their low density. These innovations demonstrate the potential of CNFs-based composites to meet the diverse requirements of modern electronics through structural optimization and material integration.

      Conclusion and Prospect The development of CNF-based composite materials for EMI shielding has achieved notable advancements, with various structural designs significantly enhancing shielding performance. However, several challenges remain. Current systems often exhibit high reflection coefficients, leading to potential secondary electromagnetic pollution, which is a critical issue that needs to be addressed. Future research should focus on improving impedance matching and reducing reflection losses to minimize secondary pollution. Additionally, enhancing the mechanical properties and durability of these composites is essential for practical applications. This includes optimizing the structural design to improve the composite's resistance to deformation and degradation over time. The development of low-reflection materials through advanced structural designs, such as asymmetric gradient structures and multi-layered composites with tailored material compositions, will be a key direction for future research. Exploring intelligent responsive structures that can adapt to varying electromagnetic environments will also be crucial. These structures could potential offer dynamic control over shielding properties, making them suitable for a wider range of applications. Furthermore, enhancing the structural integrity and long-term performance of composites under stress, through optimized fabrication processes and the incorporation of reinforcing agents, will be vital for their widespread adoption. Overall, continued innovation in structural design and material composition will be pivotal in advancing cellulose-based electromagnetic shielding materials, paving the way for their integration into emerging technologies, particularly in lightweight and flexible electronic devices.

      Fiber Materials
      Fabrication and properties of polyamide 6-based elastomers and their side-by-side elastic fibers
      LI Yujie, WANG Chengqin, WANG Wei, YUAN Ruchao, YU Jianyong, LI Faxue
      Journal of Textile Research. 2025, 46(09):  46-56.  doi:10.13475/j.fzxb.20241206601
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      Objective This study aimed to address the inherent elasticity limitations of polyamide 6 (PA6) fibers by combining intrinsic elasticity through block copolymerization and morphological elasticity through side-by-side spinning. The research is focused on developing high-strength polyether-ester-amide 6 thermoplastic elastomers (TPAEE6) and fabricating f(PA6/TPAEE6) side-by-side elastic fibers, so as to overcome the challenges of low strength and declining elasticity in existing PA6-based elastic fibers.

      Method A novel TPAEE6 elastomer was synthesized using a three-step melt copolymerization process involving non-crystalline polyether-ester diols and PA6. Characterization techniques, including proton nuclear magnetic resonance spectroscopy (1H NMR), Fourier-transform infrared spectroscopy (FT-IR), wide-angle X-ray diffraction (WAXD), small-angle X-ray scattering (SAXS), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), and tensile testing, were employed to verify the synthesis and evaluate the structural and thermodynamic properties of TPAEE6s. Side-by-side elastic fibers were prepared by blending PA6 with TPAEE6 elastomers at specific ratios and varying draw ratios.

      Results 1H NMR and FT-IR results confirmed that TPAEE6 is composed of soft and hard segments connected by ester bonds. GPC analysis revealed that the molecular weight of the elastomer ranged from 36.5 to 45.7 kg/mol, while viscosity testing indicated a relative viscosity between 1.21 and 1.68, suggesting a high molecular weight for the elastomer. DMA exhibited dual glass transition temperatures, and structural changes in the crystalline regions observed in WAXD and SAXS demonstrated the excellent microphase-separated morphology of TPAEE6. Additionally, SAXS calculations indicated that the addition of polyether-ester segments did not alter the interplanar distance of the pure PA6 crystalline phase, confirming that the incorporation of soft segments did not disrupt the crystalline structure of pure PA6. Tensile testing results showed that the elastomer exhibited a tensile strength of 23-47 MPa and an elongation at break of 373%-758%. Cyclic tensile testing revealed a significant improvement in elastic recovery with increasing soft segment content. Beyond the first cycle, the subsequent tensile cycles showed minimal loss in elasticity. The f(PA6/TPAEE6) elastic fibers, prepared by side-by-side spinning of PA6 and TPAEE6-30 at a composite ratio of 4∶1, achieved a tensile strength of 3.12 cN/dtex, significantly outperforming previously reported PA6/TPAE composite fibers (2.14 cN/dtex), PA6/TPA6510 fibers (1.4 cN/dtex), PA6/PBTE fibers (2.4 cN/dtex), and commercial elastic fibers like T400 (2.44 cN/dtex). Under fixed elongations of 5%-20%, the elastic recovery rate and durability of the PA6/TPAEE6 fibers were significantly superior to those of T400, with recovery rates exceeding 90% in low-strain cycles and significantly reduced hysteresis losses.The microphase-separated structure of TPAEE6 balances flexibility and strength, imparting exceptional elasticity and mechanical performance to the fibers.

      Conclusion The developed TPAEE6 thermoplastic elastomer exhibits excellent thermodynamic properties and a well-defined microphase-separated structure, offering new approaches and choices for the elastomer market. The PA6/TPAEE6 elastic fibers developed significantly outperform existing PA6-based and commercial elastic fibers in terms of strength and elasticity, showcasing broad application potential. This research integrates intrinsic and morphological elasticity, providing a new pathway for developing high-performance elastic fibers with the potential to enhance production and manufacturing efficiency.

      Preparation and Cr6+ adsorption of polyacrylonitrile/polypyrrole nanofiber membrane
      MAO Ze, GAO Jun, LING Lei, WU Dingsheng, TAO Yun, ZHANG Chun, LI Shen, FENG Quan
      Journal of Textile Research. 2025, 46(09):  57-65.  doi:10.13475/j.fzxb.20241105401
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      Objective Heavy metal ions (Cr6+ as an example) are highly toxic and difficult to remove from wastewater, causing serious environmental problems. Many reported nanoparticle adsorbents show good effects, but are inconvenient for recycling and reuse, limiting the application of specific scenarios. Therefore, it is of great significance to develop adsorbents that could be reused as well as having good adsorption effect.

      Method Polyacrylonitrile/polyaniline (PAN/PPy) nanofiber membrane were prepared by electrospinning and in-situ oxidation using polyacrylonitrile and pyrrole as raw materials. PAN/PPy nanofibers membrance were characterized by scanning electron microscope (SEM), X-ray diffractometer (XRD) and Fourier transform infrared (FT-IR)spectrometer. Tensile performance and hydrophilicity were evaluated using tensile testing equipment and water contact angle (WCA) measuring instrument, respectively. The influences of different factors (temperature, pH value and Cr6+ concentration) on the adsorption properties of PAN/PPy nanofiber membrane were investigated, and the adsorption isotherm, adsorption thermodynamics and adsorption kinetics of PAN/PPy nanofibers membrance were analyzed.

      Results The SEM images showed that the fiber surface changed from smooth to rough with pyrrole growth. The (110) crystal system of PAN appeared at 2θ=17°, the amorphous peak of PPy appeared at 2θ=24°, the characteristic peak of C≡N appeared at 2 243 cm-1 in the FT-IR spectra, and the characteristic peak appeared at 811 and 920 cm-1 as the tensile vibration of C—H. The characteristic peaks at 1 487 and 1 558 cm-1 correspond to the tensile vibration of C=C, and the peaks at 1 685 and 1 315 cm-1 represent the vibration of C=N and C—N, respectively. SEM, XRD and FT-IR results demonstrated the successful preparation of PAN/PPy nanofibers membrane. PAN/PPy nanofiber membrane exhibited good mechanical properties (stress 4.3 MPa, strain 41.8%, elastic modulus 9.824 MPa) and hydrophilicity (water contact angle reduced from 132.3° to 40.4°). The adsorption results showed that the adsorption performance of PAN/PPy nanofiber membrane for Cr6+ increased with the rise of temperature, and decreased with the increase of pH value, because the protonated amino group decreased with the increase of pH value. Under the conditions of Cr6+ concentration of 100 mg/L, pH=2 and 318 K, the adsorption of PAN/PPy nanofiber membrane on Cr6+ reached 91.3 mg/g. The adsorption isotherm, adsorption thermodynamics and adsorption kinetics of PAN/PPy nanofibers membrane were fitted to analyze the adsorption behavior of Cr6+ by the experimental data. The results showed that the adsorption isotherm was consistent with the Langmuir model, indicating that it was monolayer adsorption.The adsorption thermodynamics showed that the adsorption of Cr6+ by PAN/PPy nanofiber membrane is a non-spontaneous endothermic reaction. The fitting of adsorption kinetics accorded with pseudo-second-order kinetics, indicating that chemisorption plays an dominant role in the adsorption process. XPS analysis results showed that about 41.3% of Cr6+ was reduced to Cr3+. The investigation also showed that after repeated use for five cycles, more than 60% adsorption was maintained compared to the adsorption result of the first use, suggesting good reusable performance.

      Conclusion PAN/PPy nanofiber membrane was prepared by electrospinning and in situ oxidation for adsorption and reduction of Cr6+in wastewater. The PAN/PPy nanofiber membrane successfully prepared has good mechanical properties and hydrophilicity. Under the conditions of pH=2, 318 K and Cr6+ concentration of 100 mg/L, the optimal adsorption performance was 91.3 mg/g. The adsorption of Cr6+ by PAN/PPy nanofiber membrane is a single molecular layer adsorption, beloning to a non-spontaneous endothermic reaction, in which chemisorption plays an important role. PAN/PPy nanofiber membrane has good reducing properties and show satisfactory reusability.

      Preparation and properties of long-lasting antimicrobial polyamide 66 fibers
      SUN Heqing, ZHAO Congying, WU Bingxue, ZHANG Youwei
      Journal of Textile Research. 2025, 46(09):  66-73.  doi:10.13475/j.fzxb.20250205901
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      Objective Antimicrobial polyamide 66 (PA66) fibers have gained a lot of attention because of the demand from the apparel and biomedical fields. Poly(hexamethylene guanidine hydrochloride) (PHMG) is an ideal antimicrobial agent because of its broad-spectrum antimicrobial properties, good biocompatibility, low cost and non-toxicity. However, due to its excellent water solubility, the antimicrobial fibres produced by direct blending of PHMG with the matrix exhibit shortcomings such as poor washability and dissolution tendency. The present study aims at producing long-lasting antimicrobial polyamide 66 (PA66) fibers via modification of PHMG with polyepoxy polystyrene (PSG).

      Method PHMG was first modified by melt blending with PSG via a twin-screw extruder to produce guanidine salt copolymer (PSGP). Next, PSGP was melt blended with PA66 chips via a twin-screw extruder to produce antimicrobial PA66 masterbatch. Finally, the antimicrobial PA66 masterbatch was used as additives to fabricate long-lasting antimicrobial PA66 fibers through blend melt spinning techniques. The chemical structure and thermal properties of the antimicrobial PA66 masterbatch, the micromorphology, crystal structure, mechanical and antimicrobial properties, as well as the distribution of Cl element on the cross-section of the antimicrobial PA66 fibres were investigated.

      Results The antimicrobial PA66 masterbatch demonstrated exceptional thermal stability with almost no mass loss below 310 ℃, fully satisfying the thermal requirements for melt spinning processes. Remarkably, even at a PHMG loading as low as 0.33%, the resulting PA66 fibers achieved outstanding antibacterial efficacy, showing 99.46% and over 99.99% reduction rates against E. coli and S. aureus, respectively. When the PHMG content was increased to 0.39%, the fibers exhibited over 99.99% antibacterial activity against both bacterial strains. Notably, after 50 washing cycles, fibers with a PHMG dosage of 0.45% maintained impressive antibacterial performance with over 95% inhibition rates for both microorganisms, demonstrating excellent wash durability and good long-lasting antimicrobial properties. Mechanical characterization revealed that as the dosage of PHMG increased gradually from 0% to 0.33%, 0.39%, 0.45% and 0.51%, the breaking strength of the resulting fibers decreased continuously from (6.09±0.21) cN/dtex to (5.48±0.22), (5.35±0.20), (5.19±0.23), and (4.98±0.27) cN/dtex, while the orientation factor only slightly decreased from 0.79±0.03 to 0.77±0.02, 0.76±0.04, 0.76±0.03, and 0.75±0.04. DSC and XRD analyses indicated that the incorporation of PHMG reduced crystallinity and diminished crystal structure regularity in the fibers, explaining the observed mechanical property changes. Importantly, despite this reduction, all antibacterial fibers maintained breaking strengths above (4.98±0.27) cN/dtex, which fulfills the mechanical requirements for practical textile applications. SEM morphological analysis demonstrated excellent compatibility between PSGP and PA66 matrix, with no evidence of phase-separation. Surface characterization studies, including the cross-section radial line-scanning of Cl (a characteristic element of PHMG) and XPS analysis of the antimicrobial PA66-0.51 fiber containing 0.51% PHMG, revealed significant PHMG enrichment on the fiber surface compared to both the inner part and bulk average of the fiber. This surface enrichment phenomenon explains the fibers' exceptional antibacterial performance at such low PHMG loadings.

      Conclusion Antimicrobial PA66 masterbatch exhibits good thermal stability. The introduction of PSG promotes the enrichment of PHMG on the fiber surface during the spinning process. This enhances the utilization rate of the antimicrobial agent, enabling the antimicrobial PA66 fiber to achieve over 99% antibacterial rates against E. coli and S. aureus at a low PHMG dosage of 0.33%. At a PHMG dosage of 0.45%, the resulting antimicrobial fibre not only remained excellent antimicrobial properties after 50 washing cycles, but also exhibited good mechanical properties with a breaking tenacity of 5.19 cN/dtex. In summary, this work provides a new approach for developing PA66 fibre materials that combine excellent mechanical properties with efficient antimicrobial performance, demonstrating great potential for applications in medical, sports, and home textiles.

      Preparation and performance of silver nanowires/polyurethane nanofiber membrane flexible sensor
      FU Lin, QIAN Jianhua, SHAN Jiangyin, LIN Ling, WEI Mengrong, WENG Kexin, WU Xiaorui
      Journal of Textile Research. 2025, 46(09):  74-83.  doi:10.13475/j.fzxb.20241003701
      Abstract ( 178 )   HTML ( 12 )   PDF (16998KB) ( 40 )   Save
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      Objective Flexible sensors have shown broad development prospects in fields such as electronic skin, human-computer interaction, soft robots, human motion monitoring, and smart wearables due to their characteristics of light weight, bendability, wearability, low cost, implantability, and high sensitivity. The emergence of nanomaterials has created conditions for the development of flexible sensors. Research shows that combining flexible polymer substrates with emerging conductive fillers is a common strategy for preparing flexible smart electronic fiber devices. The sensor proposed is composed of high aspect ratio AgNWs combined with a highly elastic and stretchable TPU substrate, forming a perfect conductive network. Their electrical conductivity, sensitivity and cycling stability were studied.

      Method Silver nanowires are prepared by one-step polyol method. Factors affecting the morphology of silver nanowires are analyzed. The appearance morphology, chemical structure, crystallization properties and other properties of AgNWs synthesized under the optimal conditions are tested. Through electrospinning, TPU nanofiber membrane is prepared. The TPU film is fixed in a vessel. The prepared AgNWs are coated on one side of the TPU film by dipping method. After the ethanol solution volatilizes, a transparent conductive film with a silver nanowire network structure is formed on the surface of the TPU film. Two TPU films are attached and encapsulated face to face to obtain a flexible film sensor with a ″sandwich″ structure. The performance of the developed sensor was evaluated.

      Results The solution reacts at 150 ℃ for 7 h, and the silver nitrate solution is dropped into the solution at a speed of 1.5 mL/min and stirred for 7 h to reach the optimal morphology and aspect ratio of the generated silver nanowires. Their length is 60-150 μm, the diameter is 60-120 nm, and the average aspect ratio exceeds 1 000 with the maximum reaching 1 921. The TPU/AgNWs/TPU sensor is a flexible strain resistance sensor with low initial resistance (36.1 Ω), high strain range (ε=0%-130%), high sensitivity (ε=0%-10%, GF=180; ε=10%-110%, GF=610; ε=115%-130%, GF=1 270), and a fast response time of 220 ms). At the same tensile speed and different strains (25%, 50%, 75%, 100%), the resistance change remains highly consistent, and the resistance is proportional to the strain size, indicating that the sensor has the accuracy and repeatability of sensing under different strains. When the strain is the same (50%) and the tensile speed is different, the resistance change is highly consistent, and the resistance changes slightly under different speeds, indicating that the resistance response has good independence from the stretching speed. In the strain range of 0%-10%, after 3 000 tension cycles, the resistance change rate is between 0%-2%, indicating good cyclic stability and strain sensitivity.

      Conclusion Through the research on the process parameters during the growth of silver nanowires (AgNWs) using the polyol method, silver nanowires with excellent performance were successfully prepared. A flexible sensor was fabricated by combining a polyurethane (TPU) film prepared via electrospinning technology with AgNWs, which significantly enhanced the flexibility, adhesiveness, and wear resistance of the material. Thanks to the structural design of TPU/AgNWs/TPU, the sensor effectively addresses problems with the conventional sensors, such as significant performance differences under different strains, obvious interference from the stretching rate, or substantial performance degradation after cyclic use.

      Preparation and adsorption-photocatalytic performance of cotton-based biochar-ZIF-L(Zn)-chitosan/polypropylene composite membrane
      WANG Hongli, ZHANG Hui, LIU Jianyu, YU Haize, ZHANG Yaning, WANG Lili, XU Xuechao
      Journal of Textile Research. 2025, 46(09):  84-93.  doi:10.13475/j.fzxb.20241106601
      Abstract ( 171 )   HTML ( 17 )   PDF (10978KB) ( 13 )   Save
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      Objective In order to enhance the hydrophilicity and pollutant removal efficiency of polypropylene (PP) nonwoven fabrics, a composite membrane with dual adsorption and photocatalytic functions was developed. The membrane integrates cotton-based biochar, ZIF-L(Zn) and chitosan onto a PP substrate to enable efficient removal of dyes and antibiotics from wastewater. The study emphasizes the potential of combining bio-derived materials with metal-organic frameworks (MOFs) to achieve high-performance membranes for sustainable water purification.

      Method Cotton textile waste was pyrolyzed to produce porous cotton-based biochar (CB), which was then combined with two-dimensional ZIF-L(Zn) to obtain a composite powder possessing both adsorption and photocatalytic capabilities. This powder was deposited onto a chitosan-modified PP nonwoven substrate (CSP) by spraying, yielding the CB-ZIF-L(Zn)-CSP composite membrane. The membrane's microstructure, composition, and thermal stability were characterized using scaning electron microsopy(SEM), X-ray diffraction(XRD), Fourier transform intrared (FT-IR) spectroscopy, Raman spectroscopy, and thermogravimetric analysis (TGA). Pore size distribution and filtration performance were systematically evaluated. The influences of precursor mixing order, mass ratios, hot-pressing pressure, and membrane layering on removal efficiency were also investigated.

      Results The CB-ZIF-L(Zn)-CSP membranes exhibited strong dye and antibiotic removal capabilities. A 1∶1 mass ratio of CB to ZIF-L(Zn) yielded the optimal performance, achieving a Congo Red (CR) degradation rate of 87.9% under visible light after four reuse cycles. The five-layer membrane prepared under 50 MPa hot-pressing exhibited 100% CR rejection at a flow rate of 15 L/h, with excellent reusability. Additionally, effective removal of methylene blue (MB) and tetracycline (TC) was observed. The reaction sequence of CB and ZIF-L(Zn) precursors played a critical role in determining the microstructure and functional efficiency of the composite. The membrane maintained high performance across multiple cycles, demonstrating excellent stability and regeneration ability.

      Conclusion That CB-ZIF-L(Zn)-CSP composite membranes, fabricated via a low-cost and scalable spraying process, offer a promising route for high-efficiency wastewater treatment. The synergistic integration of biochar, MOFs, and chitosan significantly enhances adsorption and photocatalytic performance. These findings highlight the potential of using waste-derived materials for developing multifunctional membranes applicable in practical and sustainable water purification systems.

      Aromatic and antibacterial linalool/polyamide/zein micro-nano nonwovens with double envelope structure
      WANG Haopeng, ZHANG Jiawen, NIU Yunwei, KE Qinfei, ZHAO Yi
      Journal of Textile Research. 2025, 46(09):  94-103.  doi:10.13475/j.fzxb.20240500901
      Abstract ( 99 )   HTML ( 2 )   PDF (13282KB) ( 8 )   Save
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      Objective Linalool, a primary constituent of lavender essential oil, is renowned for its versatile properties, including anti-inflammatory and anti-bacterial effects, as well as its sedative and hypnotic qualities. Additionally, it exhibits potent anti-oxidation capabilities. Owing to these beneficial attributes, linalool is extensively utilized in various health-related fields, such as sleep aids, antibacterial products, and anxiety relief. Its natural calming effects make it a valuable component in aromatherapy and other wellness practices.Despite these advantages, linalool's inherent volatility and poor thermal stability present significant challenges that can limit its application efficiency and effectiveness. Its tendency to evaporate quickly can lead to a loss of potency, while its instability at higher temperatures can affect its shelf life and reliability in various formulations. In order to overcome these drawbacks and harness linalool's full potential, a novel hierarchical envelope stabilization strategy for fiber microcapsules is introduced.

      Method A sophisticated hierarchical envelope stabilization strategy for fiber microcapsules is presented, which is a groundbreaking approach in the field of encapsulation technology.Micro-nano composite nonwowens were developed, which was meticulously crafted using the electrospinning technique. Polyamide-amine dendrimers (carefully designed organic molecules known for their high branching and functionality) were chose as the main material for building molecular microcapsules. Through electrospinning technology, zein-coated molecular microcapsules are prepared to achieve the sustained release of linalool.

      Results The inclusion mechanism of polyamide-amine dendrimers and linalool was verified by molecular dynamics simulation, and the optimal loading rate (64.9% for polyamide-amine dendrimers) was investigated.Besides, the long-active antibacterial aromatic micro-nano nowowens (the loading rate of linalool increased from 2.61% to 13.9%) was formed, and the mechanical properties (breaking strength 21.23 cN, elongation at break 6.25%) were improved by 90.52% and 53.56%, respectively.

      Conclusion The micro-nano scaffolds developed through the electrospinning of zein and polyamide-amine dendrimers have significantly improved the storage stability of linalool when kept at room temperature.Encapsulating linalool within the fibrous matrices of the micro-nano nonwowen not only protected the compound from degradation but also prolonged its antibacterial efficacy over an extended period. This advancement in encapsulation technology has allowed linalool to retain its potent antibacterial activity, making it a viable candidate for a wide range of application in the field of medical dressing, the sustained release of linalool from these micro-nano scaffolds can provide a continuous antimicrobial effect, reducing the risk of infection in wound healing environments. Furthermore, in food packaging, the integration of linalool-containing microcapsules into packaging materials can serve as a natural preservative, prolonging the shelf life of perishable goods by inhibiting the growth of bacteria and fungi.

      Quantitative detection of wool and cashmere based on near infrared spectroscopy and multi-feature network
      ZHU Yaolin, LI Zheng, ZHANG Qiang, CHEN Xin, CHEN Jinni, ZHANG Hongsong
      Journal of Textile Research. 2025, 46(09):  104-111.  doi:10.13475/j.fzxb.20241107501
      Abstract ( 137 )   HTML ( 3 )   PDF (7771KB) ( 27 )   Save
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      Objective Textiles with similar contents, such as cashmere and wool, are known to be tough to categorize. When their amounts in waste textiles are close, conventional detection models have difficulties to distinguish them. This often results in low accuracy in identifying cashmere and wool. This study aims to build a hybrid CNN-LSTM model combined with local feature extraction with temporal feature extraction, so as to detect cashmere and wool content accurately with near-infrared spectroscopy(NIR). This method is expected to extract the variations of absorption peaks and the relationship between absorption peaks, and then obtain the complex spectral variations.

      Method Cashmere and wool samples with similar colour radii are collected for preparing mixed samples of cashmere and wool in various ratios using the potassium bromide pressing method. Spectra using a near-infrared spectrometer are obtained to create a database, and the NIR spectral data are nomalized with the Z-Score algorithm, which helps remove differences in magnitude. Gaussian noise data enhancement follows to boost data diversity and the dataset is split using 10-fold cross-validation which is used as input to a hybrid CNN-LSTM model. MLP regression prediction is performed through the convolutional layer and gated sequence.

      Result In the experiments, the improved CNN-LSTM-MLP model predicts cashmere and wool contents well. The model efficiently pulls out key spatial features from near-infrared spectral data which cuts down on processing time and boosts feature extraction efficiency. It uses depth-separable convolution to first identify peaks from chemical bond vibrations in the near-infrared spectra, and combines these features using stationary point convolution. The LSTM (long short-term memory) layer effectively captures the time-based relationships in spectral data to enhance the model's sensitivity to changes in spectral features. It also preserves contextual information across bands using forgetting gates and memory units. As a result, the model can focus on intensity changes in individual absorption peaks. It also learns patterns among several key bands, such as the connections between absorption peaks from 2 028 to 2 470 nm. By modelling the spectral sequence, LSTM reveals how different absorption peaks relate over time. It boosts the weight of continuous absorption peak bands, and allows it to better spot changes in mixing ratios and peak intensity, even with minor differences. The results show that the improved model predicts more accurately than the conventional methods. In the 10-fold cross-validation, most R2 values on the test set are above 0.95 and the MSE is below 0.01, indicating that the improved CNN-LSTM-MLP model is accurate and stable in analysing near-infrared spectroscopic data. It also offers strong support for quick and accurate detection of cashmere and wool content.

      Conclusion The proposed new prediction model for cashmere and wool uses an enhanced CNN-LSTM-MLP architecture in combination with deep separable convolution (DSC) with conventional convolutional neural networks (CNN). This setup effectively extracts spatial features from near-infrared spectral data, and also models temporal features with LSTM layers. Quantitative predictions are achieved using a multilayer perceptron (MLP), and deep separable convolution cuts down the model's computational complexity, keeping rich channel information in the high-dimensional spectral data. The proposed model greatly improves prediction accuracy, and the efficient algorithm results in the need of little computing power to predict cashmere and wool contents. The model performs well in analysing cashmere and wool and it is practically useful for spectral analysis in real production.

      Textile Engineering
      Influence of air-jet vortex spinning process on properties of three-component blended yarns
      MIAO Lulu, GU Jiahua, TAO Huaguan, SUN Guojun, ZOU Zhuanyong
      Journal of Textile Research. 2025, 46(09):  112-119.  doi:10.13475/j.fzxb.20241000901
      Abstract ( 140 )   HTML ( 8 )   PDF (6315KB) ( 21 )   Save
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      Objective This study investigates the influences of key spinning parameters on the performance of polyester fiber/dyed cotton fiber/ PHBV-based polyester fiber (50/35/15) air-jet vortex spinning blended yarn.By optimizing spinning conditions, the research aims to enhance yarn quality, thus providing scientific guidance for industrial parameter settings and improving the efficiency and sustainability of blended yarn manufacturing.

      Method Based on Box-Behnken Design (BBD) and response surface model analysis, the influences of delivery speed, nozzle pressure and the reciprocal of yarn linear density on the break strength, elongation at break, breaking work, evenness CV value and hairiness H value of blended yarn were studied.

      Results Statistical analysis of the test results indicated that the delivery speeds, nozzle pressure and the reciprocal of yarn linear density had significant effect on the yarn tenacity, elongation at break, breaking work and hairiness H value, and the reciprocal of yarn linear density has a significant effect on the yarn evenness CV value. Through the change of yarn break strength, it was found that the yarn break strength exhibited an increase and then followed by a decrease with the increase of nozzle pressure, and demonstrated a decreasing trend with the increase of the reciprocal of yarn linear density. The yarn break strength increased slowly with the change of the delivery speed, and this change became obvious when the reciprocal of yarn linear density was on small values (i.e. with thicker yarns). The elongation at break of the yarn decreases with higher reciprocal of yarn linear density and delivery speeds, primarily due to reduced fiber slippage in the yarn. The elongation at break of the yarn increased slowly with the increase of the nozzle pressure. The yarn breaking work was related to the change of yarn tenacity and break elongation, and it was most affected by the reciprocal of yarn linear density in such a way that yarn breaking work would increase with the decrease of the reciprocal of yarn linear density. The yarn evenness CV value demonstrated increase with the increase of the reciprocal of yarn linear density. It was found that that the yarn hairiness H value decreased with the increase of the reciprocal of yarn linear density and nozzle air pressure, and decreased with the decrease of delivery speed.

      Conclusion In the spinning process, increasing the delivery speed properly can reduce the fiber loss in the twisting chamber enhancing the fiber wrapping effect, which is beneficial to the yarn break strength. Increasing the delivery speed would reduce the probability of fiber slippage within the yarn, leading to reduced elongation at break of the yarn. The change of delivery speed has little effect on yarn breaking work, because the trend of yarn and breaking elongation is opposite. The result showed that the yarn was prone to hair formation with the increase of delivery speed. For polyester fiber/dyed cotton fiber/PHBV-based polyester fiber (the blend ratio of 50∶35∶15) air-jet spinning blended yarn, when the nozzle pressure is set near 0.55 MPa, the yarn can obtain satisfactory breaking work. With the increase of the nozzle pressure, the twisting degree of the wrapped fiber increases and the yarn hairiness decreases. The yarn evenness CV value is mainly affected by the yarn linear density. When the yarn is finer, it is easy to form draft fluctuations, resulting in yarn evenness variation.

      Cotton yarn quality prediction based on one-dimensional convolutional neural network
      ZHENG Xiaohu, DU Siqi, LIU Yongqing, WANG Jian, CHEN Feng
      Journal of Textile Research. 2025, 46(09):  120-127.  doi:10.13475/j.fzxb.20241102101
      Abstract ( 156 )   HTML ( 2 )   PDF (8085KB) ( 26 )   Save
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      Objective The aim of this study is to address the challenges of diverse and high-dimensional data, as well as low prediction accuracy, in the multi-step and multi-variable cotton yarn production process. A feature selection method is proposed based on copula entropy (CE), combined with a one-dimensional convolutional neural network (1D-CNN) and K-nearest neighbors (KNN) algorithm, to predict four yarn quality indicators: coefficient of variation of strip stem uniformity (CVm), hairiness index (H value), thin yarns (-50%), and thick yarns (+50%). This approach emphasizes the importance and necessity of enhancing prediction accuracy and model efficiency in yarn production.

      Method This study proposed a CE-based feature selection method and a yarn quality prediction model based on 1D-CNN and KNN. Initially, CE was utilized as the basis for feature selection, quantifying the relationship between variables and targets, and selecting the top seven variables with the highest correlation for input into subsequent prediction models to achieve model lightweighting. Subsequently, a 1D-CNN-KNN model was constructed, where 1D-CNN extracted features from the variables, and KNN is utilized to fit the yarn quality indicators.

      Results In order to verify the effectiveness of the proposed method, real ring spinning production data from a textile mill was used as an example. The copula entropy of raw cotton performance quantities and yarn quality indexes were calculated, and in order to determine the optimal number of features, cross-validation was adoptd to evaluate the average performance of the model with different numbers of features, and the top 7 features were finally selected as the key variables. The key variables were used as inputs to compare the performance differences between the proposed 1D-CNN-KNN and 1D-CNN, support vector regression(SVR), KNN, LightGBM, and Transformer models. The experimental results showed that the proposed model had higher prediction accuracy for yarn quality. Specifically, for the four yarn quality indicators of the mean absolute error, root mean square error, and cotticient of determination of the proposed models were improved by 18.4%, 16.5%, and 23.8%, respectively. Due to the small sample of experimental data, in order to verify the generalization performance of the proposed model, different training set samples were set to discuss the generalization ability of the model under small samples, and the experiments showed that the proposed model's comprehensive fitting ability was better than other models, and the performance was more stable. In addition, by comparing the results of different feature selection methods on the model performance, the copula entropy-based method had the highest prediction accuracy and the prediction time was shortened by 36.5% on average, improving the production prediction efficiency. Detailed analysis showed that CE-based feature selection effectively reduced the data dimensionality while retaining key information related to yarn quality. The 1D-CNN component of the model was able to capture complex patterns and features from the selected variables, which were then fitted by a KNN algorithm. The combination of these techniques produced an efficient and accurate predictive model for yarn quality metrics.

      Conclusion The proposed CE-based feature selection method combined with the 1D-CNN-KNN model has proven effective in improving the prediction accuracy and efficiency of yarn quality indicators in the cotton yarn production process. This approach has the potential to contribute to the optimization of yarn production processes and the improvement of yarn quality in the textile industry. However, the current experimental data is only for cotton yarns, which can be extended to quality prediction tasks for more yarn types, such as chemical fiber and hemp, in the future. Thus, a model with better generalization can be constructed to further improve the feature selection and model training process to achieve better performance.

      Construction and color rendering characteristics of jacquard structure model with double warps and quadruple wefts for double-weft color gradation
      LU Shuangyi, WANG Lan, CHEN Si, ZHOU Jiu
      Journal of Textile Research. 2025, 46(09):  128-135.  doi:10.13475/j.fzxb.20241000801
      Abstract ( 211 )   HTML ( 4 )   PDF (28104KB) ( 14 )   Save
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      Objective Towards full understanding of characteristics of jacquard woven fabrics with double warps and quadruple wefts for double-weft color gradation, construction of jacquard woven fabric models are proposed involving six primary color threads (red, yellow, green, blue, black, and white), with a double-layer structure which enables independent regulation over the coloring and the backing warp and weft threads. Five key factors are taking into consideration in the development and calculation of double-weft color gradation compound weaves for color expression, namely the weave repeat number N, the step number S, the quantity of its available value ${Q}_{{S}_{N}}$QSN, the transition speed M, and the quantity of available interlacing for stitching at the stitching positions QIS. This research aims to provide insights for the color space construction and jacquard structure modeling with double warps and quadruple wefts for double-weft color gradation.

      Method In order to construct the fabric model, 2 sets of achromatic threads and 4 sets of chromatic threads were placed in the warp and weft configuration, and the face and back weaves, as well as the relationship between the face and back layers were arranged to form double-weft color gradation compound weaves with their quantities calculated. Eventually, 12-thread 7-step sateen was selected as basic weave for shaded face weave-database and full-color face weave-database establishment. Double-weft color gradation compound weaves for validation were employed for the EAT sample simulation, enabling comparison and analysis of the structural coloring characteristics of jacquard structure with double warps and quadruple wefts for double-weft color gradation according to technique parameters given.

      Results 720 varieties of jacquard structure model were found available with double warps and quadruple wefts based on six primary color threads. 3 warp and weft color configurations were formed according to the arrangement of achromatic and chromatic warp and weft threads, generaing 8 types of warp and weft color configuration on the face layer, and maximizing the structural coloring space, 2 sets achromatic warp and 4 sets chromatic weft were employed to the construction of jacquard structure model with double warps and quadruple wefts for double-weft color gradation. Further, 12 structural coloring series of jacquard structure model with double warps and quadruple wefts on double-weft gradation were formed under the interlacement of single achromatic warp and double chromatic weft. The maximum quantity of compound weaves applying shaded weaves is $12\times {Q}_{S{W}_{M=1}}^{4}\times [1+4({2}^{N}-1)+4({2}^{N}{-1)}^{2}]$12×QSWM=14×[1+4(2N-1)+4(2N-1)2], while that employing full-color face weaves is $12\times {2}^{4{N}^{2}-8N}\times [1+4({2}^{N}-1)+4({2}^{N}{-1)}^{2}],$12×24N2-8N×[1+4(2N-1)+4(2N-1)2], then more than 1.565×1032 and over 5.491×1022 double-weft color gradation compound weaves were obtained when weave repeat N equals to 5, and transition speed M equals to 1, respectively. Sample simulation of double-weft color gradation compound weaves were used for validation, on one hand, with the application of double-layer structure, face layer covers back layer completely, and thread interchanging within the structure makes it possible for double layer to connect without self-stitching, on the other hand, both juxtaposition and covering features expressed within the adjacent two wefts of the compound shaded weaves, while any adjacent two wefts of the compound full-color weaves juxtapose permanently, it is reducing the slippage of adjacent threads that is beneficial to the stabilization of woven structure, what's more, obvious oblique texture occurred on the sample surface because of the influence of start point and step number S of basic weave, configuration ratio of face wefts as well as lightness variation of warp and weft.

      Conclusion In jacquard structure model with double warps and quadruple wefts for double-weft gradation, the application of full-color face weave-databases regulates the status of the adjacent face wefts within double-weft color gradation compound weaves, conducing to the stability of structural coloring, when weave repeat N to take the minimum value, the maximum quantity of double-weft gradation compound weaves reaches 1032 and 1022 when shaded face weave-database and full-color face weave-database are implemented respectively. What's more, the employment of full-color technical points is conductive to the juxtaposition of face wefts, thus, this study contributes to the structural coloring space construction and optimization of jacquard structure model with double warps and quadruple wefts for double-weft color gradation.

      Design and 3-D simulation of knitted fabrics with crocheted loops
      SUN Buqing, GUAN Songsong, JIANG Gaoming, LI Bingxian
      Journal of Textile Research. 2025, 46(09):  136-142.  doi:10.13475/j.fzxb.20241101001
      Abstract ( 154 )   HTML ( 5 )   PDF (7440KB) ( 18 )   Save
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      Objective Current research on the simulation of double structure crocheted fabrics is limited to two-dimensional fabrics, and this study focuses on three-dimensional simulation of such fabrics based on fabric geometry. JavaScript and C# programming languages are employed to rapidly simulate double structure crocheted fabrics, enabling diversified and rapid design of such fabrics. This work aims at the visual display of the design effects, reduced simulation time, and the overall quality and precision of fabric representation.

      Method By integrating the lapping matrix model for warp knitting, a lapping motion and yarn threading matrix model for topping-on structure crocheted fabrics is proposed to determine the positions of loops in the fabric. Through the analysis of the structural characteristics of topping-on structure crochet fabrics, three-dimensional annular models of an 8-point plain loop, a 2-point weft-layered loop, a 5-point centipede loop, and an 18-point topping-on structure are constructed under ideal fabric conditions to define the loop morphology. These models are employed to create the codes for three-dimensional structural simulation.

      Results The formation of loop arcs in double structure crochet fabrics is essentially a deformation of weft-insertion structures. By combining the warp-knitting lapping digital model to represent needle front lapping and needle back shogging, the width of the loop arc is expressed using the distance of needle front lapping in the lapping digital. A lapping matrix model is established, and combined with the yarn threading matrix model, which is used for the calculation of knitting diagram matrix. During the construction of the loop structure model, the loop structure is studied at a microscopic level. After determining the horizontal and vertical density of the fabric, the distance between two adjacent needles is denoted as Gw, and the distance between two adjacent courses is denoted as Gh. The relationship between the width of the loop arc and Gw is measured, and the width of the loop arc is 3Gw. From the fabric structure, it is evident that the formation of a double-loop structure corresponds to four chain structures in terms of height. The loop control points are determined using experimental results, and the final loop model is constructed. Two different loop fabric processes are designed, including raw materials, knitting structures, and warp cycles. Using C# and WebGL programming, three-dimensional simulations of the two fabrics and their composite fabrics are carried out, and a comparison between the physical images and simulated images is presented for validation.

      Conclusion This study accomplishes three-dimensional simulation of both topping-on structure crocheted fabrics and centipede loop fabrics. A composite design integrating these two fabric types is developed and rapidly simulated, providing novel approaches for efficient and diversified design of such specialized textiles.

      Model construction and deformation behavior of multilayer biaxial weft knitted fabrics based on virtual fiber model under off-axis tension
      ZHANG Xin, ZHOU Kanghui, JIANG Qian, WU Liwei
      Journal of Textile Research. 2025, 46(09):  143-153.  doi:10.13475/j.fzxb.20240805801
      Abstract ( 180 )   HTML ( 7 )   PDF (20560KB) ( 86 )   Save
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      Objective The multilayer biaxial weft knitted fabric is a specially structured textile characterized by parallel-aligned straight yarns (axial yarns) in both warp and weft directions, which are bound and fixed by knitted loop structures to form a three-dimensional knitted fabric. By employing high-performance yarns as axial yarns in both directions, this structure achieves enhanced stability and directional properties, making it particularly suitable for applications such as composite reinforcements, industrial textiles, and protective clothing. This study investigates the in-plane deformation characteristics and mechanical behavior of the multilayer biaxial weft knitted fabric using finite element methods, based on its unique structural features.

      Method In finite element simulation, the advantages of the virtual fiber model over the physical model lie in its ability to establish a high-precision model that is more consistent with real fabrics, and to show the tightness and interlacing deformation characteristics of real fabrics. Therefore, with reference to the spatial positions of knitting loops and axial yarns in the multilayer biaxial weft knitted fabric, a theoretical geometric model was first constructed. Through a pre-tightening program, preprocessing was performed on the theoretical geometric model to achieve the tight state of knitting loops against axial yarns in real fabrics, and regression equations were adopted to ensure the geometric consistency between the fabric model and the real fabric. Subsequently, off-axis tension simulation was carried out on the above-mentioned high-precision model, and the deformation behavior of the model was compared and analyzed with the morphology, loop inclination angle, and yarn cross-sectional deformation of the real fabric, aiming at more accurately simulating the in-plane deformation of real fabrics.

      Results The entire fabric model is built by adopting the virtual fiber method including two sets of yarn systems. A pre-tightening processing is implemented on the fabric models containing 10, 18 and 36 bundled yarns, respectively. By considering the correlation between the simulated and real coil path and comparing it with the morphology of the real fabric, it is concluded that when the tightening degree is 20%, the fabric model with 36 bundled yarns is consistent to the real fabric. After calculating the correlation coefficient, it is found that the correlation coefficient between the simulated and real bundled yarn coil trajectories approaches 0.9.The numerical simulation of off-axis tension is conducted on the fabric model that most closely approximates the real effect. Simultaneously, it is compared with the morphology of the real fabric after tigntening. As a result, it can be verified that the approach of constructing a fabric model can effectively represent the performance of the real fabric. By comparing the overall deformation as well as the deformation at different stages, it is discovered that the deformation behavior of the fabric model is similar to that of the real fabric, with the difference in the coil inclination angles between the two at different stages within 4°. Through analyzing the cross-sectional deformation situations of individual bundled yarn coils and axial yarns, it is found that the region with the largest deformation of the coil is located where the coils are interlaced and intertwined with each other. This deformation behavior is transmitted to the coil pillars and coil loops, which is in line with the analysis of the stress situation of the coils in the knitted fabric coil structure. The cross-sectional deformation degree of the coil pillars is greater than that of the coil loops. Under a 20% tightening degree, the ratio of the short axis to the long axis is lower than 0.6. The axial yarns transform from a rectangular cross-section to a runway shape and an elliptical shape.

      Conclusion The method of constructing virtual fiber models can effectively simulate the deformation behavior of real fabrics when bearing loads. By determining a certain quantity of virtual fiber, it is possible to approach more closely to the pre-tightening state of the fabric under actual conditions and the morphological changes after tightening. The fabric model can also reflect the squeezing deformation of the internal fibers within the yarns when under stress. This fully validates the effectiveness and feasibility of the multilayer biaxial weft knitted fabric model. This method also provides new ideas for model construction of other fabric structures.

      Multi-objective optimization of ureteral stent tubes based on in vitro degradation
      HOU Yinghui, LIU Xiaoyan, LIU Dongchen, HAO Kuangrong, ZOU Ting
      Journal of Textile Research. 2025, 46(09):  154-162.  doi:10.13475/j.fzxb.20241205401
      Abstract ( 136 )   HTML ( 2 )   PDF (11979KB) ( 13 )   Save
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      Objective Ureteral stent tubes provide necessary support and drainage within the body, so the mechanical properties of the stent tube are crucial to ensurine its effectiveness and safety. For biodegradable ureteral stent tubes, their mechanical properties will gradually decrease over the degradation period. A study on the mechanical properties of ureteral stent undergoing in vitro degradation and on the performance of multi-objective optimization is purposed.

      Method A mathematical model for the random hydrolysis of polymers was established and embeded into finite element simulation for degradation simulation. The writing of the VUMAT subroutine was adopted to control the simulation of cell failure in the degradation process of the stent, and a combination of finite element simulation, theoretical prediction, and experimental test results was adopted to study the mechanical properties of the ureteral stent under different degradation periods.

      Results A corresponding three-dimensional geometric model was constructed based on ureteral stent prepared from a fiber-membrane. The accuracy of the geometric model was verified by comparing the finite element results with the actual experimental results. For the ureteral stent prepared from the fiber-membrane, the regular weaving structure of PGA and PGLA yarns evenly distributed on the stent after being combined demonstrated the best mechanical enhancement performance after high-temperature heat treatment. Therefore, stent tube C was selected for the study of its mechanical properties during the degradation cycle. The degradation process was expressed in the form of unit damage failure, and the numerical method of ABAQUS was used in combination with the user material subroutine (VUMAT) to automatically update material parameters based on degradation time. At the same time, a strength based failure criterion was applied to simulate the mechanical properties of fiber-membrane degradable ureteral stents under different degradation times. Based on this result, 20 initial sample points were generated using the optimal Latin hypercube sampling method, and a Kriging surrogate model was constructed using these sample points to predict the mechanical properties of the fiber-membrane ureteral stent before degradation at 0 weeks and 3 weeks of degradation. NSGA-II was adopted to optimize the structure of the fiber-membrane ureteral stent. After optimization using this algorithm, a set of Pareto solutions was obtained. The algorithm specified the optimal solution as the optimization result, and the stent structure parameters with the best mechanical properties during degradation were obtained. The optimized stent showed a 17.89% increase in radial compression performance and a 27.89% increase in axial tensile performance before degradation. After 3 weeks of degradation, the radial compression performance increased by 25.14% and the axial tensile performance increased by 33.62%. The optimized fiber-membrane degradable ureteral stent was found to possess improved mechanical properties before degradation and to maintain a high level of performance during a certain degradation period, thereby extending its support and drainage period in vivo.

      Conclusion This study investigated the mechanical properties of degradable ureteral stent tubes with fiber-membrane structure before degradation and simulated degradation in vitro, and the following conclusions can be drawn. (1) Numerical simulation was conducted on the degradation process of fiber-membrane degradable ureteral stent, and the mechanical properties during the degradation cycle were studied. The effectiveness of the degradation model was verified through comparison with physical experiments, effectively solving the problems of long cycles and high costs in experimental and clinical testing. (2) Multi-objective optimization of the mechanical properties of stents was carried out based on a kriging surrogate model, and the evolution relationship of mechanical properties before and during degradation was obtained, providing reference for the design of biodegradable stent structures.

      Preparation of quasi-zero stiffness fabric isolator based on ABAQUS simulation
      ZHANG Zhaodong, WANG Lei, PAN Ruru
      Journal of Textile Research. 2025, 46(09):  163-170.  doi:10.13475/j.fzxb.20241207401
      Abstract ( 98 )   HTML ( 3 )   PDF (10424KB) ( 17 )   Save
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      Objective In order to solve the contradiction between the isolation bearing capacity and isolation frequency of linear isolators at low frequencies, a quasi-zero stiffness fabric isolator with this characteristic is designed using diagonal fabric based on the principle of nonlinear stiffness. A sinusoidal excitation signal is applied to the vibration isolator to evaluate its vibration isolation performance through vibration testing.

      Method A bending crease model was developed in SolidWorks, and finite element analysis (FEA) was conducted using ABAQUS to simulate the compression behavior of the model. The same bending crease pattern was then applied to the fabric, followed by compression experiments. Two fabric solid elements with different crease curvatures were designed based on the bending crease model. Finite element simulations and experimental compression tests were performed. Vibration isolation performance tests were carried out on different fabric three-dimensional unit arrays to verify the low-frequency vibration isolation performance of the quasi-zero stiffness fabric isolator.

      Results Finite element simulation compression was performed on the bending crease model. The simulation results showed that during the compression process of the model, the stress was first concentrated at the creases on both sides with a symmetrical distribution. As the degree of bending increased, the stress was transferred to the middle of the crease. The stress value on the bending surface was always lower than that at the crease throughout the process. The compression force-displacement curve was analyzed to assess the performance. Three different types of stiffness curves were obtained by changing the model parameters (chord height h, folding angle β). When other parameters were held constant, the chord height h was increases from 2.0 mm to 5.5 mm, the stiffness of the model was changed from negative stiffness to quasi-zero stiffness and then to positive stiffness, and the initial compression force value demonstrated a decrease from 30 cN to 21 cN. As the crease angle β varied from 90° to 150°, the model's stiffness was changed from negative stiffness to positive stiffness. Compression experiments were performed on fabric samples using the same bending crease pattern. The compression force displacement curves of the fabric at folding angles β of 110°, 130°, and 150° were highly similar to those obtained from finite element simulation, verifying the correctness of the finite element simulation and jointly elucidating the adjustable mechanism of nonlinear stiffness. Finite element simulation and experimental compression were conducted on fabric units with two different fold curvatures. The correlation coefficients between the simulation results and the experimental results were both above 0.833. Two types of fabric unit arrays were placed on an excitation table. Loads were applied to them to achieve quasi-zero stiffness and positive stiffness, respectively. The experimental results demonstrated that the designed quasi-zero stiffness fabric unit exhibited superior isolation performance compared to the positive stiffness fabric unit in the frequency range of 5-25 Hz.

      Conclusion A fabric three-dimensional unit isolator was designed to solve the problem of low-frequency isolation in linear isolators. A bending crease model was proposed, which was subjected to finite element simulation compression and fabric experimental compression. The influence of model parameters on the compression force displacement curve was revealed in two ways. Three distinct stiffness curves were obtained, which elucidate the mechanism of nonlinear stiffness adjustment. Based on this mechanism, two types of fabric three-dimensional units with different bending crease curvatures were designed and simulated and experimentally verified. The experimental compression force-displacement curves of the two fabric units exhibited a strong correlation with the simulation results, with quasi-zero stiffness and positive stiffness demonstrated, respectively. The results show that in the low-frequency range, the vibration transmission of quasi-zero stiffness fabric array is negative, while that of positive stiffness fabric array is positive. The quasi-zero stiffness fabric array exhibits better isolation performance than the positive stiffness fabric array, indicating that the former can be used as a nonlinear isolator.

      Influences of nonwoven fabric structure and surface properties on performance of polysulfone support layer and separation layer of reverse osmosis membranes
      JIA Yanjun, GAO Lu, ZHAO Yingying, JING Zhaojing, GUO Ziyang, WANG Haitao, CHANG Na
      Journal of Textile Research. 2025, 46(09):  171-180.  doi:10.13475/j.fzxb.20250104801
      Abstract ( 125 )   HTML ( 16 )   PDF (13944KB) ( 36 )   Save
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      Objective The structure of polyamide composite reverse osmosis (RO) membranes primarily consists of a nonwoven fabric base layer, a polysulfone ultrafiltration (PSF) support layer, and a polyamide (PA) separation layer. The microstructure and properties of the nonwoven fabric directly influence the structure of the PSF support layer, which in turn affects the structure and performance of the RO membrane. A series of PSF base membranes and RO membranes were prepared based on nonwoven fabrics with different structural characteristics. The structure-performance relationships between the characteristics of the nonwoven fabric and the the PSF base membranes and RO membranes were investigated.

      Method A series of polysulfone ultrafiltration base membranes were prepared using polyethylene terephthalate (PET) nonwoven fabric through a phase inversion process, and the corresponding RO membranes were fabricated by interfacial polymerization (IP). The influences of structural parameters, such as fiber packing density, water contact angle, and Wenzel roughness, of the nonwoven fabric on the structure of the polysulfone ultrafiltration base membranes were studied. Additionally, the RO membranes prepared were characterized using scanning electron microscope, and their separation performance was tested.

      Results During the preparation of PSF-A base membranes, the surface was relatively hydrophilic (water contact angle of about 60°) with moderate Wenzel roughness because of the uniform fiber packing and moderate average cross-sectional density of approximately 0.75 g/(m2·μm) of nonwoven fabric A. This facilitated the casting of the PSF membrane solution and effectively permeated half of the nonwoven fabric A, resulting in a PSF-A base membrane with a moderate pore size (of about 35 nm) and a high surface porosity (of about 3.8%). This contributed to the effective permeation and uniform dispersion of the m-phenylenediamie (MPD) aqueous solution on the PSF membrane surface, leading to the formation of a uniform and dense RO-A membrane. Nonwoven fabric B exhibited severe fiber adhesion and the highest average cross-sectional density of approximately 0.85 g/(m2·μm), with a hydrophobic surface (water contact angle of about 84°) and the lowest Wenzel roughness. This reduced the effective permeation depth of the PSF casting solution (about one-third of nonwoven fabric B) while accelerating the phase inversion rate on the PSF membrane surface, resulting in a PSF-B base membrane with the largest pore size (about 45 nm), but fewer and unevenly distributed surface pores. During the preparation of the RO-B membrane, the MPD aqueous solution struggled to evenly disperse on the surface of the PSF-B membrane, causing the PA layer of the RO-B membrane to be uneven with more significant defects. Nonwoven fabric C had the loosest fiber packing with the lowest average cross-sectional density of about 0.50 g/(m2·μm), a strongly hydrophilic surface (water contact angle of about 12°), and the highest Wenzel roughness, which promoted the effective permeation (about two-thirds of nonwoven fabric C) of the PSF casting solution. The resulting PSF-C base membrane had the smallest pore size (of about 30 nm) and relatively concentrated surface pores. This led to the MPD aqueous solution being distributed only at the membrane pores of the PSF-C base membrane, resulting in an uneven distribution of the PA layer in the prepared RO-C membrane.

      Conclusion In this study, a series of PSF base membranes were prepared by phase inversion process with three different types of nonwoven fabrics possessing varying properties. The influences of nonwoven fabric characteristics on the pore structure and performance of PSF base membranes were investigated. Additionally, the relationship between the pore structure of the PSF base membrane and the structure-performance of the polyamide layer in the RO membrane was explored. The results showed that when the fiber packing density of the nonwoven fabric is moderate (average cross-sectional density of approximately 0.75 g/(m2·μm)), the hydrophilicity is suitable (water contact angle of about 60°), and the surface Wenzel roughness is optimal (Wenzel roughness of about 1.15), it favors the permeation of the PSF casting solution (permeation depth of approximately half the thickness of the nonwoven fabric). The PSF base membrane prepared from this nonwoven fabric exhibited uniform pore size and distribution, which facilitated the orderly dispersion of MPD and promoted the interfacial polymerization (IP) reaction, resulting in a uniform and dense polyamide layer in the RO membrane, achieving the desalination rate of over 97%. In summary, by adjusting the pore structure and surface properties of the PSF base membrane, the nonwoven fabric effectively controlled the IP process. This study provides new insights into the development of high-performance RO membranes using nonwoven fabrics and PSF ultrafiltration base membranes.

      Dyeing and Finishing Engineering
      Influence of polyvinyl alcohol polymerization and alcoholysis degrees on performance of cotton-sized yarns
      SHI Mi, WANG Wencong, FAN Xuerong, GAO Weidong
      Journal of Textile Research. 2025, 46(09):  181-187.  doi:10.13475/j.fzxb.20250201901
      Abstract ( 121 )   HTML ( 5 )   PDF (5418KB) ( 22 )   Save
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      Objective In order to explore the influence of polyvinyl alcohol (PVA) polymerization and alcoholysis degrees on sizing performance, the performance of cotton yarn sized with 10 different polymerization and alcoholysis degrees of PVA was investigated. The most suitable PVA for cotton yarn was selected by fuzzy comprehensive evaluation method, minimizing the amount of PVA to ensure sizing performance.

      Method The sealing performance of the size box of the single yarn sizing machine was improved to keep the size concentration and hence the size pick-up stable. Cotton yarns of 14.6 tex were sized using PVA sizing agents with different degrees of polymerization (500, 800, 1 200, 1 400, 1 700) and alcoholysis (partial, 88%; full, 99%) respectively, and the size pick-up was controlled within the range of (8.2±0.1)% by finely adjusting the size concentration. The size pick-up percentage of sized yarn was obtained using the constant-length gravimetric method. The performance of the sized yarn was tested for breaking strength and elongation at break, wear resistance, and hairiness, which was evaluated using fuzzy comprehensive evaluation taking tested parameters as the indexes for selecting the most suitable PVA polymerization and alcoholysis degrees for cotton yarn sizing.

      Results The results showed that the breaking strength of the sized yarns increased and then decreased with increased polymerization degrees of partially and fully alcoholyzed PVA under the same size pick-up, and finally stabilized. The breaking strength of yarns sized with partially alcoholyzed PVA peaked at 800 degree of polymerization, while the breaking strength of yarns sized with fully alcoholyzed PVA reached a maximum 1 200 degree of polymerization. The elongation at break of partially and fully alcoholyzed PVA sized yarns was very similar. However, the elongation at break of sized yarns decreased with increased PVA polymerization degree and ranged from 5.57% to 3.94%. The strength resistance of yarns sized with partially and fully alcoholyzed PVA increased and then reduced with increased degree of polymerization. The strength resistance of yarns sized with partially alcoholyzed PVA reached its maximum at 800 degrees of polymerization. The strength resistance of yarns sized with fully alcoholyzed PVA increased significantly at 1 200 and 1 400 degrees of polymerization. The effect of PVA polymerization degree on the hairiness number of sized yarns was less at the same alcoholysis degree. When the degree of polymerization ranged between 500 and 1 700, the hairiness number of yarns sized with partially alcoholyzed PVA was 18-19, while those sized with fully alcoholyzed PVA showed significantly lower values (9-12). The results of the fuzzy comprehensive evaluation demonstrated that the fully alcoholyzed PVA sizing agent showed superior performance compared to the partially alcoholyzed PVA. Among the fully alcoholyzed PVA, PVA-1299 had the best performance, while among the partially alcoholyzed PVA, PVA-0888 presented the optimal performance.

      Conclusion The single yarn sizing experiment method was improved to study the influence of PVA with different degrees of polymerization and alcoholysis on sized yarn properties. It was found that the optimal interval of sizing performance for both partially and fully alcoholyzed PVA was located in the intermediate polymerization degree under the same size pick-up percentage. In addition, the results of fuzzy comprehensive evaluation revealed that for cotton sized yarns, the sizing performance of fully alcoholyzed PVA was usually better than that of partially alcoholyzed PVA, with PVA-1299 showing the finest sizing performance, followed by PVA-1499. This study provides theoretical guidance for size producers to develop intermediate polymerization degree fully alcoholyzed PVA sizing agent, and thus reduce the use of PVA-1799 to further improve the sizing effectiveness.

      Hydrophobic modification and performance of bamboo pulp spunlace nonwovens for disposable hygiene products
      LIU Mei, CUI Li'na, GUAN Fuwang, LI Fu, FEI Pengfei, MA Chi, WANG Huaping
      Journal of Textile Research. 2025, 46(09):  188-196.  doi:10.13475/j.fzxb.20241202701
      Abstract ( 152 )   HTML ( 9 )   PDF (15791KB) ( 26 )   Save
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      Objective Conventional absorbent hygiene products (AHP) are primarily composed of polyolefin and polyester nonwovens as wrapping materials, exhibiting features such as high consumption rates, short usage cycles, challenging recyclability, and slow degradation. These attributes render them as significant contributors to fiber-based microplastic pollution. In contrast, cellulose-based nonwoven fabrics boast advantages like softness, permeability, and inherent biodegradability. The development of novel cellulose-based nonwoven materials presents a promising approach to mitigate the persistent microplastic pollution caused by non-degradable conventional absorbent hygiene products.

      However, the wrapping layer of AHP must be hydrophobic to effectively contain fluid within the absorbent core and prevent rewetting against the skin. Therefore, the highly hydrophilic nature of cellulose nonwovens necessitates hydrophobic modification for this application.

      Method The surface hydrophobic modification of bamboo pulp cellulose spunlace nonwoven fabric (BCNW) was conducted via a one-step urethanation reaction using 3-isocyanatopropyltrimethoxysilane (ISPTMOS) containing siloxane-based hydrophobic functional groups. Hydrophobicity, air-permeability, and mechanical properties of the modified nonwoven fabrics were investigated before and after modification. Furthermore, liquid penetration and anti-backflow properties of BCNW-ISPTMOS samples with different mesh sizes were quantitatively evaluated.

      Results Compared to pristine bamboo pulp cellulose spunlace nonwoven fabric (B-BCNW), the modified fabric exhibited a transition from superhydrophilicity to hydrophobicity. The modified sample of BCNW-ISPTMOS demonstrated a water contact angle (WCA) of 135.5°, attributable to the blocking of hydrophilic hydroxyl groups in cellulose structure by low-surface-energy silane groups and enhanced surface roughness from silane cluster formation. Notably, the micro-scale silane clusters on the surface of the ultrasonically hydrolyzed hydrophobic bamboo pulp cellulose nonwovens (BCNW-ISPTMOS(U)) were converted into micro-nano scale, with partial nano-clusters encapsulated within silane layers. This structural evolution increased both hydrophobicity and hydrophobic stability, increasing the WCA to 139.2°. Concurrently, the reduced silane cluster size during ultrasonication decreased pore blockage in nonwoven matrix while improving fabric loftiness, resulting in enhanced air-permeability of 3 122 mm/s that meets permeability requirements for hygiene product surface layers. Furthermore, application performance tests revealed that when the mesh size was 2 mm, the hydrophobic mesh nonwoven exhibited good unidirectional liquid transport properties, with liquid penetration time, wet-back and run-off amount of 2.84 s, 0.012 g, and 1.403 g, respectively.

      Conclusion Bamboo pulp cellulose nonwoven materials with integrated hydrophobicity and permeability were successfully developed through a one-step urethanation reaction between ISPTMOS and cellulose hydroxyl groups. The BCNW-ISPTMOS(U) demonstrated significantly enhanced hydrophobic performance, achieving a WCA of 139.2° with stable hydrophobic efficacy. Laser perforation experiments revealed that nonwoven with 2 mm triangular pore arrays optimally balanced liquid penetration and anti-backflow performance, confirming their potential as surface layer materials for absorbent hygiene products. However, current technological implementation faces dual constraints of high production costs and localized structural alterations due to laser processing. These limitations necessitate methodological innovations in research approaches to accelerate the industrial adoption of cellulose-based nonwovens in hygiene product manufacturing.

      Optimization of treatment efficiency of indigo dyeing wastewater by electrocoagulation using Al-Mg alloy anodes
      ZUO Zhuofan, LU Kailiang, LI Qianwen, ZHANG Wei
      Journal of Textile Research. 2025, 46(09):  197-204.  doi:10.13475/j.fzxb.20250200101
      Abstract ( 147 )   HTML ( 1 )   PDF (21966KB) ( 21 )   Save
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      Objective The passivation of Al anodes during electroflocculation reduces the dissolution rate and current efficiency, negatively impacting flocculation yield, contaminant removal efficiency, and increasing energy consumption. In order to solve the above problems, Al-Mg alloy electrodes with varying Mg content were selected as anodes, and the electroflocculation system for indigo dyeing wastewater was constructed together with graphite cathode. The wastewater treatment efficiency of Al-Mg alloy anode and the Mg doping on the inhibition of anode passivation were investigated to understand the activation mechanism of Al-Mg alloy electrode by Mg element, providing a new path and theoretical basis for the performance and effect optimization of the electroflocculation system for indigo dyeing wastewater.

      Method Al and four types of Al-Mg alloy electrodes with different Mg contents, namely 5052 (Mg 2.2%-2.8%), 5A03 (Mg 3.2%-3.8%), 5083 (Mg 4.0%-4.9%), 5A06 (Mg 5.8%-6.8%), were selected as anode. The performance of alloy electrode on chemical oxygen demand (COD), total organic carbon (TOC) removal and energy consumption was analyzed. The influence of Mg doping on the dissolution and passivation of the alloy anode during the electroflocculation process was investigated with EDS energy spectroscopy, thermal infrared imaging, open circuit potential and polarisation curve tests.

      Results Under the same electroflocculation operating parameters i.e.,applied voltage of 10 V, electrolytic time of 20 min and plate space of 3 cm, the electroflocculation treatment results showed that Al-Mg alloy 5A03 and 5083 did not have significant performance on COD removal rate, chromaticity and flocculation yield. Therefore, Al, 5052 and 5A06 were selected for the experimental verification and characterization analysis of Mg doping, which is conducive to improving electrode activity and electroflocculation effect. Within the same operational conditions, the loss rate of the Al-Mg 5052 was lower than that of Al and 5A06. After electroflocculation with 5A06 and 5052 anodes, the TOC removal rate was 49% and 48%, respectively, and the chromaticity was 50 times for both cases, which were both better than pure Al. In addition, the COD removal rate with 5A06 anode was higher than the electroflocculation system of pure Al anode. After the electroflocculation process, the corrosion potentials for Al, 5052, and 5A06 electrodes shifted positively. The polarization curves of the Al electrode showed current plateau due to the inhibition of metal ion dissolution by passivation. However, it was not detected in that of Al-Mg alloy electrodes. Following treatment, the Al anode surface showed a decrease in Al content and an increase in O content, alongside the presence of Al2O3 spherical particles in the electrode's dissolved pits, with Al2O3 content exceeding that of the Al-Mg alloy surface.

      Conclusion The wastewater after electroflocculation using Al-Mg alloy 5A06 and 5052 achieved effectively improved TOC removal rate and chromaticity compared to the pure Al anode electroflocculation system. Notably, the COD removal efficiency with the 5A06 anode exceeded that of pure Al. The polarization curve of the Al-Mg alloys electrode after electrocoagulation showed no current plateau, and the open-circuit potential was negatively shifted. The performance is attributed to the addition of Mg, which increases the electrode dissolution rate and inhibits passivation. Thermal infrared imaging revealed more pronounced passivation at the electrode plate edges compared to the center, with the passivation area of the Al electrode being significantly greater than that of the Al-Mg alloy electrode. In conclusion, the electroflocculation system constructed with 5A06 as the anode improved the treatment effect of indigo dyeing wastewater to a certain extent and effectively inhibited the passivation process of the electrode.

      Apparel Engineering
      Optimal selection mechanism for multi-dimensional cutting schemes in garment customization production
      WU Xiying, DU Jinsong, LI Hanhan
      Journal of Textile Research. 2025, 46(09):  205-212.  doi:10.13475/j.fzxb.20250306201
      Abstract ( 109 )   HTML ( 7 )   PDF (8718KB) ( 30 )   Save
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      Objective The rapid proliferation of personalized customization and fast-response orders in the garment industry necessitates dynamic scheduling for mixed-order production. Existing studies predominantly focus on single-order optimization, lacking frameworks to address multi-dimensional heterogeneity in fabric properties, order sizes, and equipment compatibility. A three-dimensional coupling model is developed to optimize cutting schemes, enhance resource allocation efficiency, and reduce production cycles. It is critical for enabling flexible manufacturing systems to adapt to small-batch, high-variability environments while balancing efficiency and equilibrium.

      Methods A data-driven framework integrated machine learning and multi-objective optimization. Order attributes and cutting parameters were quantified into feature vectors. A classification and regression tree (CART) algorithm, trained on historical data, classified spreading units and matched them to compatible devices. An improved non-dominated sorting genetic algorithm II (NSGA-Ⅱ) was adopted to optimize scheduling with dual objectives, i.e. minimizing total cutting time (F1) and maximizing production balance rate (F2). Constraints included device availability and fabric-device compatibility matrices. Validation was carried out using real-world data from HL Customization Enterprise, involving heterogeneous equipment and mixed orders.

      Results The proposed framework demonstrated significant improvements in production efficiency, resource allocation, and decision-making robustness through comprehensive validation with real-world data. The CART model identified fabric width as the most influential factor in device matching, with a feature importance of 0.299, followed by color (0.245) and texture orientation (0.102), while attributes like fabric elasticity and thickness showed negligible impacts. These criteria enabled the classification of 1 065 spreading units into seven device categories. Narrow-width fabrics measuring 91.5 mm or less were systematically assigned to devices P1-P3 and P5-P7 under rules such as limiting layers to 11.0 and texture orientation thresholds to 0.5. Orders requiring precision for wider fabrics, such as 144 mm materials, were routed to laser cutters (P4).The N S G A II helped achieve the dual-objective optimization, reducing the maximum completion time by 4.2%, from 291.95 to 279.63 hours, while improving the production balance rate to 89.96%. Pareto solutions revealed a spectrum of trade-offs, where the most time-efficient solution minimized the completion time to 279.63 h but yielded a lower balance rate of 70.54%, whereas the equilibrium-focused solution achieved an 89.96% balance rate at a marginally higher completion time of 284.64 hours. Total cutting time was converged to 274 h after 200 generations, with 78% of non-dominated solutions at generation 100 remaining optimal in the final set, indicating algorithm stability. Device workload variation was decreased sharply, as evidenced by the reduction in the coefficient of variation from 0.15 to 0.05, ensuring near-uniform utilization across 83% of equipment. Material efficiency improved significantly, with fabric waste decreasing by 23% through optimized device-fabric pairing. Orders with complex patterns, such as striped fabrics, achieved 98.2% material utilization when assigned to laser cutters, compared to 89.5% with conventional methods. The algorithm-maintained solution diversity, with crowding distances exceeding 0.8, and minimized premature convergence through a population size of 200, crossover probability of 0.6, and mutation probability of 0.4. Cross-generational analysis revealed a 12.3% increase in non-dominated solutions between generations 50 and 200. These results highlight the framework's capacity to reconcile conflicting objectives in mixed-order production. The integration of data-driven classification and multi-objective optimization enhanced operational efficiency while introducing adaptability to dynamic order influx, as demonstrated by a 27% reduction in rescheduling frequency for new orders. Empirical relationships, such as the inverse correlation between fabric width and device compatibility, further validated the model's alignment with real-world constraints.

      Conclusions This study proposes a dynamic decision-making framework integrating the CART and NSGA-II to address resource allocation and efficiency coordination in mixed-order garment customization. The framework shortens the maximum completion time by 4.2%, improves production balance rate to 89.96%, and decreases material waste by 23% through optimized device-fabric pairing. The CART model identifies fabric width, color, and texture orientation as critical factors in equipment compatibility, while NSGA-II generates Pareto solutions that balance efficiency and equilibrium. The innovation lies in dynamically mapping order attributes to process parameters, overcoming limitations of single-objective optimization. The framework is scalable to discrete manufacturing sectors such as automotive and electronics, particularly for small-batch, high-variability scenarios. Future work should integrate real-time IoT data for adaptive scheduling and explore multi-stage production chain coordination. Practical implementation requires establishing process rule libraries and adopting digital twin technology for constraint simulation. This research advances intelligent transformation in garment manufacturing, providing an important reference for sustainable and flexible production paradigms.

      Research on style design of Qing dynasty mandarin square based on Cycle GAN
      LIU Beifen, ZHANG Tantan, FENG Zhengrong
      Journal of Textile Research. 2025, 46(09):  213-224.  doi:10.13475/j.fzxb.20250306501
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      Objective An improved cycle generative adversarial network (Cycle GAN) style transfer method is proposed to address insufficient color preservation and loss of multi-layered pattern details when transferring Qing dynasty mandarin square badge styles, aiming to preserve these imperial rank insignia's cultural heritage while effectively reproducing their complex pattern systems through deep learning techniques.

      Method The Qing dynasty mandarin square patterns were analyzed through pattern elements, color schemes, and compositional structure. Five style transfer models, i.e., self-discriminative cycle generative adversarial networks (SD GAN), no-independent-component-for-encoding GAN (Nice GAN), dual generative adversarial network (Dual GAN), generative adversarial networks that learns to discover relations between different domains (Disco GAN), and cycle generative adversarial network (Cycle GAN), were compared. Based on the recognition of Cycle GAN as the optimal foundation, three modifications were implemented, including adding feature fusion modules to the generator to enhance pattern detail capture, and simplifying the discriminator structure to preserve compositional features, and introducing perceptual loss functions to prevent pattern-background color merging.

      Results The modified model demonstrated significant technical enhancements. The structural similarity index measure (SSIM) increased by 0.041, peak signal-to-noise ratio (PSNR) improved by 2.17 dB, mean squared error (MSE) decreased by 0.031, learned perceptual image patch similarity (LPIPS) reduced by 0.042, and the frÉchet inception distance (FID) index dropped by 4.157.

      The modified model also generated clearer traditional motifs, particularly auspicious cloud patterns and sea-mountain designs. It effectively separated background colors from foreground patterns, enhancing layering effects and edge definition crucial to these historical insignia. The feature fusion mechanism in the generator captured multi-scale pattern features more effectively, preserving intricate details of emblematic elements while maintaining proportional relationships. This improvement appeared most notably in the preservation of fine line work and distinctive gradations in cloud and water motifs. The simplified discriminator better preserved pattern distribution logic and spatial relationships between decorative elements, maintaining the symbolic hierarchy inherent in these rank-signifying textiles. This improvement particularly affected the compositional integrity of central animal motifs (such as cranes or lions) that designated specific ranks. The perceptual loss functions addressed color bleeding between foreground and background elements, resulting in more precise color boundaries while maintaining harmonious transitions characteristic of traditional silk embroidery. The improved color fidelity preserved symbolic color associations while allowing adaptability to contemporary palettes.

      Visual assessment confirmed the improved model reproduced the distinctive qualities of Qing dynasty mandarin squares more accurately, including balanced composition, symbolic coherence, and intricate detailing.

      Conclusion This study systematically analyzed style transfer models for Qing dynasty mandarin square patterns, revealing their unique artistic characteristics through content form, color composition, and layout arrangement. Through comprehensive evaluation of five mainstream image generation style transfer models using artistic and technical metrics, Cycle GAN was identified as the optimal choice. Effective improvements were developed addressing insufficient layering, pattern overlapping, and excessive color blending in generated images. The improved model achieved breakthroughs in three key areas, namely (i) the feature fusion module enhanced multi-scale pattern feature capture, particularly improving preservation of cloud motifs and sea-mountain designs, (ii) the optimized discriminator with 1×1 convolution kernels and reduced network layers prevented information loss, enhanced understanding of unique compositional layouts, and resolved pattern continuity issues, and (iii) the perceptual loss functions optimized background-pattern separation, creating natural color transitions consistent with traditional principles. These improvements enabled successful transfer of artistic characteristics while preserving modern image content, integrating traditional elements with contemporary aesthetics. This research provides an innovative pathway for digital inheritance of mandarin square patterns, enabling automated creation of modern animal images in traditional styles, improving design efficiency and meeting personalization requirements. Future research will explore this method's applicability to other complex traditional patterns.

      Machinery & Equipment
      Analysis of air duct structure and flow field fiber movement trajectory of airflow web forming machine
      HU Zehan, CUI Jianghong, XU Hang, FAN Zhen, DU Qingxiang, FAN Lankun
      Journal of Textile Research. 2025, 46(09):  225-231.  doi:10.13475/j.fzxb.20241202901
      Abstract ( 121 )   HTML ( 3 )   PDF (13603KB) ( 18 )   Save
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      Objective The uniformity of airflow inside the air duct of the airflow web forming machine affects the trajectory of fiber movement, thereby affecting the uniformity of fiber web laying. The study aims to investigate the influence of the air duct structure of the airflow web forming machine on the uniformity of air flow, improve the structure of the air duct of the airflow web forming machine, and at the same time, based on determining the optimal air duct model, study the motion of fiber length under the conditions of the optimal model, providing reference for the design and production of the air flow forming machine.

      Method Finite element analysis was adupted to simulate the air duct of the airflow web forming machine. Using SolidWorks software to establish a model of the airflow web forming machine's air duct, the model was imported into the commercial software Cradle CFD for simulation calculation. Boundary conditions were set according to actual working conditions, and simulations were conducted to draw velocity and pressure cloud maps for different situations. The Choi model was adopted to describe the bending motion of fibers, and the motion trajectory cloud map of fibers was drawn. The changes in the motion trajectory of fibers with two different lengths in the flow field were compared.

      Results The analysis results indicate that the maximum velocity of the three types of air duct tail opening structures is generated at the same position, but there is a significant difference in their velocity distribution. The airflow distribution of the air duct structure with a tail opening of 10° is more uniform compared to the air duct structures with openings of 20° and 30°, and its average wind speed of 21.8 m/s occupies more than half of the duct. Meanwhile, in the comparison of the airflow velocity cloud maps at the outlet, the average velocity of the air duct model with an opening of 10° can fully cover the width direction of the air duct outlet and occupy more than two-thirds of the area. The air duct model structure with an opening of 20° does not fully occupy the width direction, while the air duct model structure with an opening of 30° has an average velocity that is also fully covered in the width direction, but occupies a smaller area. Therefore, from the above comparison, it can be concluded that the airflow situation in the air duct with an opening of 10° is better than the other two. The coupling calculation of the airflow field model with an opening degree of 10° and the fiber model of the airflow web forming machine shows that the fibers with a length of 15 mm can be uniformly dispersed without entanglement or accumulation, and remain dispersed at the outlet. Fibers with a length of 30 mm will tangle and accumulate after moving in the airflow for a period of time. This entanglement and accumulation will continue all the way to the outlet of the air duct and be blown out of the air duct in the form of entanglement and accumulation. Fibers with lengths of 45, 60 and 75 mm will also show tangling at the outlet position, and the tangling of 75 mm fibers at the outlet position is more severe.

      Conclusion The distribution structure of the airflow web forming machine has a significant influence on the airflow field. Adopting an appropriate air duct structure can make the airflow field more uniform. When the opening degree of the air duct of the air flow forming machine is 10°, the airflow field is the most uniform and the outlet velocity is also more appropriate. Fibers with a length of 15 mm can be blown out more evenly from the air duct outlet compared to fibers of other lengths.

      Position detection method of permanent magnet synchronous motor for weft storage device based on Kalman feedforward fitting observer with Hall sensor
      MENG Ziyu, LU Wenqi, ZHANG Song, MIAO Shenghong, HUANG Fuhua, PENG Laihu
      Journal of Textile Research. 2025, 46(09):  232-241.  doi:10.13475/j.fzxb.20241002501
      Abstract ( 133 )   HTML ( 3 )   PDF (14625KB) ( 22 )   Save
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      Objective In order to meet the high-speed and high stability control requirements of the motor driving sulutions for the application of weft storage, and to improve the accuracy of position and speed estimation in the permanent magnet synchronous motor drive system based on Hall sensors so as to enhance the stability of yarn transport in the weft storage device, This paper analyzes in detail the working principle of Hall sensors and proposes a motor rotor position and speed estimation method based on Kalman feedforward fitting state observer to address the problems of discrete position signals and low speed estimation accuracy in the permanent magnet synchronous motor drive system based on Hall sensors.

      Method This article provides a detailed analysis of the working principle of Hall sensors and proposes a motor rotor position and velocity estimation method based on Kalman feedforward fitting state observer. First of all, This method uses the Kalman iterative algorithm to filter and fit the discrete Hall signal, eliminating the noise disturbance caused by Hall installation deviation; secondly, a full dimensional state observer is adopted to estimate the rotor position information of the motor, ultimately obtaining continuous rotor position and velocity information of the motor.

      Results Compared with conventional algorithms, in the motor drive performance testing section, using the algorithm proposed, running at a given speed of 500 r/min, the startup response time is consistent and the steady-state error is reduced by 15%. At a given speed of 1 500 r/min, the startup time was shortened by 0.2 s and the steady-state error was reduced by 11.5%. At a given speed of 5 000 r/min, the startup time was shortened by 0.8 s and the steady-state error was reduced by 0.8%. In the performance testing of closed-loop yarn conveying in the weft storage device, the algorithm proposed was a dopted to shorten the start-up time by 0.1 s and steady-state error by 7.6% under the condition of external sock machine pulling yarn speed of 100 m/min. Under the condition of external sock machine pulling yarn at a speed of 700 m/min, the startup time was shortened by 0.2 s and the steady-state error was reduced by 13.3%.

      Conclusion The experimental results show that compared with conventional algorithms, the proposed energy storage control system based on Kalman feedforward fitted state observer has higher estimation accuracy of motor rotor position and velocity during start-up and steady-state operation, and better motor driving performance; in the process of yarn conveying, the dynamic and steady-state performance of the weft storage control system is better, which better meets the high-performance control requirements of weft storage yarn conveying.

      Comprehensive Review
      Research progress and application of ion exchange membranes in fuel cells
      SU Yi, ZENG Pengjin, SUN Fei, GUO Yuhai
      Journal of Textile Research. 2025, 46(09):  242-249.  doi:10.13475/j.fzxb.20241205502
      Abstract ( 190 )   HTML ( 10 )   PDF (7271KB) ( 43 )   Save
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      Significance The growing demand for electrical energy, driven by industrial development, urbanization and rising living standards, highlights the urgent need for sustainable alternative energy solutions. Conventional energy sources, primarily fossil fuels, are becoming increasingly unsuitable due to their impact on the environment. In order to address these challenges, fuel cells have received attention as a promising clean energy technology. The core component of fuel cell operation is the ion exchange membrane, which plays a key role in determining the overall efficiency, stability and service life of the fuel cell. Therefore, advancing the performance and cost-effectiveness of fuel cell technology, especially ion exchange membranes, is critical. This study examines in detail the current status of ion exchange membrane technology in fuel cells, highlighting its key role in promoting fuel cells as a mainstream energy source. By increasing the efficiency of these membranes and reducing production costs, fuel cells can be more widely used, supporting the transition to a sustainable, low-carbon energy future.

      Progress Significant progress has been made in the development of ion exchange membranes for fuel cells over the past few decades. One of the main challenges in membrane technology is balancing high ionic conductivity, mechanical strength, and chemical stability. These properties are critical to ensuring long-term efficiency and durability of fuel cells under a variety of operating conditions. In order to address these challenges, researchers have developed several types of ion exchange membranes, including proton exchange membranes (PEMs), anion exchange membranes (AEMs), and amphoteric ion exchange membranes (AEMDs). Each type of membrane has unique properties tailored for specific fuel cell applications. For example, PEMs are commonly used in proton exchange fuel cells and have high proton conductivity, but face challenges with temperature stability. AEMs, on the other hand, are more suitable for alkaline fuel cells and have the potential to reduce costs and enhance stability in harsh environments. In addition to developing various membrane types, substantial progress has been made in improving these membranes to enhance their performance. Blending different polymer materials or adding nanoparticles to the membrane are effective strategies to improve mechanical strength and ionic conductivity. These improvements help reduce membrane losses and increase ion transport efficiency, thereby improving the overall performance of the fuel cell. In addition, these advances have helped reduce costs, making fuel cells more commercially viable. The addition of materials such as nanocomposites and conductive polymers has enabled the development of membranes that perform well in both high-temperature and high-humidity conditions, addressing some of the key limitations of earlier designs. These innovations have opened up new avenues for the commercialization of fuel cells, making them a more practical alternative to traditional energy sources in a variety of applications, from automobiles to stationary power generation.

      Conclusion and Prospect Despite the encouraging progress in the development of ion exchange membranes for fuel cells, several challenges still exist that hinder their widespread commercialization. The most important of these issues is the low ionic conductivity of many ion exchange membranes at high temperatures, which reduces the overall efficiency of fuel cells in practical applications. In addition, the stability of these membranes under harsh operating conditions remains a key challenge. In addition, while advances in membrane materials and manufacturing technologies have brought about improved performance, the cost-effectiveness of these technologies remains a barrier to large-scale adoption. In order to address these challenges, future research must focus on exploring new materials that provide better ionic conductivity and stability at higher temperatures. Novel polymers, hybrid materials, and nanomaterials are currently the mainstream research directions. In addition, optimizing the structure and composition of ion exchange membranes can further improve their performance, especially by improving their resistance to chemical degradation and enhancing their thermal stability. With the continuous progress in materials science, manufacturing technology, and system integration, fuel cells and their ion exchange membranes are expected to play a key role in achieving global carbon reduction goals. As the technology matures and becomes more cost-effective, fuel cells are likely to make a significant contribution to meeting the world's energy needs in a sustainable and environmentally friendly manner. This shift will not only transform the energy industry, but also pave the way for a more sustainable, cleaner energy future.

      Research progress in activated micro/nano-carbon fibers for adsorption of volatile organic compounds
      DU Jing, ZHOU Anqi, SHI Yingxin, WANG Yue, LIU Qixia, SHAN Haoru, YU Caijiao, GE Jianlong
      Journal of Textile Research. 2025, 46(09):  250-257.  doi:10.13475/j.fzxb.20241105302
      Abstract ( 229 )   HTML ( 5 )   PDF (8567KB) ( 17 )   Save
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      Significance Volatile organic compounds (VOCs) are organic compounds with a lower boiling point, typically existing in the atmosphere in the form of vapour. In recent years, the rapid development of petrochemical, transportation, construction, interior decoration and other industries has resulted in the emission of a significant quantity of toxic and harmful VOCs into the atmosphere. These VOCs have been identified as a source of environmental contamination and are also known to have adverse effects on human health. Therefore, the control of VOCs pollution represents a crucial aspect of environmental protection, particularly in terms of safeguarding human health and the natural environment. Activated carbon fibers (ACFs) are promising adsorbents for the treatment of VOCs pollutions owing to their advantages of high surface area, including shallow pores, and good flexibility for the textile engineering. Up to now, some advanced ACFs, including micro ACFs and nano ACFs have been developed for VOCs adsorption. In order to gain a comprehensive understanding of the development status of ACFs for VOCs adsorption, this paper presents a systematic investigation of the application field of micro/nano ACFs in VOCs adsorption, which is seldomly reported before.

      Progress In order to achieve a greater effect in the removal of VOCs, both micro and nano ACFs are being developed with an increased specific surface area, greater adsorption capacity, a faster adsorption rate and a competitive adsorption priority by adopting porous carbon materials. Typically, the fabrication process of ACFs includes preparation of organic precursor fibers, stabilization of precursor fibers, carbonization and activation. The organic precursors most commonly used for the preparation of ACFs include cellulose, pitch, polyacrylonitrile, and phenolic resin. The physical and chemical structures of ACFs prepared by different precursors are distinct. In order to further enhance the adsorption capabilities of ACFs, it is essential to meticulously regulate the morphology, pore structure, and surface physical/chemical properties of ACFs. The influence of the properties of organic precursor fibers, techniques of carbonization and activation, and the functionalization strategies are crucial for the improvement of the VOCs adsorption performance of ACFs, which were summarized and preliminary discussed.

      Conclusion and Prospect Micro/nano ACFs, as an emerging type of porous carbon adsorption materials, have shown broad application prospects in the field of VOCs adsorption and separation. This review summarizes the research progress of micro/nano ACFs for VOCs adsorption, and analyzes the effects of different precursor polymer types, carbonization and activation processes on the physicochemical structure and VOCs adsorption performance of ACFs. The results indicate that the existing ACFs for VOCs adsorption are usually prepared from polymeric fibers rich in carbon elements as precursors by carbonization and activation. The organic precursors for micro ACFs are usually cellulose fibers, pitch fibers, polyacrylonitrile fibers, and phenolic resin fibers, and the precursors of nano ACFs are mainly polymeric nanofibers prepared from polyacrylonitrile, phenolic resin fibers, and some other mixed polymers by electrospinning. In addition, according to application requirements, effective control over the specific surface area, pore structure (pore size, pore volume, pore shape), and surface chemical properties (nitrogen/oxygen functional group type and content) of ACFs can be achieved by changing the precursor fiber type and optimizing the carbonization activation process, thereby improving their adsorption performance for different types of VOCs. In future research, focusing on selecting suitable precursor polymers, developing efficient modification/activation methods, and deepening adsorption mechanism research, it is expected to develop new generation of ACFs to meet the requirement of VOCs adsorption.

      Progress in application of three-dimensional silk protein scaffolds
      ZENG Yao, LÜ Jinfeng, WANG Jieping, LIU Rongpeng, ZHOU Chan
      Journal of Textile Research. 2025, 46(09):  258-267.  doi:10.13475/j.fzxb.20241200302
      Abstract ( 246 )   HTML ( 6 )   PDF (9756KB) ( 25 )   Save
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      Significance Silk protein is a naturally occurring polymer protein composed of sericin and fibroin. Fibroin has good biocompatibility, adjustable biodegradability, excellent antimicrobial properties and mechanical properties as well as strong moldable properties. Sericin has properties such as good water solubility, unique gelation properties and cell adhesion promotion. Therefore, silk proteins are often utilized to prepare various types of biomedical materials and tissue repair, among which three-dimensional silk protein scaffolds are more widely used. In order to expand the application of silk protein in biomaterials and tissue engineering and promote the clinical research of filament-based materials, the structure and preparation methods of three-dimensional silk protein scaffolds and the latest research progress and limitations of three-dimensional silk protein scaffolds in cell culture, skin, bone, cartilage, ligament and nerve repair were reviewed, aiming to provide a valuable reference for the application of silk-based biomaterials in the medical field.

      Progress Silk proteins have been shown to be biocompatible and maintain normal cell growth in both two-dimensional and three-dimensional cultures, but three-dimensional cultures based on silk proteins are able to provide cells with a porous structure that can be used as a geometrical carrier for directed cell growth, and three-dimensional culture is more suitable for disease modeling than two-dimensional culture, and more accurate results can be obtained. Since donor shortages, immune rejection of grafts, repeated surgeries, and long recovery times are prevalent in the repair of locomotor systems such as bone, cartilage, and ligaments, silk proteins have been widely adopted to prepare raw materials for the repair of these tissues by virtae of their unique properties. Three-dimensional silk protein-based scaffolds can reduce pain, shorten wound healing time as well as promote skin barrier recovery as wound dressings. The repair and regeneration effects of three-dimensional silk protein scaffolds on skin can also be further enhanced through the compounding and functionalization of raw materials. Three-dimensional silk protein-based scaffolds can promote osteoblast differentiation, repair bone defects, form artificial cartilage in animals, and also promote ligament regeneration. In addition, Three-dimensional silk protein conduits can promote the proliferation of nerve cells and the secretion of neurotrophic factors, and provide direction for the growth of nerve fibers.

      Conclusion and Prospect Because silk protein has many excellent properties, its preparation into three-dimensional scaffolds has been widely used in cell culture and tissue engineering, and it has significant advantages in promoting cell proliferation and adhesion, including promoting cell proliferation and adhesion, accelerating wound healing, collagen deposition, promoting angiogenesis, inducing osteoblast differentiation, forming cartilage in vitro and achieving functional integration in vivo, enhancing ligament-specific differentiation of adult stem cells, promoting nerve repair and so on. However, due to tissue specificity, for different damaged tissues or organs, a single silk protein scaffold material may have certain deficiencies in tissue affinity, mechanical properties, structure and functionality, so it is necessary to form a composite material by combining materials with different performance advantages. Although silk proteins have no significant side effects, the results show that structurally and functionally modified silk proteins have broader prospects for biomedical applications. In order to promote the research process of silk proteins in clinical applications, standardized and verifiable 3D cell culture models can be established in the future, while further technological improvements and optimizations can be enhanced in the areas of high-throughput analysis, image scanning, reproducibility, compatible readout technology and automation.

      Research progress in personal cooling garment technologies
      ZHU Yuancheng, HE Yonghong, XIONG Weiguo
      Journal of Textile Research. 2025, 46(09):  268-277.  doi:10.13475/j.fzxb.20241103902
      Abstract ( 165 )   HTML ( 15 )   PDF (11908KB) ( 51 )   Save
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      Significance Personal cooling garment (PCG) technology has emerged as a critical solution to mitigate heat stress for workers in high-temperature environments, such as mining, firefighting, and industrial settings. With global temperatures rising, evidenced by a 1.5 ℃ increase since the Industrial Revolution and accelerating at 0.2 ℃ per decade, heat-related health risks and economic losses (e.g. $863 billion in potential income loss in 2022) are intensifying. PCGs offer a targeted approach to maintain thermal balance, enhancing worker safety and productivity where traditional cooling methods fall short. This review evaluates the technological advancements in PCGs, emphasizing their role in addressing heat stress, a growing concern amid climate change. By systematically analyzing diverse cooling mechanisms, this review underscores the importance of lightweight, efficient, and adaptable systems to meet the urgent needs of high-risk occupations, providing a foundation for innovative thermal protection strategies in industrial applications.

      Progress This study evaluates five PCG technologies, i.e. air-cooled (ACG), liquid-cooled (LCG), phase change material (PCM), thermoelectric (TEC) and evaporative cooling (ECG), detailing their mechanisms and recent advancements. ACG systems show progress with the body ventilation system (BVS) offering lightweight designs (0.8-1.5 kg) and cooling capacities of 80-150 W through fan-driven convection, though efficacy wanes above 35 ℃. Vortex tube cooling (VTC) achieves 280-350 W using cold gas separation, but fixed gas source reliance (e.g. high-pressure compressors) limits portability. LCG systems excel in extreme heat (>45 ℃) situations, with vapor compression-based designs delivering 360-586 W/m2, and studies in this direction highlight miniaturization advances though energy density challenges remain. PCM-based systems like BVS/PCM hybrids provide 220-315 W/m2 and extend cooling by 28% via integrated ventilation and heat absorption, yet face 30% energy loss to ambient heat. TEC developments include flexible TEDs with over 10 ℃ localized cooling and COPs of 1.5-1.8, while LCG/TEC systems reach 220-300 W/m2, though low efficiency (e.g. ACG/TEC COP 0.85) remains a drawback. ECG systems yield 150-373 W/m2 in dry conditions, with innovations like vacuum desiccant designs doubling work duration in protective suits, but falter in high humidity. Key achievements include enhanced thermal comfort (e.g. UTCI drops of 1.5-2.3 ℃ in BVS/PCM) and robust heat management in harsh environments, reflecting strides in hybrid systems and material enhancements.

      Conclusion and Prospect This review confirms that PCG technologies effectively counter heat stress, each tailored to specific contexts: ACG prioritizes portability, LCG excels in extreme heat, PCM provides extended cooling duration, TEC enables precise temperature control, and ECG thrives in arid settings. However, limitations are evident. ACG's temperature sensitivity, LCG/VCR's weight (2.2-5.2 kg) and vibration issues, PCM's heat loss, TEC's poor energy efficiency (e.g. COP below 1 for ACG/TEC), and ECG's humidity dependence all highlight areas for improvement. Current challenges center on miniaturization, energy efficiency, and environmental adaptability, critical for broader adoption. Looking ahead, interdisciplinary breakthroughs are anticipated. Biomimetic designs like vortex-inspired air channels could enhance ACG performance, while magnetic levitation compressors may lighten LCG systems. Graphene-enhanced PCM composites, boosting conductivity ninefold to 1.8 W/(m·K), promise greater efficiency, and flexible TEC heterojunctions could elevate COPs. Smart controls integrating real-time thermal sensing will optimize energy use and comfort. The study advocates for hybrid systems combining strengths (e.g. PCM and TEC) and durable, lightweight materials to address industrial demands. Collaborative research across textile engineering, materials science, and thermodynamics is vital to surmount these hurdles, driving PCGs toward lighter, more powerful, and intelligent solutions. As global heat intensifies, such innovations will underpin safer, more productive work environments, aligning with sustainable industrial goals.